Here an electron momentum spectroscopy study on the electronic structure of valence shell of iso-dichloroethylene molecule is reported. The experiment is carried out with a binary (e, 2e) spectrometer at incident elec...Here an electron momentum spectroscopy study on the electronic structure of valence shell of iso-dichloroethylene molecule is reported. The experiment is carried out with a binary (e, 2e) spectrometer at incident electron energy of 1200 eV, employing noncoplanar symmetric arrangement. The binding energy spectra and electron momentum distributions (EMDs) of iso-dichloroethylene valence shell have been obtained. Theoretical EMDs are predicted with both Hartree-Fock and density functional theory methods, generally indicating good agreements with the measurement results. The interference effect is observed to significantly influence the EMDs of 2a2 and 5b2 Cl lone-pair orbitals.展开更多
The Unified S-Band （USB） ranging/Doppler system and the Very Long Baseline Interferometry （VLBI） system as the ground tracking system jointly supported the lunar orbit capture of both Chang＇E-2 （CE-2） and Chang...The Unified S-Band （USB） ranging/Doppler system and the Very Long Baseline Interferometry （VLBI） system as the ground tracking system jointly supported the lunar orbit capture of both Chang＇E-2 （CE-2） and Chang＇E-1 （CE-1） missions. The tracking system is also responsible for providing precise orbits for scientific data processing. New VLBI equipment and data processing strategies have been proposed based on CE-1 experiences and implemented for CE-2. In this work the role VLBI tracking data played was reassessed through precision orbit determination （POD） experiments for CE-2. Significant improve- ment in terms of both VLBI delay and delay rate data accuracy was achieved with the noise level of X-band band-width syn- thesis delay data reaching 0.2-0.3 ns. Short-arc orbit determination experiments showed that the combination of only 15 min＇s range and VLBI data was able to improve the accuracy of 3 h＇s orbit using range data only by a 1-1.5 order of magnitude, confirming a similar conclusion for CE-1. Moreover, because of the accuracy improvement, VLBI data was able to contribute to CE-2＇s long-arc POD especially in the along-track and orbital normal directions. Orbital accuracy was assessed through the orbital overlapping analysis （2 h arc overlapping for 18 h POD arc）. Compared with about 100 m position error of CE-l＇s 200 kin x 200 km lunar orbit, for CE-2＇s 100 km x 100 km lunar orbit, the position errors were better than 31 and 6 m in the radial direction, and for CE-2＇s 15 km^100 km orbit, the position errors were better than 45 and 12 m in the radial direction. In addi- tion, in trying to analyze the Delta Differential One-Way Ranging （ADOR） experiments data we concluded that the accuracy of ADOR delay was dramatically improved with the noise level better than 0.1 ns and systematic errors better calibrated, and the Short-arc POD tests with ADOR data showed excellent results. Although unable to support the development of an independent lunar gravity model, the tracking data of CE-2 provided evaluations of different lunar gravity models through POD. It is found that for the 100 km x 100 km lunar orbit, with a degree and order expansion up to 165, JPL＇s gravity model LP165P did not show noticeable improvement over Japan＇s SGM series models （100x100）, but for the 15 kmxl00 km lunar orbit, a higher de- gree-order model can significantly improve the orbit accuracy.展开更多
Two approximations, center-beam approximation and reference digital elevation model （DEM） approximation, are used in synthetic aperture radar （SAR） motion compensation procedures. They usually introduce residual m...Two approximations, center-beam approximation and reference digital elevation model （DEM） approximation, are used in synthetic aperture radar （SAR） motion compensation procedures. They usually introduce residual motion compensation errors for airborne single-antenna SAR imaging and SAR interferometry. In this paper, we investigate the effects of residual uncompensated motion errors, which are caused by the above two approximations, on the performance of airborne along-track interferometric SAR （ATI-SAR）. The residual uncompensated errors caused by center-beam approximation in the absence and in the presence of elevation errors are derived, respectively. Airborne simulation parameters are used to verify the correctness of the analysis and to show the impacts of residual uncompensated errors on the interferometric phase errors for ATI-SAR. It is shown that the interferometric phase errors caused by the center-beam approximation with an accurate DEM could be neglected, while the interferometric phase errors caused by the center-beam approximation with an inaccurate DEM cannot be neglected when the elevation errors exceed a threshold. This research provides theoretical bases for the error source analysis and signal processing of airborne ATI-SAR.展开更多
基金supported by the National Natural Science Foundation of China (No.11534011)the National Key Research and Development Program of China (No.2017YFA0402300)
文摘Here an electron momentum spectroscopy study on the electronic structure of valence shell of iso-dichloroethylene molecule is reported. The experiment is carried out with a binary (e, 2e) spectrometer at incident electron energy of 1200 eV, employing noncoplanar symmetric arrangement. The binding energy spectra and electron momentum distributions (EMDs) of iso-dichloroethylene valence shell have been obtained. Theoretical EMDs are predicted with both Hartree-Fock and density functional theory methods, generally indicating good agreements with the measurement results. The interference effect is observed to significantly influence the EMDs of 2a2 and 5b2 Cl lone-pair orbitals.
