Systematic study on sorption behavior of o-nitrophenol on marine sediments was conducted. Isotherms of sorption of o-nitrophenol on marine sediments could be described by Freundlich model; and the isotherm of sorption...Systematic study on sorption behavior of o-nitrophenol on marine sediments was conducted. Isotherms of sorption of o-nitrophenol on marine sediments could be described by Freundlich model; and the isotherm of sorption of o-nitrophenol on HCl-treated sediment could be described by Langmuir model. The sorption behavior was affected by various factors including organic carbon content, aqueous solution salinity, temperature, and acidity. The sorption amount of o-nitrophenol increased when salinity and acidity of the aqueous solution increase, but decreased with increasing temperature. Organic carbon content in sediments had apparent effect on the behavior except for HCl-treated sediments.展开更多
The present study revealed proliferation of macro-algae modifying coral reef ecosystems in a different manner due to diseases and sedimentations in the Mandapam group of islands in the Gulf of Mannar. Benthic surveys ...The present study revealed proliferation of macro-algae modifying coral reef ecosystems in a different manner due to diseases and sedimentations in the Mandapam group of islands in the Gulf of Mannar. Benthic surveys were conducted with major attack of seven coral reefs diseases with high sedimentation rate, nine species of fleshy macro-algae(Turbinaria ornata, Turbinaria conaides, Caulerpa scalpelliformis, Caulerpa racemosa, Kappaphycus alvarezii, Padina gymnosphora, Sargassum wightii, Ulva reticulata and Calurpa lentillifera) proliferation against major corals life forms(Acropora branching, Acropora digitate, Acropora tabulate, coral massive, coral submassive, coral foliose and coral encrusting). The results confirm that diseased corals most favor to macro-algae growth(15.27%) rather than the sedimentation covered corals(8.24 %). In the degradation of coral life forms, massive corals were more highly damaged(7.05%) than any other forms. Within a short period of time(May to September), coral coverage shrank to 17.4% from 21.9%, macro-algae increased 23.51% and the average sedimentation rate attained 77.52 mg cm^(-2) d^(-1) with persisting coral reef diseases of 17.59%. The Pearson correlation showed that the coral cover decreased with increasing macro-algae growth, which was statistically significant(r =-0.774, n = 100, P < 0.0005). The proliferation of the various macro-algae C. scalpellifrmis, T. ornata, C. racemosa, T. conaides, U. reticulata, S. wightii, K. alvarezii, P. gymnosphora and C. lentillifera increased with percentages of 6.0, 5.8, 5.7, 4.9, 4.2, 3.7, 2.7 and 1.9, respectively. If this trend continues, the next generation of new recruit corals will undoubtedly lead to a phase shift in Gulf of Mannar corals.展开更多
Detailed mineral magnetic measurements, integrated with grain-size distribution and X-ray diffraction (XRD) analyses, were made on the marine sediments of Core MD98-2172, retrieved from the Eastern Timor Sea. Values...Detailed mineral magnetic measurements, integrated with grain-size distribution and X-ray diffraction (XRD) analyses, were made on the marine sediments of Core MD98-2172, retrieved from the Eastern Timor Sea. Values of magnetic susceptibility in this core drop sharply down-core from -3.85 m deep below sediment/water interface and are very low at -5.35 m. However, both XRD and grain-size distribution results show no sudden change in terrigenous input during sedimentation. Mineral magnetic results indicate that the depth of -3.85 m may be an oxic/anoxic boundary. Therefore, the sediments below -3.85 m have been subjected to intense reductive diagenesis, whereas the sediments above -3.85 m are seldom affected. The magnetic properties of the sediments shallower than 3.85 m are dominated by pseudo-single domain (PSD) magnetite, with little down-core variation in its content and grain size. Below -3.85 m, the magnetic mineral assemblages that have survived in the sediments may record different stages of the reductive diagenesis: (1) the sediments from the 3.85-5.35 m interval are at the stage of iron oxide reduction; t'SD magnetite is the major magnetic contributor, but it becomes less abundant and coarser down-core; (2) the sediments below -5.35 m are at the stage of sulphate reduction; ferrimagnetie minerals almost vanish and paramagnetic minerals contribute to down-core susceptibility variations, including pyrite as evidenced by high-temperature magnetic susceptibility measurements. However, the susceptibility variations below -5.35 m of Core MD98-2172 show obvious periodicity, despite the intense effect of reduetive diagenesis. Furthermore, the down-core susceptibility variations are coincident with fluctuations in the quantity of fine detrital particles (〈8 μm), which may come mainly from the advection of the Indonesia Throughflow (ITF) and/or river input from Timor. Therefore, for Core MD98-2172, susceptibility variation below -5.35 m, which potentially correspond to fluctuations in the quantity of fine particles, may record the histories of the development of the ITF and precipitation on Timor.展开更多
