During the exploitation of offshore oil and gas,it is easy to form severe slugging which can cause great harm in the riser connecting wellheads and offshore platform preprocessing system.The flow pattern and pressure ...During the exploitation of offshore oil and gas,it is easy to form severe slugging which can cause great harm in the riser connecting wellheads and offshore platform preprocessing system.The flow pattern and pressure fluctuation of severe slugging were studied in an experimental simulation system with inner diameter of 0.051 m.It is found that severe slugging can be divided into three severe slugging regimes：regime I at low gas and liquid flow rates with large pressure fluctuation,intermittent flow of liquid and gas in the riser,and apparent cutoff of liquid phase,regime II at high gas flow rate with non-periodic fluctuation and discontinuous liquid outflow and no gas cutoff,regime III at high liquid flow rate with degenerative pressure fluctuation in form of relatively stable bubbly or plug flow.The results indicate that severe slugging still occurs when the declination angle of pipeline is 0,and there are mainly two kinds of regimes：regime I and regime II.As the angle increases,the formation ranges of regime I and regime III increase slightly while that of regime II is not affected.With the increase of gas superficial velocity and liquid superficial velocity,the pressure fluctuation at the bottom of riser increases initially and then decreases.The maximum value of pressure fluctuation occurs at the transition boundary of regimes I and II.展开更多
Recently ionic liquids(ILs) are introduced as novel dual function gas hydrate inhibitors. However, no desired gas hydrate inhibition has been reported due to poor IL selection and/or tuning method. Trial & error a...Recently ionic liquids(ILs) are introduced as novel dual function gas hydrate inhibitors. However, no desired gas hydrate inhibition has been reported due to poor IL selection and/or tuning method. Trial & error as well as selection based on existing literature are the methods currently employed for selecting and/or tuning ILs. These methods are probabilistic, time consuming, expensive and may not result in selecting high performance ILs for gas hydrate mitigation. In this work, COSMO-RS is considered as a prescreening tool of ILs for gas hydrate mitigation by predicting the hydrogen bonding energies(E_(HB)) of studied IL inhibitors and comparing the predicted E_(HB) to the depression temperature(?) and induction time. Results show that, predicted EHBand chain length of ILs strongly relate and significantly affect the gas hydrate inhibition depression temperature but correlate moderately(R = 0.70) with average induction time in literature. It is deduced from the results that, ? increases with increasing IL EHBand/or decreases with increasing chain length. However, the cation–anion pairing of ILs also affects IL gas hydrate inhibition performance. Furthermore, a visual and better understanding of IL/water behavior for gas hydrate inhibition in terms of hydrogen bond donor and acceptor interaction analysis is also presented by determining the sigma profile and sigma potential of studied IL cations and anions used for gas hydrate mitigation for easy IL selection.展开更多
A design method for a kerosene fuel-rich gas-generator of a liquid rocket engine using turbopumps to supply propellant was performed at a conceptual level. The gas-generator creates hot gases, enabling the turbine to ...A design method for a kerosene fuel-rich gas-generator of a liquid rocket engine using turbopumps to supply propellant was performed at a conceptual level. The gas-generator creates hot gases, enabling the turbine to operate the turbopumps. A chemical non-equilibrium analysis and a droplet vaporization model were used for the estimation of the burnt gas properties and characteristic chamber length. A premixed counter-flow flame analysis was performed for the prediction of the burnt gas properties, namely the temperature, the specific heat ratio and heat capacity, and the chemical reaction time. To predict the vaporization time, the Spalding model, using a single droplet in convective condition, was used. The minimum residence time in the chamber and the characteristic length were calculated by adding the reaction time and the vaporization time. Using the characteristic length, the design methods for the fuel-rich gas-generator were established. Finally, a parametric study was achieved for the effects of the O/F ratio, mass flow rate, chamber pressure, initial droplet temperature, initial droplet diameter and initial droplet velocity.展开更多
基金Supported by the National High Technology Research and Development Program of China(2006AA09Z302)
文摘During the exploitation of offshore oil and gas,it is easy to form severe slugging which can cause great harm in the riser connecting wellheads and offshore platform preprocessing system.The flow pattern and pressure fluctuation of severe slugging were studied in an experimental simulation system with inner diameter of 0.051 m.It is found that severe slugging can be divided into three severe slugging regimes：regime I at low gas and liquid flow rates with large pressure fluctuation,intermittent flow of liquid and gas in the riser,and apparent cutoff of liquid phase,regime II at high gas flow rate with non-periodic fluctuation and discontinuous liquid outflow and no gas cutoff,regime III at high liquid flow rate with degenerative pressure fluctuation in form of relatively stable bubbly or plug flow.The results indicate that severe slugging still occurs when the declination angle of pipeline is 0,and there are mainly two kinds of regimes：regime I and regime II.As the angle increases,the formation ranges of regime I and regime III increase slightly while that of regime II is not affected.With the increase of gas superficial velocity and liquid superficial velocity,the pressure fluctuation at the bottom of riser increases initially and then decreases.The maximum value of pressure fluctuation occurs at the transition boundary of regimes I and II.
文摘Recently ionic liquids(ILs) are introduced as novel dual function gas hydrate inhibitors. However, no desired gas hydrate inhibition has been reported due to poor IL selection and/or tuning method. Trial & error as well as selection based on existing literature are the methods currently employed for selecting and/or tuning ILs. These methods are probabilistic, time consuming, expensive and may not result in selecting high performance ILs for gas hydrate mitigation. In this work, COSMO-RS is considered as a prescreening tool of ILs for gas hydrate mitigation by predicting the hydrogen bonding energies(E_(HB)) of studied IL inhibitors and comparing the predicted E_(HB) to the depression temperature(?) and induction time. Results show that, predicted EHBand chain length of ILs strongly relate and significantly affect the gas hydrate inhibition depression temperature but correlate moderately(R = 0.70) with average induction time in literature. It is deduced from the results that, ? increases with increasing IL EHBand/or decreases with increasing chain length. However, the cation–anion pairing of ILs also affects IL gas hydrate inhibition performance. Furthermore, a visual and better understanding of IL/water behavior for gas hydrate inhibition in terms of hydrogen bond donor and acceptor interaction analysis is also presented by determining the sigma profile and sigma potential of studied IL cations and anions used for gas hydrate mitigation for easy IL selection.
基金supported by the Output-oriented Project of the Collaborative Research Program with the Higher Education Partners of the Korea Aerospace Research Institute in 2009
文摘A design method for a kerosene fuel-rich gas-generator of a liquid rocket engine using turbopumps to supply propellant was performed at a conceptual level. The gas-generator creates hot gases, enabling the turbine to operate the turbopumps. A chemical non-equilibrium analysis and a droplet vaporization model were used for the estimation of the burnt gas properties and characteristic chamber length. A premixed counter-flow flame analysis was performed for the prediction of the burnt gas properties, namely the temperature, the specific heat ratio and heat capacity, and the chemical reaction time. To predict the vaporization time, the Spalding model, using a single droplet in convective condition, was used. The minimum residence time in the chamber and the characteristic length were calculated by adding the reaction time and the vaporization time. Using the characteristic length, the design methods for the fuel-rich gas-generator were established. Finally, a parametric study was achieved for the effects of the O/F ratio, mass flow rate, chamber pressure, initial droplet temperature, initial droplet diameter and initial droplet velocity.