基金supported by the National Natural Science Foundation of China (Grant Nos. 10703011 and11073047)the Science and Technology Commission of Shanghai (GrantNo. 06DZ22101)the National High Technology Research and Development Program of China (Grant No. 2010AA122202)
文摘The Unified S-Band （USB） ranging/Doppler system and the Very Long Baseline Interferometry （VLBI） system as the ground tracking system jointly supported the lunar orbit capture of both Chang＇E-2 （CE-2） and Chang＇E-1 （CE-1） missions. The tracking system is also responsible for providing precise orbits for scientific data processing. New VLBI equipment and data processing strategies have been proposed based on CE-1 experiences and implemented for CE-2. In this work the role VLBI tracking data played was reassessed through precision orbit determination （POD） experiments for CE-2. Significant improve- ment in terms of both VLBI delay and delay rate data accuracy was achieved with the noise level of X-band band-width syn- thesis delay data reaching 0.2-0.3 ns. Short-arc orbit determination experiments showed that the combination of only 15 min＇s range and VLBI data was able to improve the accuracy of 3 h＇s orbit using range data only by a 1-1.5 order of magnitude, confirming a similar conclusion for CE-1. Moreover, because of the accuracy improvement, VLBI data was able to contribute to CE-2＇s long-arc POD especially in the along-track and orbital normal directions. Orbital accuracy was assessed through the orbital overlapping analysis （2 h arc overlapping for 18 h POD arc）. Compared with about 100 m position error of CE-l＇s 200 kin x 200 km lunar orbit, for CE-2＇s 100 km x 100 km lunar orbit, the position errors were better than 31 and 6 m in the radial direction, and for CE-2＇s 15 km^100 km orbit, the position errors were better than 45 and 12 m in the radial direction. In addi- tion, in trying to analyze the Delta Differential One-Way Ranging （ADOR） experiments data we concluded that the accuracy of ADOR delay was dramatically improved with the noise level better than 0.1 ns and systematic errors better calibrated, and the Short-arc POD tests with ADOR data showed excellent results. Although unable to support the development of an independent lunar gravity model, the tracking data of CE-2 provided evaluations of different lunar gravity models through POD. It is found that for the 100 km x 100 km lunar orbit, with a degree and order expansion up to 165, JPL＇s gravity model LP165P did not show noticeable improvement over Japan＇s SGM series models （100x100）, but for the 15 kmxl00 km lunar orbit, a higher de- gree-order model can significantly improve the orbit accuracy.
基金Project supported by the National Natural Science Foundation of China （Nos. 61331017 and 61401428）
文摘Two approximations, center-beam approximation and reference digital elevation model （DEM） approximation, are used in synthetic aperture radar （SAR） motion compensation procedures. They usually introduce residual motion compensation errors for airborne single-antenna SAR imaging and SAR interferometry. In this paper, we investigate the effects of residual uncompensated motion errors, which are caused by the above two approximations, on the performance of airborne along-track interferometric SAR （ATI-SAR）. The residual uncompensated errors caused by center-beam approximation in the absence and in the presence of elevation errors are derived, respectively. Airborne simulation parameters are used to verify the correctness of the analysis and to show the impacts of residual uncompensated errors on the interferometric phase errors for ATI-SAR. It is shown that the interferometric phase errors caused by the center-beam approximation with an accurate DEM could be neglected, while the interferometric phase errors caused by the center-beam approximation with an inaccurate DEM cannot be neglected when the elevation errors exceed a threshold. This research provides theoretical bases for the error source analysis and signal processing of airborne ATI-SAR.