The P-T stability conditions of gas hydrate in different systems (i.e., solution, silica sand, and marine sediment) were studied using multi-step decomposition method with our experimental equipment. The effects of ...The P-T stability conditions of gas hydrate in different systems (i.e., solution, silica sand, and marine sediment) were studied using multi-step decomposition method with our experimental equipment. The effects of different ions with various concentra- tions and sediment grains on the P-T stability conditions of gas hydrate were investigated. The results show that different ions have different influences on the phase equilibrium of gas hydrate. However, the influence of ions is in a similar trend: the larg- er the concentration, the bigger the P-T curve shifts to the left. For the silica sand, the influence of pore capillarity of coarse particles (〉 460 ~tm) can be negligible. The P-T curve measured in coarse silica is in agreement with that in pure water. How- ever, the influence of pore capillarity of fine particles (〈 35 μm) is significant. The maximum reduction value of temperature is 1.5 K for methane hydrate under stable state. The sediment from the South China Sea significantly affects the P-T stability conditions of methane hydrate, with an average reduction value of 1.9 K within the experimental conditions. This is mainly the result of both the pore water salinity and the pore capillarity of sediment. Because the pore water salinity is keeping diluted by the fresh water released from hydrate dissociation, the measured P-T stability points fall on different P-T curves with the de- creasing salinity.展开更多
文摘Systematic study on sorption behavior of o-nitrophenol on marine sediments was conducted. Isotherms of sorption of o-nitrophenol on marine sediments could be described by Freundlich model; and the isotherm of sorption of o-nitrophenol on HCl-treated sediment could be described by Langmuir model. The sorption behavior was affected by various factors including organic carbon content, aqueous solution salinity, temperature, and acidity. The sorption amount of o-nitrophenol increased when salinity and acidity of the aqueous solution increase, but decreased with increasing temperature. Organic carbon content in sediments had apparent effect on the behavior except for HCl-treated sediments.
基金the National Remote Sensing Center, ISRO-Hyderabad for providing financial supports
文摘The present study revealed proliferation of macro-algae modifying coral reef ecosystems in a different manner due to diseases and sedimentations in the Mandapam group of islands in the Gulf of Mannar. Benthic surveys were conducted with major attack of seven coral reefs diseases with high sedimentation rate, nine species of fleshy macro-algae(Turbinaria ornata, Turbinaria conaides, Caulerpa scalpelliformis, Caulerpa racemosa, Kappaphycus alvarezii, Padina gymnosphora, Sargassum wightii, Ulva reticulata and Calurpa lentillifera) proliferation against major corals life forms(Acropora branching, Acropora digitate, Acropora tabulate, coral massive, coral submassive, coral foliose and coral encrusting). The results confirm that diseased corals most favor to macro-algae growth(15.27%) rather than the sedimentation covered corals(8.24 %). In the degradation of coral life forms, massive corals were more highly damaged(7.05%) than any other forms. Within a short period of time(May to September), coral coverage shrank to 17.4% from 21.9%, macro-algae increased 23.51% and the average sedimentation rate attained 77.52 mg cm^(-2) d^(-1) with persisting coral reef diseases of 17.59%. The Pearson correlation showed that the coral cover decreased with increasing macro-algae growth, which was statistically significant(r =-0.774, n = 100, P < 0.0005). The proliferation of the various macro-algae C. scalpellifrmis, T. ornata, C. racemosa, T. conaides, U. reticulata, S. wightii, K. alvarezii, P. gymnosphora and C. lentillifera increased with percentages of 6.0, 5.8, 5.7, 4.9, 4.2, 3.7, 2.7 and 1.9, respectively. If this trend continues, the next generation of new recruit corals will undoubtedly lead to a phase shift in Gulf of Mannar corals.
