重差分相式液膜法提取Cu^(2+)

采用重差分相液膜(GSPLM)分离技术,以P204为载体,H2SO4为反萃剂,对初始浓度为552mg/LCu2+水溶液提取4次后,其浓度降至101mg/L,反萃相中Cu2+浓度达980mg/L,整个过程不需要制乳和破乳。

重差分相液膜分离技术

报道了一种新的液膜分离方法 ,实践证明它具有液膜分离的优点 .克服了要求乳状液既稳定又容易破乳这一对难于调和的矛盾 ,去掉了制乳与破乳过程 ,使工艺简化并显著地节省能耗 .

L-苯丙氨酸在密度差分相液膜中的传输

采用密度差分相液膜技术,以二(2 乙基己基)磷酸(P204)为载体,研究了L 苯丙氨酸(L phe)在密度差分相液膜中的传输.考察了表面活性剂质量分数、载体质量分数、初始料液酸度、油相与料液水相两相密度差、反萃液水相与油相两相密度差对L phe迁移率的影响,实验结果表明:密度差分相液膜对L phe有显著的迁移富集作用,在最佳传质条件下,L phe从料液水相向油相的迁移率接近100%,从油相向反萃液水相的迁移率达90 4%.

液膜法处理含酚废水

用柴油为液膜相制备液膜体系,进行液膜法处理含酚废水的实验研究。测定搅拌强度、乳状液组成、乳状波用量等对结果的影响。用液膜法对工业含酚废水进行净化,结果满意。

声发射在密封监测领域的研究进展

将声发射无损检测技术应用到机械密封监测中是密封领域新的发展方向。从实验研究和理论研究两方面综述声发射在密封领域的研究进展;从早期的实验探索到后期的信号降噪、信号分析和信号识别等方面总结各阶段的研究成果,并且介绍机械密封相变实验研究;展望基于声发射的机械密封监测技术的未来发展方向,如将大数据技术应用到声发射信号的处理分析,探索声发射技术在机械密封不同方向监测的应用,如液膜相变的监测等。

Role of tensile forces in hot tearing formation of cast Al-Si alloy

The instrumented applied rod casting apparatus （ARCA） was developed to investigate the effects of tensile forces in the hot tearing formation of cast AI-Si alloys. The obtained data of tensile forces/temperature was used to identify hot tearing initiation and propagation and the fracture surface of samples was also investigated. The result shows that the applied tensile forces have a complex effect on load onset for the hot tearing initiation and propagation. During the casting solidification, the tensile forces are gradually increased with the increase of solid fraction. Under the action of tensile forces, there will appear hot tearing and crack propagation on the surface of the sample. When the tensile forces exceed the inherent strength of alloys, there will be fractures on the sample. As for the A356 alloy, the critical fracture stress is about 0.1 MPa. The hot tearing surface morphology shows that the remaining intergranular bridge and liquid films are thick enough to allow the formation of dendrite-tip bumps on the fracture surface.

Preparation of TiO_2/ITO film by liquid phase deposition and its photoelectrocatalytic activity for degradation of 4-aminoantipyrine

A thin layer of TiO2 film was deposited on ITO surface via the liquid phase deposition （LPD） process. The photocurrent and electrochemical impedance spectroscopy （EIS） measurements indicated that the as-prepared LPD TiO2/ITO film had an excellent photoelectrochemical performance, which showed a sensitive and rapid response to the UV irradiation. The photogenerated electron-hole pairs could be effectively separated by applying an external bias to the TiO2 film electrode. The LPD TiO2/ITO film was employed to study the photoelectrocatalytic （PEC） degradation of 4-aminoantipyrine. Compared with other techniques, the PEC technique based on such a LPD film electrode had a synergetic effect for 4-aminoantipyrine degradation. When the applied bias potential was＋0.8 V and the supporting electrolyte concentration of Na2SO4 was 0.1 mol/L, the highest degradation efficiency within 120 min could reach 95%for 0.1 mmol/L 4-aminoantipyrine solution at pH 2.0.

提高油气润滑使用效果的措施

介绍了油气润滑的组成、原理及优缺点 。

Liquid Film Characteristics on Surface of Structured Packing

Structured packing is a good candidate for CO2 capture process because of its higher mass transfer efficiency and lower pressure drop. Now, the challenging problem of CO2 capture and storage demands more and more efficiency equipment. The aim of the present study is to investigate the liquid film characteristics under counter current gas phase and throw some insight into the enhancing mechanism of mass transfer performance in structured packing. A high speed digital camera, non-intrusive measurement technique, was used. Water and air were working fluids. Experiments were carried out for different gas/liquid flow rates and different inclination angles. The time-average and instantaneous film widths for each set of flow parameters were calculated. It is shown that the effects of gas phase could be neglected for lower flow rate, and then, become more pronounced at higher flow rate. According to instantaneous film width, three different stages can be distinguished. One is the constant width of liquid film. The second is the slight decrease of film width and the smooth surface. This kind of character will lead to less interfacial area and deteriorate the packing mass transfer performance. For the third stage, the variation of film width shows clearly chaotic behavior. The prediction model was also developed in present work. The predicted and experimental results are in good agreement.

