洋山四期自动化集装箱码头发展战略研究

在智慧化码头建设的总体趋势下,港口的运营效率、安全性、服务水平与产业链协同水平正经历快速发展。创新是我国目前新常态下经济增长的新动力,科技的进步有望推动港口行业的转型升级与可持续发展。打造的当前全球单项规模最大,技术最先进的全自动化集装箱码头工程,其设计经验对于推动我国港口的技术进步具有重要的借鉴意义,据此可以加强洋山四期自动化码头发展的研究,为智慧码头的发展提供经验与参考。

海洋情报计算机检索系统的建设

随着海洋经济和海洋科学技术的发展，迫切要求海洋科技情报工作大力采用以计算机为主的先进技术。本文介绍计算机、光盘技术在海洋科技情报检索工作中的实际应用，并对今后海洋数据库的建设作了全面考虑、规划。

鱼粪化石特征对早侏罗世托阿尔期湖泊生态系统的启示:以川东大安寨段为例

早侏罗世托阿尔期早期大洋缺氧事件(Toarcian Oceanic Anoxic Event,~183.8 Ma)是一次全球性的多幕式生物—环境事件,其在四川盆地下侏罗统自流井组大安寨段亦有显示。对采集自川东北地区大安寨段的鱼粪化石进行形态学描述和内含物分析,发现鱼粪化石中含有大量的磷质成分,多为未经消化的鱼骨化石,另有大量介壳类化石与有机质混杂在一起。据露头岩性和显微薄片特征认为:(1)粪化石呈螺旋状,生产该粪化石的鱼类为大型肉食性鱼类,其喜食小型鱼类和软体动物等,推测可能是肺鱼类(角齿鱼);(2)鱼粪化石形成于开放型淡水湖泊中的半深湖—深湖区,其中湖泊表层含氧量丰富,主要由生产者、消费者构成了研究区早侏罗世托阿尔期大型湖泊生态系统,食物链较为复杂,而湖底为水动力条件较弱的还原环境。该研究成果可为早侏罗世托阿尔期大洋缺氧事件在湖泊中的沉积响应及生态影响研究提供依据。

鄂尔多斯盆地早侏罗世富县期沉积演化:大洋缺氧事件前后陆地气候变化的响应

托阿尔期早期早侏罗世大洋缺氧事件(T-OAE,~183.8 Ma)是一次全球性的地质事件,鄂尔多斯盆地下侏罗统富县组记录了此次地质事件的陆地响应过程。主要基于盆地东缘野外地质调查、扫描电镜及薄片分析,本次研究描述了盆地东北部富县组岩性、颜色和沉积序列,利用前人研究成果总结了富县期岩相古地理变化规律及沉积模式,认为富县期经历了由干旱到湿润的古气候变化:富县组下部含植物化石较为丰富的白色砂砾岩及黑色、灰色泥页岩沉积于湿润气候时期,对应着盆地下切河谷发育期和填平补齐期;而上覆的罕见植物化石的杂色、红色泥页岩为(富县期晚期)相对平坦地形条件下的沉积,对应着早、中侏罗世湿润气候背景下的一次干旱气候脉动,为托阿尔期大洋缺氧事件在陆相环境的气候响应,可由此进行富县组区域等时性对比。研究认为“粗富县”为下切谷内河流充填沉积,“细富县”形成于湖泊环境或河漫环境,“黑富县”和“白富县”是湿润气候条件下沉积产物,而“红富县”和“杂富县”为T-OAE期后干旱条件下形成。

Expired drugs as vapor-phase corrosion inhibitors of copper in simulated marine atmospheric environment

Urea,paracetamol and glutamine(based on the expired drugs)were selected as vapor-phase corrosion inhibitors(VCIs)to study their corrosion protection effect on red copper in simulated marine atmospheric environment by using weight loss,electrochemical measurement techniques(specially designed electrochemical testing device for simulating marine atmospheric environments)and surface morphology characterization analysis(SEM/EDS,XRD,RAMAN,XPS).Weight loss results show that the three corrosion inhibitors have good corrosion inhibition effect on red copper,and the corrosion inhibition efficiency in the order of glutamine(83.62%)>urea(68.46%)>paracetamol(61.47%).Surface morphology characterization analysis provides evidence of adsorption of corrosion inhibitors molecules on the red copper surface,thus forming a protective film that blocked the red copper surface from the aggressive chloride ion attack.

