In this paper, pyrolysis of Indonesian oil sands （lOS） was investigated by two different heating methods to develop a better understanding of the microwave-assisted pyrolysis. Thermogravimetric analysis was conducte...In this paper, pyrolysis of Indonesian oil sands （lOS） was investigated by two different heating methods to develop a better understanding of the microwave-assisted pyrolysis. Thermogravimetric analysis was conducted to study the thermal decomposition behaviors of lOS, showing that 550 ℃ might be the pyrolysis final temperature. A explanation of the heat-mass transfer process was presented to demonstrate the influence of mi- crowave-assisted pyrolysis on the liquid product distribution. The heat-mass transfer model was also useful to explain the increase of liquid product yield and heavy component content at the same heating rate by two differ- ent heating methods. Experiments were carried out using a fixed bed reactor with and without the microwave irradiation. The results showed that liquid product yield was increased during microwave induced pyrolysis, while the formation of gas and solid residue was reduced in comparison with the conventional pyrolysis. Moreover, the liquid product characterization by elemental analysis and GC-MS indicated the significant effect on the liquid chemical composition by microwave irradiation. High polarity substances （ε 〉 10 at 25 ℃）, such as oxy- organics were increased, while relatively low polarity substances （ε 〈 2 at 25℃）, such as aliphatic hydrocarbons were decreased, suggesting that microwave enhanced the relative volatility of high polarity substances. The yield improvement and compositional variations in the liquid product promoted by the microwave-assisted pyrolysis deserve the further exploitation in the future,展开更多
Ulsan port is the hugest industry-oriented port in South Korea. It has the third highest traffic volume of cargo, and also it has the most liquid bulk in Korea. However, on account of thoughtless development, there ar...Ulsan port is the hugest industry-oriented port in South Korea. It has the third highest traffic volume of cargo, and also it has the most liquid bulk in Korea. However, on account of thoughtless development, there are other cases like Ulsan port that liquid cargo and general cargo are simultaneously handled. The demurrage ratio takes up to 12.5% of probability on average. In 2010, it has less room at berths for liquid bulk than general cargo and it totally has 107% of processing ratio （throughput）. This indicates that Ulsan port concentrates on liquid cargo more than general cargo depending on the characteristics of the port. This research suggests the effects as alternatives for efficiency and effectivity at both ports, Ulsan port and Pohang port in the case that the general cargo handled in Ulsan port is relocated to Pohang port in terms of the characteristics of products which Pohang port and its hinterland the most focused on. Namely, we estimate volume of relocated volume suitable for relocation in assumption that volume handled in Ulsan port is relocated to Pohang port scenario by scenario, analyze the effects of relocated volume, and suggest alternatives for vitalizing Ulsan port.展开更多
基金Supported by the National Key Research and Development Program of China(2016YFB0301800)the partial support by The Royal Society International Exchange Award(IE161344)the State Scholarship Fund of China Scholarship Council(CSC)(201706255020)
文摘In this paper, pyrolysis of Indonesian oil sands （lOS） was investigated by two different heating methods to develop a better understanding of the microwave-assisted pyrolysis. Thermogravimetric analysis was conducted to study the thermal decomposition behaviors of lOS, showing that 550 ℃ might be the pyrolysis final temperature. A explanation of the heat-mass transfer process was presented to demonstrate the influence of mi- crowave-assisted pyrolysis on the liquid product distribution. The heat-mass transfer model was also useful to explain the increase of liquid product yield and heavy component content at the same heating rate by two differ- ent heating methods. Experiments were carried out using a fixed bed reactor with and without the microwave irradiation. The results showed that liquid product yield was increased during microwave induced pyrolysis, while the formation of gas and solid residue was reduced in comparison with the conventional pyrolysis. Moreover, the liquid product characterization by elemental analysis and GC-MS indicated the significant effect on the liquid chemical composition by microwave irradiation. High polarity substances （ε 〉 10 at 25 ℃）, such as oxy- organics were increased, while relatively low polarity substances （ε 〈 2 at 25℃）, such as aliphatic hydrocarbons were decreased, suggesting that microwave enhanced the relative volatility of high polarity substances. The yield improvement and compositional variations in the liquid product promoted by the microwave-assisted pyrolysis deserve the further exploitation in the future,
文摘Ulsan port is the hugest industry-oriented port in South Korea. It has the third highest traffic volume of cargo, and also it has the most liquid bulk in Korea. However, on account of thoughtless development, there are other cases like Ulsan port that liquid cargo and general cargo are simultaneously handled. The demurrage ratio takes up to 12.5% of probability on average. In 2010, it has less room at berths for liquid bulk than general cargo and it totally has 107% of processing ratio （throughput）. This indicates that Ulsan port concentrates on liquid cargo more than general cargo depending on the characteristics of the port. This research suggests the effects as alternatives for efficiency and effectivity at both ports, Ulsan port and Pohang port in the case that the general cargo handled in Ulsan port is relocated to Pohang port in terms of the characteristics of products which Pohang port and its hinterland the most focused on. Namely, we estimate volume of relocated volume suitable for relocation in assumption that volume handled in Ulsan port is relocated to Pohang port scenario by scenario, analyze the effects of relocated volume, and suggest alternatives for vitalizing Ulsan port.
