The complex {[Cd2(C9H8O3N)2(CH3COO)2(4,4'-bipy)2]·(4,4'-bipy)·(H2O)4}n with 4-acetamidobenzoic acid and 4,4'-bipyridine has been synthesized with liquid diffusion method and characterized. It cry...The complex {[Cd2(C9H8O3N)2(CH3COO)2(4,4'-bipy)2]·(4,4'-bipy)·(H2O)4}n with 4-acetamidobenzoic acid and 4,4'-bipyridine has been synthesized with liquid diffusion method and characterized. It crystallizes in the monoclinic space group C2/c. The crystal structure shows that two neighboring cadmium(Ⅱ) ions are linked together by two bridging acetic acid radicals,forming a binuclear structure. Adjacent binnuclear structure is linked together by two bridging 4,4'-bipy molecules and the complex molecule forms an one-dimensional doublechain structure. The luminescent properties of the complex were studied.展开更多
文摘The complex {[Cd2(C9H8O3N)2(CH3COO)2(4,4'-bipy)2]·(4,4'-bipy)·(H2O)4}n with 4-acetamidobenzoic acid and 4,4'-bipyridine has been synthesized with liquid diffusion method and characterized. It crystallizes in the monoclinic space group C2/c. The crystal structure shows that two neighboring cadmium(Ⅱ) ions are linked together by two bridging acetic acid radicals,forming a binuclear structure. Adjacent binnuclear structure is linked together by two bridging 4,4'-bipy molecules and the complex molecule forms an one-dimensional doublechain structure. The luminescent properties of the complex were studied.