驳美国国务院《海洋疆界》第143期有关南海历史性权利论述的谬误

在菲律宾就南中国海问题提出国际仲裁的背景下,美国国务院在2014年12月5日公布的《海洋疆界》第143期中,对南中国海中中国提出的"断续线"做出了三种解释,并就每一种解释与国际法是否吻合做出评论。本文针对第三种解释中所涉及的历史性权利部分进行分析与评论,批驳其中的谬误。

从腾冲和香格里拉沉积记录看60ka BP以来的印度季风活动特征

通过腾冲北海与香格里拉纳帕海有机碳含量、δ^13C、粒度等沉积指标和若干孢粉指标的对比,参照60ka BP以来孟加拉湾的沉积韵律互层与δ^18O记录,发现它们同与印度季风系统存在密切关联。然而由于经纬与海陆分布的差异,夏季风和冬季风对各处的影响亦有很大差别。大约发生于37-32ka BP的强大的暖湿型气候事件在北海与纳帕海盆地的沉积序列之中反映突出,成为过去60ka间最引人瞩目的现象,但是却缺乏海域记录的有力呼应。海陆记录对比结果表明,MIS3后期区域气候事件的控制因素来自陆地而非海洋,青藏高原在此期间的特别升温导致印度冬季风的衰退及其他大气环流型式的改变有可能是重大气候事件形成的主因。此外,陆地地貌对于季风的降水效应也有不可忽视的影响。

北极海域的大地构造:新的观测研究

苏联大陆架的近期研究显著地扩展了我们对苏联大陆边缘地区地质构造的了解。从苏联广袤的北极大陆架水域的研究获得了大量的新资料。

Joint Occurrence Period of Wind Speed and Wave Height Based on Both Service Term and Risk Probability

Return periods calculated for different environmental conditions are key parameters for ocean platform design.Many codes for offshore structure design give no consideration about the correlativity among multi-loads and over-estimate design values.This frequently leads to not only higher investment but also distortion of structural reliability analysis.The definition of design return period in existing codes and industry criteria in China are summarized.Then joint return periods of different ocean environmental parameters are determined from the view of service term and danger risk.Based on a bivariate equivalent maximum entropy distribution,joint design parameters are estimated for the concomitant wave height and wind speed at a site in the Bohai Sea.The calculated results show that even if the return period of each environmental factor,such as wave height or wind speed,is small,their combinations can lead to larger joint return periods.Proper design criteria for joint return period associated with concomitant environmental conditions will reduce structural size and lead to lower investment of ocean platforms for the exploitation of marginal oil field.

Northward expansion of the western Pacific Warm Pool in late 1990s and early 2000s

Based on 48-year (1958-2006) ocean reanalysis data of Simple Ocean Data Assimilation and 23-year (1984-2006) global ocean-surface heat flux products developed by the Objectively Analyzed Air-Sea Heat Flux Project, meridional variation of the western Pacific Warm Pool (WPWP) is addressed. The results show that there is a significant expansion of the northern edge of the WPWP in the late 1990s and early 2000s. This variation is mainly within 120°E-160°E by 8°N-20°N, we define this region (120°E-160°E by 8°N-20°N) as the core region. Furthermore, analyses on upper ocean heat budget show that the short wave radiation plays a key role in the northward expansion of the northern edge of the WPWP in the core region. It is proved that the northward expansion may be caused by the change of the mixed layer which became shallower in 1994-2006 compared with 1984-1993 in the study region. The short wave radiation flux distribution within the shallower mixed layer leads to a positive anomaly in seawater temperature, promoting the northward expansion of the WPWP.

Long-term variabilities of thermodynamic structure of the East China Sea Cold Eddy in summer

Based on more than 30 years observed sectional temperature data since the 1960s, and compared with multi-year wind and Changjiang (Yangtze) River discharge data, spatial-temporal variations of the East China Sea Cold Eddy (ECSCE) in summer was analyzed in relationship to ocean circulation and local atmospheric circulation. Empirical Orthogonal Function (EOF) and Singular Value Decomposition (SVD) analyses were applied to this study. The results show that: 1) The ECSCE in summer possesses significant interannual variabilities, which are directly associated with oceanic and atmospheric circulation anomaly. Main fluctuations demonstrate their falling in basically with El Nino events (interannual) and interdecadal variability. 2) The ECSCE in summer is closely related to the variation of the Yellow Sea Warm Current (YSWC) and the Changjiang River discharge. The stronger the YSWC, the more intensive the ECSCE with its center shifting westward, and vice versa. However, a negative correlation between the Changjiang River discharge and the ECSCE strength is shown. The ECSCE was strengthened after the abrupt global climate change affected by the interdecadal variation of the YSWC. 3) SVD analysis suggested a high correlation between the variation of the ECSCE in summer and the anomalous cyclonic atmospheric circulation over the ECS. Intensification of the cyclonic wind strengthens the ECSCE, and vice versa. 4) The cyclonic atmospheric circulation has dominant influence on the interannual variation of the ECSCE, and the influence of the ocean circulation takes the second in. The ECSCE was usually stronger in El Nino years affected by strong cyclonic circulation in the atmosphere. The variation in strength of the ECSCE resulted from the joint effect of both oceanic and atmospheric circulation.

