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含钙和锶重晶石在水中溶解时液相组分的演化
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作者 朱义年 Ingrid Stober Kurt Bucher 《桂林工学院学报》 2003年第1期31-35,共5页
通过实验研究了常温下天然的含钙和锶重晶石在水中溶解时,水溶液中化学组分随时间的演化.(Ba,Sr,Ca)SO4固溶体在水中发生不一致性溶解,导致固相逐渐富集较难溶的组分(BaSO4),而液相则向着富集较易溶组分(SrSO4和CaSO4)的方向变化.Ba2+,S... 通过实验研究了常温下天然的含钙和锶重晶石在水中溶解时,水溶液中化学组分随时间的演化.(Ba,Sr,Ca)SO4固溶体在水中发生不一致性溶解,导致固相逐渐富集较难溶的组分(BaSO4),而液相则向着富集较易溶组分(SrSO4和CaSO4)的方向变化.Ba2+,Sr2+和Ca2+从固相进入液相的速度顺序为Ba2+<Sr2+<Ca2+.实验测得的溶液中的SO2-4浓度明显低于Ba2+,Sr2+和Ca2+的总浓度(mol/L).固溶体-水溶液体系中的反应路径与天然重晶石矿物中气液包裹体组分、所用固体样品的粒度等相关.水溶液中Ca2+和Sr2+的相对含量随重晶石样品的粒度的减小而升高. 展开更多
关键词 重晶石 化学组分 固溶体 液相演化 气液包裹体 粒度
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Multi-objective optimization of p-xylene oxidation process using an improved self-adaptive differential evolution algorithm 被引量:1
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作者 Lili Tao Bin Xu +1 位作者 Zhihua Hu Weimin Zhong 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第8期983-991,共9页
The rise in the use of global polyester fiber contributed to strong demand of the Terephthalic acid (TPA). The liquid-phase catalytic oxidation of p-xylene (PX) to TPA is regarded as a critical and efficient chemi... The rise in the use of global polyester fiber contributed to strong demand of the Terephthalic acid (TPA). The liquid-phase catalytic oxidation of p-xylene (PX) to TPA is regarded as a critical and efficient chemical process in industry [ 1 ]. PX oxidation reaction involves many complex side reactions, among which acetic acid combustion and PX combustion are the most important. As the target product of this oxidation process, the quality and yield of TPA are of great concern. However, the improvement of the qualified product yield can bring about the high energy consumption, which means that the economic objectives of this process cannot be achieved simulta- neously because the two objectives are in conflict with each other. In this paper, an improved self-adaptive multi-objective differential evolution algorithm was proposed to handle the multi-objective optimization prob- lems. The immune concept is introduced to the self-adaptive multi-objective differential evolution algorithm (SADE) to strengthen the local search ability and optimization accuracy. The proposed algorithm is successfully tested on several benchmark test problems, and the performance measures such as convergence and divergence metrics are calculated. Subsequently, the multi-objective optimization of an industrial PX oxidation process is carried out using the proposed immune self-adaptive multi-objective differential evolution algorithm (ISADE). Optimization results indicate that application oflSADE can greatly improve the yield of TPA with low combustion loss without degenerating TA quality. 展开更多
关键词 p-Xylene oxidation Operation condition optimization Multi-objective optimization Self-adaptive differential evolution
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