Improvement of HydrophUicity and Blood Compatibility on Polyethersulfone Membrane by Blending Sulfonated Polyethersulfone

Polyethersulfone(PES) is widely used as biomaterials due to its thermal stability,mechanical strength,and chemical inertness.Nevertheless,their blood compatibility is still not adequate for hemodialysis and blood purification.In this study,the sulfonated polyethersulfone(SPES) was synthesized through an electrophilic substitution reaction,and PES/SPES blending membranes were prepared.The characterization of the SPES was studied by FTIR.The water adsorption and water contact angle experiments show that the hydrophilicity of PES/SPES blend membrane was improved as for the sulfonate group existing in the SPES.Moreover,PES/SPES blend membrane could effectively reduce bovine serum albumin adsorption and prolong the blood coagulation time compared with the PES membrane,thereby improving blood compatibility.

Reduction of Patulin Content in Apple Juice Using Activated Carbone

The mycotoxin, patulin （4-hydroxy-4H-furo [3, 2c] pyran-2 [6H]-one）, is produced by a number of fungi common to fruit and vegetable-based products, most notably apples. Patulin contamination within apple products poses a serious health risk to consumers. Studies done on laboratory animals have demonstrated that patulin has a broad spectrum of toxicity, including mutagen city and carcinogenicity. The aim of the experiment was studying influence of selectively acting activated carbon powder--Ercarbon SH （Erbsloh, Germany） which is special produced for lowering HMF （hydroxy methyl furfural）, on reduction of patulin content in clear apple juice. Industrial apple row material with some damaged parts was pressed, juice was pasteurized at 95 ℃ during 2 min. After cooling on 55 ℃, enzymatic treated and clarified juice were filtered by 0.45 [am pore sizes membrane filter, Apple clear juice sample was divided for five parts. The samples of apple juice were diluted to 11.5° Brix and contacted with concentrations of 2, 2.5, 3 and 3.5 g/L activated carbon powder for 30 min. After filtration in the experimental samples, putulin was quantitatively determined by HPLC （high performance liquid chromatography with UV） detector at 276 nm. The research revealed that the best results were achieved by treatment with activated carbon in its powder form at concentration of 2.5 g/L with 30 min contact time.

Optimizing the nickel boride layer thickness in a spectroelectrochemical ATR-FTIR thin-film flow cell applied in glycerol oxidation

The influence of the drop-casted nickel boride catalyst loading on glassy carbon electrodes was investigated in a spectroelectrochemical ATR-FTIR thin-film flow cell applied in alkaline glycerol electrooxidation.The continuously operated radial flow cell consisted of a borehole electrode positioned 50μm above an internal reflection element enabling operando FTIR spectroscopy.It is identified as a suitable tool for facile and reproducible screening of electrocatalysts under well-defined conditions,additionally providing access to the selectivities in complex reaction networks such as glycerol oxidation.The fast product identification by ATR-IR spectroscopy was validated by the more time-consuming quantitative HPLC analysis of the pumped electrolyte.High degrees of glycerol conversion were achieved under the applied laminar flow conditions using 0.1 M glycerol and 1 M KOH in water and a flow rate of 5μL min^(–1).Conversion and selectivity were found to depend on the catalyst loading,which determined the catalyst layer thickness and roughness.The highest loading of 210μg cm^(–2)resulted in 73%conversion and a higher formate selectivity of almost 80%,which is ascribed to longer residence times in rougher films favoring readsorption and C–C bond scission.The lowest loading of 13μg cm^(–2)was sufficient to reach 63%conversion,a lower formate selectivity of 60%,and,correspondingly,higher selectivities of C_(2)species such as glycolate amounting to 8%.Thus,only low catalyst loadings resulting in very thin films in the fewμm thickness range are suitable for reliable catalyst screening.