The potential of ocean acidification on suppressing larval development in the Pacific oyster Crassostrea gigas and blood cockle Area inflata Reeve

We evaluated the effect of pH on larval development in larval Pacific oyster(Crassostrea gigas) and blood cockle(Arca inflata Reeve).The larvae were reared at pH 8.2(control),7.9,7.6,or 7.3beginning 30 min or 24 h post fertilization.Exposure to lower pH during early embryonic development inhibited larval shell formation in both species.Compared with the control,larvae took longer to reach the D-veliger stage when reared under pH 7.6 and 7.3.Exposure to lower pH immediately after fertilization resulted in significantly delayed shell formation in the Pacific oyster larvae at pH 7.3 and blood cockle larvae at pH 7.6 and 7.3.However,when exposure was delayed until 24 h post fertilization,shell formation was only inhibited in blood cockle larvae reared at pH 7.3.Thus,the early embryonic stages were more sensitive to acidified conditions.Our results suggest that ocean acidification will have an adverse effect on embryonic development in bivalves.Although the effects appear subtle,they may accumulate and lead to subsequent issues during later larval development.

Experimental Dynamical Forecast of an MJO Event Observed during TOGA-COARE Period

With a hybrid atmosphere-ocean coupled model we carried out an experimental forecast of a well documented Madden-Julian Oscillation (MJO) event that was observed during the period of Tropical Ocean Global Atmosphere Coupled Ocean-Atmosphere Response Experiment (TOGA-COARE). The observed event, originated in the western Indian Ocean around 6 January 1993, moved eastward with a phase speed of about 6.2 m s 1 and reached the dateline around February 1. The hybrid coupled model reasonably forecasts the MJO initiation in the western Indian Ocean, but the predicted MJO event propagates too slow (～ 4.4 m s 1 ). Results from previous observational studies using unprecedented humidity profiles obtained by NASA Aqua/AIRS satellite suggested that two potential physical processes may be responsible for this model caveat. After improving the cumulus parameterization scheme based on the observations, the model is able to forecast the same event one month ahead. Further sensitivity experiment confirms that the speed-up of model MJO propagation is primarily due to the improved convective scheme. Further, air-sea coupling plays an important role in maintaining the intensity of the predicted MJO. The results here suggest that MJO prediction skill is sensitive to model cumulus parameterization and air-sea coupling.

3-D BAROCLINIC NUMERICAL SIMULATION OF THE SOUTH CHINA SEA I. UPPER CIRCULATION

A three dimensional baroclinic shelf sea model was employed to simulate the seasonal characteristics of the South China Sea (SCS) upper circulation. The results showed that: in summer, an anticyclonic eddy, after its formation between the Bashi Channel and Dongsha Islands in the northeastern SCS, moves southwestward until it disperses slowly. There exists a northward western boundary current along the east shore of the Indo China Peninsula in the western SCS and an anticyclonic gyre in the southern SCS. But at the end of summer and beginning of autumn, a weak local cyclonic eddy forms in the Nansha Trough, then grows slowly and moves westward till it becomes a cyclonic gyre in the southern SCS in autumn. At the beginning of winter, there exists a cyclonic gyre in the northern and southern SCS, and there is a southward western boundary current along the east shore of the Indo China Peninsula. But at the end of winter, an anticyclonic eddy grows and moves toward the western boundary after forming in the Nansha Trough. The eddy’s movement induces a new opposite sign eddy on its eastern side, while the strength of the southward western boundary current gets weakened. This phenomenon continues till spring and causes eddies in the southern SCS.

