Neodymium dialkylthiophosphate （NdDDP） with alkyls of isopropyl and isooctyl were synthesized by exchanged reaction respectively. The structures of the two NdDDPs were determined using IR and XRD. Properties of anti...Neodymium dialkylthiophosphate （NdDDP） with alkyls of isopropyl and isooctyl were synthesized by exchanged reaction respectively. The structures of the two NdDDPs were determined using IR and XRD. Properties of anti-wear and friction-reducing of the two additives were investigated with four ball experiment and the commercial anti-wear additive ZDDP was selected as control. The elemental analysis of the wear scars after 10 s friction at low stress were investigated by EDXA （Energy Dispersion Analysis of X-ray）. Primary results showed that the NdDDPs possess better lubrication ability than ZDDP. This might mainly be contributed to the formation of a boundary film containing Nd2O3, FeS and sulphate, phosphate, organo-sulfide, etc., and a neodymium-rich diffused layer which changes the crystal structure of the surface of friction materials.展开更多
A new kind of friction-reducing and repairing additive containing nano-scale copper and rare earth compounds were prepared by means of synthesis and compounding methods. The performance of the said additive was invest...A new kind of friction-reducing and repairing additive containing nano-scale copper and rare earth compounds were prepared by means of synthesis and compounding methods. The performance of the said additive was investigated by engine bench test, and was compared to the performance of similar domestic and imported additives. The deterioration of lube oils containing additives over different time intervals was studied by means of plasma spectrometry and mass spectrometry, and the effect of additive package on engine power was also studied. Test results have revealed that the synthetic additive package can provide good anti-wear performance to the tribo-pairs. In particular, after 300 hour application of the said additive package the connection rod shaft and copper sleeve showed 'zero wear' to achieve the in situ dynamic repairing of tribo-pairs. Application of the said synthetic additive can effectively improve the engine power performance and extend the engine service life.展开更多
文摘Neodymium dialkylthiophosphate （NdDDP） with alkyls of isopropyl and isooctyl were synthesized by exchanged reaction respectively. The structures of the two NdDDPs were determined using IR and XRD. Properties of anti-wear and friction-reducing of the two additives were investigated with four ball experiment and the commercial anti-wear additive ZDDP was selected as control. The elemental analysis of the wear scars after 10 s friction at low stress were investigated by EDXA （Energy Dispersion Analysis of X-ray）. Primary results showed that the NdDDPs possess better lubrication ability than ZDDP. This might mainly be contributed to the formation of a boundary film containing Nd2O3, FeS and sulphate, phosphate, organo-sulfide, etc., and a neodymium-rich diffused layer which changes the crystal structure of the surface of friction materials.
文摘A new kind of friction-reducing and repairing additive containing nano-scale copper and rare earth compounds were prepared by means of synthesis and compounding methods. The performance of the said additive was investigated by engine bench test, and was compared to the performance of similar domestic and imported additives. The deterioration of lube oils containing additives over different time intervals was studied by means of plasma spectrometry and mass spectrometry, and the effect of additive package on engine power was also studied. Test results have revealed that the synthetic additive package can provide good anti-wear performance to the tribo-pairs. In particular, after 300 hour application of the said additive package the connection rod shaft and copper sleeve showed 'zero wear' to achieve the in situ dynamic repairing of tribo-pairs. Application of the said synthetic additive can effectively improve the engine power performance and extend the engine service life.