基金Supported by the National Basic Research Program of China (No. 2006CB701400)the National Natural Science Foundation of China (Nos. 40621002,40974035,40272074)Projects of Ministry of Education of China ("111" Project B07011,IRT0546)
文摘Detailed mineral magnetic measurements, integrated with grain-size distribution and X-ray diffraction (XRD) analyses, were made on the marine sediments of Core MD98-2172, retrieved from the Eastern Timor Sea. Values of magnetic susceptibility in this core drop sharply down-core from -3.85 m deep below sediment/water interface and are very low at -5.35 m. However, both XRD and grain-size distribution results show no sudden change in terrigenous input during sedimentation. Mineral magnetic results indicate that the depth of -3.85 m may be an oxic/anoxic boundary. Therefore, the sediments below -3.85 m have been subjected to intense reductive diagenesis, whereas the sediments above -3.85 m are seldom affected. The magnetic properties of the sediments shallower than 3.85 m are dominated by pseudo-single domain (PSD) magnetite, with little down-core variation in its content and grain size. Below -3.85 m, the magnetic mineral assemblages that have survived in the sediments may record different stages of the reductive diagenesis: (1) the sediments from the 3.85-5.35 m interval are at the stage of iron oxide reduction; t'SD magnetite is the major magnetic contributor, but it becomes less abundant and coarser down-core; (2) the sediments below -5.35 m are at the stage of sulphate reduction; ferrimagnetie minerals almost vanish and paramagnetic minerals contribute to down-core susceptibility variations, including pyrite as evidenced by high-temperature magnetic susceptibility measurements. However, the susceptibility variations below -5.35 m of Core MD98-2172 show obvious periodicity, despite the intense effect of reduetive diagenesis. Furthermore, the down-core susceptibility variations are coincident with fluctuations in the quantity of fine detrital particles (〈8 μm), which may come mainly from the advection of the Indonesia Throughflow (ITF) and/or river input from Timor. Therefore, for Core MD98-2172, susceptibility variation below -5.35 m, which potentially correspond to fluctuations in the quantity of fine particles, may record the histories of the development of the ITF and precipitation on Timor.
基金financially supported by the National Basic Research Program of China (Grant No. 2009CB219503)the National Natural Science Foundation of China (Grant No. 41072037)
文摘The P-T stability conditions of gas hydrate in different systems (i.e., solution, silica sand, and marine sediment) were studied using multi-step decomposition method with our experimental equipment. The effects of different ions with various concentra- tions and sediment grains on the P-T stability conditions of gas hydrate were investigated. The results show that different ions have different influences on the phase equilibrium of gas hydrate. However, the influence of ions is in a similar trend: the larg- er the concentration, the bigger the P-T curve shifts to the left. For the silica sand, the influence of pore capillarity of coarse particles (〉 460 ~tm) can be negligible. The P-T curve measured in coarse silica is in agreement with that in pure water. How- ever, the influence of pore capillarity of fine particles (〈 35 μm) is significant. The maximum reduction value of temperature is 1.5 K for methane hydrate under stable state. The sediment from the South China Sea significantly affects the P-T stability conditions of methane hydrate, with an average reduction value of 1.9 K within the experimental conditions. This is mainly the result of both the pore water salinity and the pore capillarity of sediment. Because the pore water salinity is keeping diluted by the fresh water released from hydrate dissociation, the measured P-T stability points fall on different P-T curves with the de- creasing salinity.