Effects of Elevated Seawater pCO2 on Early Development of Scallop Argopecten irradias (Lamarck, 1819)

To investigate the effects of elevated seawater p CO_2 on the early developmental stages of marine benthic calcifying organisms, we exposed the eggs and larvae of Argopecten irradias, an important bivalve species in Chinese aquaculture, in seawater equilibrated with CO_2-enriched(1000 ppm) gas mixtures. We demonstrated that elevated seawater pCO_2 significantly interfered with fertilization and larval development and resulted in an increased aberration rate. Fertilization in the treatment(pH 7.6) was 74.3% ± 3.8%, which was 9.7% lower than that in the control(p H 8.3)(84.0% ±3.0%). Hatching success decreased by 23.7%, and aberration rate increased by 30.3% under acidic condition. Larvae in acidified seawater still developed a shell during the post-embryonic phase. However, the shell length and height in the treatment were smaller than those in the control. The development of embryos differed significantly at 12 h after fertilization between the two experimental groups. Embryos developed slower in acidified seawater. Nearly half of the embryos in the control developed into D-shaped larvae at 48 h after fertilization, which were considerably more than those in the treatment(11.7%). Results suggest that future ocean acidification(OA) would cause detrimental effects on the early development of A. irradias.

Total Synthesis of Marine Cyclic Enol-Phosphotriester Salinipostin Compounds

Due to their structural diversity and variety of biological activities, marine natural products have been the subject of extensive study. These compounds, especially phospholipid polycyclic aromatic hydrocarbons, have a wide range of pharmacological applications, including embedded DNA and central nervous system, anti-tumor, anti-virus, anti-parasite, anti-bacterial, and antithrombotic effects. Unfortunately, the insufficient drug sources have limited the development of these compounds. In this study, we isolated salinpostin compounds from a fermentation solution of marine-derived Salinospora sp., which has a common bicyclic enol-phosphotriester core framework, as well as potent and selective antimalarial activities against P. falciparum with EC_(50)=50 nmolL^(-1). The chemical synthesis of these compounds in greater quantities is necessary for their use in bioactivity studies. Thus we explored a short route with high yields and mild reaction conditions, which can generate combinatorial libraries for drug discovery and lead optimization. We developed a new total synthesis method for six cyclic enol-phosphotriester salinipotin compounds and their diastereomers. For the total synthesis of cyclipostin P, we prepared cyclic enol-phosphotriester salinipostin compounds in 10 steps from a readily accessible starting material, 1,3-dihydroxyacetone, and obtained an overall yield of 1.29%. We fully characterized these compounds by proton nuclear magnetic resonance(~1H-NMR), carbon-13 NMR(^(13)C-NMR), and high-resolution mass spectrometry(HRMS) analyses, and found they coincide absolutely with the same compounds reported previously.

Diurnal Variation of Tropical Cyclone Rainfall in the Western North Pacific in 2008-2010

Diurnal variation of tropical cyclone （TC rainfall in the western North Pacific （WNP） is investi gated using the high-resolution Climate Prediction Ce~ ter＇s morphing technique （CMORPH） products obtaine from the National Oceanic and Atmospheric Administra tion （NOAA）. From January 2008 to October 2010, 7 TCs and 389 TC rainfall days were reported by the Joir Typhoon Warning Center＇s （JTWC） best-track record. Th TC rain rate was partitioned using the Objective Synopti Analysis Technique （OSAT） and interpolated into Local Standard Time （LST）. Harmonic analysis was applied t analyze the diurnal variation of the precipitation. Obviou diurnal cycles were seen in approximately 70% of the TC rainfall days. The harmonic amplitude and phase of the mean TC rainfall rate vary with TC intensity, life stage, season, and spatial distribution. On the basis of intensity, tropical de- pressions （TDs） exhibit the highest precipitation variation amplitude （PVA）, at approximately 30%, while super ty- phoons （STs） contain the lowest PVA, at less than 22%. On the basis of lifetime stage, the PVA in the decaying stage （more than 37%） is stronger than that in the devel oping （less than 20%） and sustaining （28%） stages. On the basis of location, the PVA of more than 35% （less than 18%） is the highest （lowest） over the high-latitude oceanic areas （the eastern ocean of the Philippine Islands）. In ad dition, a sub-diurnal cycle of TC rainfall occurs over the high-latitude oceans. On the basis of season, the diurnal variation is more pronounced during summer and winter, at approximately 30% and 32%, respectively, and is weaker in spring and autumn, at approximately 22% and 24%, respectively.

