We demonstrate a new kind of multi-core photonic liquid crystal fibers (PLCFs) which have six liquid crystal cores arrayed in the ring-type geometry and separated by the air holes. Through analyzing the structure of t...We demonstrate a new kind of multi-core photonic liquid crystal fibers (PLCFs) which have six liquid crystal cores arrayed in the ring-type geometry and separated by the air holes. Through analyzing the structure of this kind of PLCFs, it can be found that they have the ability to resist the structure deformation. Due to the effective index of the liquid crystal can be adjusted by temperature and wavelength, the energy in the six liquid crystal cores is increased with the temperature increasing and wavelength decreasing. The effective index of the PLCFs is decreased, the effective fundamental mode area is increased and the dispersion properties are gently affected with the wavelength increasing and temperature decreasing.展开更多
We experimentally studied the catalytic performances of a series of Brrnsted-Lewis acidic N-methyl-2-pyrrolidonium metal chlorides （[Hnmp]Cl/MClx, where M=Fe, Zn, A1, or Cu） for the hydrolysis of microcrystalline ce...We experimentally studied the catalytic performances of a series of Brrnsted-Lewis acidic N-methyl-2-pyrrolidonium metal chlorides （[Hnmp]Cl/MClx, where M=Fe, Zn, A1, or Cu） for the hydrolysis of microcrystalline cellulose （MCC） and cotton to produce reducing sugar. A variety of factors, such as temperature, time, ionic liquid （IL） species, IL dosage, and the concentra- tion of the metal chloride were investigated. [Hnmp]Cl/FeCl3 presented the best hydrolysis performance, affording a 98.8% yield of total reducing sugar from MCC （1 h, 100 ℃, 0.1 g MCC, 0.2 g acidic IL, 2.0 g [Bmim]Cl as solvent）, which is better than or comparable to results previously obtained with other -SO3H functionalized acidic ILs. The hydrolysis performances of [Hnmp]Cl/MClx were rationalized using density functional theory calculations, which indicated that interactions between the metal chlorides and the cellulose, including charge-transfer interactions are important in the hydrolysis of cellulose and degra- dation of glucose. This work shows that Bronsted-Lewis acidic ILs are potential catalysts for the hydrolysis of cellulose to produce sugar.展开更多
基金supported by the National Natural Science Foundation of China (Nos.61077047 and 61107059)the Natural Science Foundation of Heilongjiang Province (No.A200914)the Research Fund for the Doctoral Program of Higher Education of China (No.200802171034)
文摘We demonstrate a new kind of multi-core photonic liquid crystal fibers (PLCFs) which have six liquid crystal cores arrayed in the ring-type geometry and separated by the air holes. Through analyzing the structure of this kind of PLCFs, it can be found that they have the ability to resist the structure deformation. Due to the effective index of the liquid crystal can be adjusted by temperature and wavelength, the energy in the six liquid crystal cores is increased with the temperature increasing and wavelength decreasing. The effective index of the PLCFs is decreased, the effective fundamental mode area is increased and the dispersion properties are gently affected with the wavelength increasing and temperature decreasing.
基金supported by the National Natural Science Foundation of China (21176021, 21276020)Fundamental Research Funds for the Central Universities (YS1401)+1 种基金the National High Technology Research and Development Program of China (2012AA- 101803)the Deanship of Scientific Research at King Saud University for funding the work through the research group project (RG-1436-026)
文摘We experimentally studied the catalytic performances of a series of Brrnsted-Lewis acidic N-methyl-2-pyrrolidonium metal chlorides （[Hnmp]Cl/MClx, where M=Fe, Zn, A1, or Cu） for the hydrolysis of microcrystalline cellulose （MCC） and cotton to produce reducing sugar. A variety of factors, such as temperature, time, ionic liquid （IL） species, IL dosage, and the concentra- tion of the metal chloride were investigated. [Hnmp]Cl/FeCl3 presented the best hydrolysis performance, affording a 98.8% yield of total reducing sugar from MCC （1 h, 100 ℃, 0.1 g MCC, 0.2 g acidic IL, 2.0 g [Bmim]Cl as solvent）, which is better than or comparable to results previously obtained with other -SO3H functionalized acidic ILs. The hydrolysis performances of [Hnmp]Cl/MClx were rationalized using density functional theory calculations, which indicated that interactions between the metal chlorides and the cellulose, including charge-transfer interactions are important in the hydrolysis of cellulose and degra- dation of glucose. This work shows that Bronsted-Lewis acidic ILs are potential catalysts for the hydrolysis of cellulose to produce sugar.
