LNG超低温设备密封件的结构及试验方法

通过对超低温密封产品结构的设计和密封材料进行改性,研究出一种可靠的密封件,通过液氮深冷到-196°C,用氦气作为密封介质,按照英国低温阀门标准BS 6364 1984中的实验步骤来验证密封结构的合理性,并进行优化。经优化验证,密封结构设计合理,材料物理性能优越,可以推广应用到LNG超低温设备中,弥补了国内在超低温设备密封上的难点。

Process Intensification of VOC Removal from High Viscous Media by Rotating Packed Bed

The removal of a volatile organic compound (VOC) from high viscous liquid was carried out in a rotat-ing packed bed (RPB) in this study. The mixed liquid of syrup and acetone was used as simulated high viscous polymer solution with acetone as the volatile compound. The influence of the rotating speed of RPB, liquid viscos-ity, liquid flow rate, vacuum degree, and initial acetone content in the liquid on acetone removal efficiency was in-vestigated. The experimental results indicated that the removal efficiency increased with increasing rotating speed and initial acetone content in the viscous liquid and decreased with increasing liquid viscosity and flow rate. It was also observed that acetone removal efficiency increased with an increasing vacuum degree and reached 58% at a vacuum degree of 0.1 MPa. By the comparison with a flash tank devolatilizer, it was found that acetone removal ef-ficiency in RPB increased by about 67%.

Dispersion and Stability of Physical Sunscreen Agents in Liquid Medium

The dispersion processes and methods of physical sun-screening agents in liquid medium were briefed.Several stabilizing mechanisms of ultrafine particle in liquid medium was introduced, and the stabilizing mechanisms of physical sunscreens were discussed. At last, the currently existing evaluation methods of physical sun-screening slurry stability were also illustrated.

Syntheses of Coumarins in Environmentally Friendly Ionics Liquids

Syntheses of 3-substituted coumarins by the condensation reaction of salicylaldehyde with activated methylene compounds （ethyl cyanoacetate, malonic acid） are discussed in media of ionic liquids--（2-hydroxyethyl）ammonium carboxylates （formates, acetates, lactates） without utilization of any other catalysts. The dependence of yields of the reaction product is investigated on the structure of ionic liquids （their cations, anions, total polarity and pseudo-pH values）. 3-Substituted coumarins are prepared in high yields in media of these environmentally friendly ionic liquids which serve simultaneously as reaction media and as catalysts. The mentioned ionic liquids are prepared by reactions of corresponding hydroxyethyl-amines with carboxylic acids, and their quantitative analyses being made by potentiometric titration of ionic liquids with perchloric acid in 100% acetic acid.

One-pot three-component synthesis of tetrahydrobenzo[b]pyrans catalyzed by cost-effective ionic liquid in aqueous medium

A simple and ef ficient method is proposed for the synthesis of tetrahydrobenzo[b]pyrans with aromatic aldehydes, active methylene compounds, and dimedone using basic ionic liquid catalyst in water. The procedure offers several advantages including short reaction time, good yield, easy procedure, and good recyclability of catalysts, which may be a practical alternative to conventional processes for preparation of 4-hpyrans.

Obtaining Sulfur Nanoparticles from Sodium Polysulfide Aqueous Solution

This paper thoroughly studies the＇. process of obtaining sulfur nanoparticles in aqueous medium from sodium polysulfide. Nanosize sulfur particles with orthorhombic structure were obtained at room temperature by mixing sodium polysulfide aqueous solution with various inorganic and organic acids. Sulfur nanoparticles were characterized by laser particle-size analyzer, X-ray diffraction, electron probe microscopy. Size of sulfur nanoparticles in aqueous dispersion is affected ;trongly by acid concentration, as well as nature of alcohols, used as wetting agents when measuring sulfur particles size iin aqueous medium. Availability of obtaining sulfur nanoparticles of 22-25 nm average si;,e in aqueous medium was revealed. High biological activity of sulfur nanoparticles and ethylalcohol composition on wheat grain couching was established.

Stripping of uranium from an ionic liquid medium by TOPO-modified supercritical carbon dioxide

UO2＋, which is extracted from the aqueous phase into the 1-ethyl-3-methylimidazolium bis（trifluoromethylsulfonyl）imide（C2mim NTf2） ionic liquid ph^ase with octyl（phenyl）-N,N-diisobutylcarbamoylmethylphosphine oxide（CMPO）, can be stripped by supercritical CO2. Trioctylphosphine oxide（TOPO）, the modifier added to the supercritical CO2 phase, enhances the stripping efficiency by up to 99%.

Conversion of bimetallic MOF to Ru-doped Cu electrocatalysts for efficient hydrogen evolution in alkaline media

The rational design and construction of inexpensive and highly active electrocatalysts for hydrogen evolution reaction(HER)is of great importance for water splitting.Herein,we develop a facile approach for preparation of porous carbon-confined Ru-doped Cu nanoparticles(denoted as Ru-Cu@C)by direct pyrolysis of the Ru-exchanged Cu-BTC metal–organic framework.When served as the electrocatalyst for HER,strikingly,the obtained Ru-Cu@C catalyst exhibits an ultralow overpotential(only 20 mV at 10 mA cm^(-2))with a small Tafel slope of 37 m V dec^(-1)in alkaline electrolyte.The excellent performance is comparable or even superior to that of commercial Pt/C catalyst.Density functional theory(DFT)calculations confirm that introducing Ru atoms into Cu nanocrystals can significantly alter the desorption of H_(2) to achieve a close-to-zero hydrogen adsorption energy and thereby boost the HER process.This strategy gives a fresh impetus to explore low-cost and high-performance catalysts for HER in alkaline media.