Modulation by the Atlantic Multidecadal Oscillation of the intensity of the interannual seesaw between the Somali and Australian cross-equatorial flows

The decadal variation of the intensity of the interannual opposite connection （seesaw） between the Somali and Australian cross-equatorial flows （CEFs） is investigated. During the period prior to the mid-1960s, and after the early-2000s, the intensity of the interannual seesaw connection is significantly weaker relative to the period between. Such interdecadal shifts in the interannual seesaw intensity bear a resemblance to the decadal shift in ENSO＇s strength, and can be further attributed to the phase transition of the Atlantic Multidecadal Oscillation （AMO）. When the AMO is in a positive phase, the ENSO amplitude reduces and the seesaw strength becomes weakened, and vice versa.The historical simulation outputs of the CMIP5 models are used to verify the connection, and a similar result was obtained. Thus, the notion that the intensity of the interannual opposite connection （seesaw） between the CEFs is modulated by the AMO is robust.

Sedimentary Characteristics of the Second Marine Layer During the Late Marine Isotope Stage 3 in Southern Yellow Sea and Their Response to the East Asian Monsoon

We use the particle size of sediments in core YS01A to study the sedimentary environment of the mud deposit in the central South Yellow Sea of China during late Marine Isotope Stages 3 （MIS3; 40.5 kyr-31.3 kyr）. In addition, the East Asian Monsoon and its relationship with the North Atlantic Ocean climate change are discussed based on the sensitive grain-size calculation and the spectrum analysis. The results show that during late MIS3, the muddy area in the central South Yellow Sea experienced the evolution of coastal facies, shallow marine facies, coastal facies, and continental facies, with weak hydrodynamic conditions. Compared with other climate indicators, we found that there were many century to millennium-scale climate signals documented in the muddy area sediments in the central South Yellow Sea. According to our particle size results, three strong winter monsoon events occurred at 37.6kyr, 35.6kyr and 32.2kyr. The East Asian Winter Monsoon records in core YS01A are consistent with the Greenland ice core and the Hulu cave stalagmite 8180. The millennial and centennial scale cycles, which are 55 yr, 72 yr, 115 yr, 262 yr respectively, correspond to solar activity cycles, while the 1049 yr and 2941 yr cycles correspond to the Dansgaard-Oeschger cycles. These cycles indicate that the paleoclimate evolution of the area was controlled by the solar activities, with the high-latitude driving thermohaline circulation as the main energy conveyor belt, followed by the sea-air-land amplification of the winter monsoon variation in the central Yellow Sea in the late MIS3.

Heavy mineral stratigraphy of sediments from the southern outer shelf of the East China Sea since the last glaciation using fuzzy C-means cluster method

Correspondence analysis and fuzzy C-means cluster methods were used to divide the stratigraphy of heavy mineral assemblages, and the sediment sources and depositional dynamics of the environment reconstructed. The assemblages were taken from marine sediments from the late Pleistocene to the Holocene in Core Q43 situated on the outer shelf of the East China Sea. Based on the variable boundaries of the mineral assemblage at 63 and 228 cmbsf （cm below sea floor）, the core might have previously been divided into three sediment strata marked with units Ⅰ, Ⅱ and Ⅲ, which would be consistent with the divided sediment stratum of the core using minor element geochemistry. The downcore distribution of heavy minerals divided the sedimentary sequence into three major units, which were further subdivided into four subunits. The interval between 0 and 63 cmbsf of the core （unit Ⅰ）, which spans the Holocene and the uppermost late Pleistocene, is characterized by a hornblende-epidote-pyroxene assemblage, and contains relatively a smaller amount of schistic mineral and authigenic pyrite. In comparison, the interval between 63 and 228 cmbsf （unit Ⅱ）, is representative of the Last Glacial Maximum （LGM）, and features a hornblende-epidote-magnetite-ilmenite assemblage containing the highest concentrations of heavy minerals and opaque minerals. However, the interval between 228 and 309 cmbsf （unit Ⅲ）, which spans the subinterglacial period, is characterized by a hornblende-authigenic-pyrite-mica assemblage. Relative ratios of some heavy minerals can be used as tracers of clastic sediment sources. The lower part of the sediment core shows the highest magnetite/ilmenite ratio and relatively high hornblende/augite and hornblende/epidote ratios. The middle core shows the highest hornblende/augite and hornblende/epidote ratios, and the lowest magnetite/ilmenite ratio. The upper part exhibits a slightly higher magnetite/ilmenite ratio, and also the lowest hornblende/augite and hornblende/epidote ratios. The distribution of the mineral ratio is consistent with stratigraphic division in heavy mineral data using correspondence analysis and fuzzy C-means clustering. Variations in heavy mineral association and mineral ratio in core Q43 revealed changes in provenance and depositional environment of the southern outer shelf of the East China Sea since the late Pleistocene, well corresponding to interglacial and glacial cycles.