A functional PES membrane for hemodialysis-Preparation,characterization and biocompatibility

In this work, we evaluate the properties of solution casted polysulfone （PSf）/sulfonated polyethersulfone （SPES） blend membranes prepared by non-solvent induced phase inversion technique. The morphologies of these blend membranes, observed using scanning electron microscopy （SEM） and atomic force microscopy （AFM） imaging, indicated a smoother skin layer and an increased number of highly interconnected pores in the sub layer. The efficacy of the prepared membranes was evaluated in terms of porosity, ultrafiltration rate （UFR）, molecular weight cut-off （MWCO） and mean pore size. The hydrophilicity of these membranes was in consonance with contact angle values. It was observed that the selectivity and the UFR of the blend membranes were higher when compared to pristine membranes. Furthermore, these blend membranes demonstrated an increase in biocompatibility - prolonged blood clotting time, suppressed platelet adhesion, reduced protein adsorption and lower complement activation. These membranes were also investigated for uremic solute removal. Diffusive permeability of middle molecular weight cytochrome-c revealed an increase from 8 × 10 ^-4 cm·s ^-1 to 18 × 10^-4 cm· s^- and illustrates the possibility that these sulfonated PES/PSf blend membranes can be used to prepare membrane modules for hemodialysis applications.

Liquid-phase epitaxy of metal organic framework thin films

Metal-organic framework(MOF) thin films are multilayer materials ranging from nanometers to micrometers in thickness,physically or chemically adhesive to a(functionalized) substrate and,in an ideal case,exhibiting low roughness and high homogeneity.Various innovative approaches have been developed for MOF thin film fabrication.Among these advanced materials,surface-attached metal-organic frameworks(SURMOFs) are an important class of MOF films.SURMOFs,fabricated in a step-by-step liquid phase epitaxial(LPE) fashion by alternating deposition of metal and organic linker precursors on a functionalized substrate,for example,thiolate-based self-assembled monolayers(SAMs),have already exhibited their utility in both research and potential applications.SURMOFs combine surface science and the chemistry of MOFs,possessing the following unique advantages that cannot be accessed through other methods:(i) precisely controlling thickness,roughness and homogeneity as well as growth orientation,(ii) studying of MOF growth mechanism,(iii) modifying/tailoring MOFs' structures during the SURMOF growth and thus creating customizable properties,and(iv) existing in the form of thin film/membrane for direct applications,for example,as sensors.This review discusses the oriented and crystalline SURMOFs fabricated by LPE approach,covering their preparation,growth mechanism,and characterization methodology as well as applications based upon the most newly updated knowledge.

Stability Investigation on the Thin Films in Capillary

The stability of the thin liquid film in a capillary is important to the phase-change heat transfer process in miniature or micro structures. From the basic equations for motion and heat transfer at the interface of the film, its stability is theoretically studied. With evaluation of the effects and relative magnitudes of various driving forces and with the use of long-wave theory in addition to linear stability analysis, the controlling equations are simplified and an evolution equation for the film’s thickness is obtained. Detailed analysis on the evolution equation shows that instability occurs first in the meniscus region and the instability condition varies with boundary conditions, geometrical scales and thermal properties. The numerical results ape well with earlier ones with some favorable extensions and improvements.

Effects of Interfaces on Dynamics in Micro-Fluidic Devices：Slip-Boundaries' Impact on Rotation Characteristics of Polar Liquid Film Motors

A new approach for exploring effects of interfaces on polar liquids is presented. Their impact on the polar liquid film motor(PLFM) – a novel micro-fluidic device – is studied. We account for the interface's impact by modeling slip boundary effects on the PLFM's electro-hydro-dynamical rotations. Our analytical results show as k = l_s/R increases(with ls denoting the slip length resulting from the interface's impact on the film's properties, k >-1 and R denoting the film's radius):(a) PLFMs subsequently exhibit rotation characteristics under "negative-", "no-", "partial-" and"perfect-" slip boundary conditions;(b) The maximum value of the linear velocity of the steady rotating film increases linearly and its location approaches the film's border;(c) The decay of the angular velocities' dependency on the distance from the center of the film slows down, resulting in a macroscopic flow near the boundary. With our calculated rotation speed distributions consistent with the existing experimental ones, research aiming at fitting computed to measured distributions promises identifying the factors affecting ls, e.g., solid-fluid potential interactions and surface roughness.The consistency also is advantageous for optimizing PLFM's applications as micro-washers, centrifuges, mixers in the lab-on-a-chip.

Homogenization of a Class of Nonlinear Variational Inequalities with Applications in Fluid Film Flow

The authors consider the homogenization of a class of nonlinear variational inequalities,which include rapid oscillations with respect to a parameter.The homogenization of the corresponding class of differential equations is also studied.The results are applied to some models for the pressure in a thin fluid film fluid between two surfaces which are in relative motion.This is an important problem in the lubrication theory.In particular,the analysis includes the effects of surface roughness on both faces and the phenomenon of cavitation.Moreover,the fluid can be modeled as Newtonian or non-Newtonian by using a Rabinowitsch fluid model.