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谷氨酸结晶中的细晶回用工艺 被引量:2
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作者 李小明 张建华 +1 位作者 张宏建 毛忠贵 《化学工程》 CAS CSCD 北大核心 2014年第6期38-42,共5页
谷氨酸工业结晶过程中会产生大量难以分离回收的细晶,影响收率和产品质量。文中提出了结晶-粒径切割沉降-细晶回用的工艺设想,将不同粒径的晶体分步分离,细晶浓缩后作为晶种回用至结晶过程。使用扫描电镜和粉末X-衍射(PXRD)研究细晶的... 谷氨酸工业结晶过程中会产生大量难以分离回收的细晶,影响收率和产品质量。文中提出了结晶-粒径切割沉降-细晶回用的工艺设想,将不同粒径的晶体分步分离,细晶浓缩后作为晶种回用至结晶过程。使用扫描电镜和粉末X-衍射(PXRD)研究细晶的晶习及其作为晶种回用的可行性,进行不同条件下的分批等电结晶,参考结晶速率、聚结度、CSD等参数确定细晶回用量、适用过饱和度范围等回用条件。结果表明:液体细晶表观为非典型四方六面体,但在谷氨酸结晶中晶面具有自我修复能力;过饱和度和细晶回用量均影响结晶过程,液体细晶的最适过饱和度范围为1-3;在过饱和度S=2时液体细晶的最适回用量(质量分数)为1%,在S=3时最适回用量为3%。最终证明通过控制合适的晶体生长环境,细晶回用的谷氨酸结晶工艺是可行的。 展开更多
关键词 谷氨酸结 液体细晶 分布分离 种回用 过饱和度
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Relationship between solid/liquid interface and crystal orientation for pure magnesium solidified in fashion of cellular crystal 被引量:2
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作者 常国威 陈淑英 +2 位作者 周聪 岳旭东 齐义辉 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第2期289-293,共5页
The relationship between the solid/liquid interface and the crystal orientation for pure magnesium,which grows in fashion of cellular crystal in unidirectional solidification,was investigated.The results show that the... The relationship between the solid/liquid interface and the crystal orientation for pure magnesium,which grows in fashion of cellular crystal in unidirectional solidification,was investigated.The results show that the energy of the solid/liquid interface is the lowest during cellular crystal growth of pure magnesium;and the solid/liquid interface is covered by the basal face{0001}and by the crystal face made up of three atoms located at the orientation{0001}0100and two atoms located at the inner of magnesium crystal cell.The strongest bond is formed in the direction of 61.9°viating from the growth direction,and the second strong bond is formed in the directions of 8.5°d 47.7°espectively,deviating from the growth direction.The angle between the basal face{0001} and the growth direction is 61.9°he theoretical analysis results are basically consistent with the experimental results from SUSUMU et al. 展开更多
关键词 magnesium solidification process crystal growth crystal orientation
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