The thermokinetics of liquid-liqui d reaction of samarium nitrate /dysp rosium nitrate /erbium nitrate with histidine are studied using a microcalorimeter.On the basis of experime ntal and calculated results,three t h...The thermokinetics of liquid-liqui d reaction of samarium nitrate /dysp rosium nitrate /erbium nitrate with histidine are studied using a microcalorimeter.On the basis of experime ntal and calculated results,three t hermo-dynamic parameters(the activation enthalpy,the active entropy and the activation free energy),the rate constant,three kinetic parameters(the activation energy,the pre-exponential constant and the reaction order)are obtained.The influence of temperature on the t itled reaction and the synthetic con dition of the complex have been discu ssed.展开更多
The kinetics of liquid-phase hydrogenation of benzene in misch metai nickel-five (MINi5) and benzene slurry system was studied by investigating the influences of the reaction temperature, pressure, alloy concentration...The kinetics of liquid-phase hydrogenation of benzene in misch metai nickel-five (MINi5) and benzene slurry system was studied by investigating the influences of the reaction temperature, pressure, alloy concentration and stirring speed on the mass transfer-reaction processes inside the slurry. The results show that the whole process is controlled by the reaction at the surface of the catalyst. The mass transfer resistance at gas-liquid interface and that from the bulk liquid phase to the surface of the catalyst particles are negligible. The apparent reaction rate is zero order for benzene concentration and first order for hydrogen concentration in the liquid phase. The kinetic modei obtained fits the experimental data very well. The apparent activation energy of the hydrogen absorption reaction of MINi5-C6H6 slurry system is 42.16kJ·mol-1.展开更多
The co-extraction behavior of galena-pyrolusite in a sodium chloride solution and the electrochemical mechanism of this process were investigated,and some factors affecting the leaching rate of Pb and Mn were optimize...The co-extraction behavior of galena-pyrolusite in a sodium chloride solution and the electrochemical mechanism of this process were investigated,and some factors affecting the leaching rate of Pb and Mn were optimized.The results show that all the factors such as the concentration of NaCl,HCl and pyrolusite ore,reaction time,temperature,adding times of HCl,affect the leaching rate of Pb.The main affecting factors are the concentration of NaCl,reaction time and temperature.The Tafel polarization curves and EIS plots of the galena and pyrolusite in the NaCl solution demonstrate that during the oxidation process of galena mineral electrode,film forms on the galena surface,which prevents galena from deeper oxidation.However,the film resistance can be greatly reduced in the presence of sodium chloride,thus promoting the reaction rate of galena.展开更多
In this work, the effects of injecting an evaporating liquid jet into solid-gas flow are experimentally investigated. A new model （SHED model） and a supplementary model （spray model） have also been proposed to inv...In this work, the effects of injecting an evaporating liquid jet into solid-gas flow are experimentally investigated. A new model （SHED model） and a supplementary model （spray model） have also been proposed to investigate some flow-field characteristics in three-phase fluidized bed with the mean relative error 4.3% between model and measured results. Some experiments were conducted to study the influences of flow-field parameters such as liquid volumetric flow rate, injection velocity, jet angle and gas superficial velocity as well as solid mass flux on the jet penetration depth （JPD）. In addition, independent variables were experimentally employed to propose two empirical correlations for JPD by using multiple regression method and spray cone angle （SCA） by using dimensional analysis technique. The mean relative errors between the JPD and SCA correlations versus ex- perimental data were 7.5% and 3.9%, respectively. In addition, in order to identify the variable effect, a parametric study was carried out. Applying the proposed model can avoid direct use of expensive devices to measureJPD and to nredict dronlet size.展开更多
Trans-sobrerol （Sob） and 8-p-menthen-1,2-diol （Limo-diol） are the primary products in the atmospheric oxidation of α-pinene and limonene, respectively. Because of their low volatility, they associate more likely ...Trans-sobrerol （Sob） and 8-p-menthen-1,2-diol （Limo-diol） are the primary products in the atmospheric oxidation of α-pinene and limonene, respectively. Because of their low volatility, they associate more likely to the liquid particles in the atmosphere, where they are subject to the aqueous phase oxidation by the atmospheric oxidants. In this work, through experimental and theoretical study, we first provide the rate constants of Sob and Limo-diol reacting with hydroxyl radical （.OH） in aqueous solution at room temperature of 3044-3 K and 1 atm pressure, which are （3.05±0.5）×10 9 and （4.57±0.2）×10 9 L/（mol.s）, respectively. Quantum chemistry calculations have also been employed to demonstrate the solvent effect on the rate constants in aqueous phase and the calculated results agree well with the measurements. Some reaction products have been identified based on liquid chromatography combined with mass spectroscopy and theoretical calculations.展开更多
Evaporating bubble column reactor (EBCR) is a kind of aerated reactor in which the reaction heat is removed by the evaporation of volatile reaction mixture. In this paper, a mathematical model that accounts for the ga...Evaporating bubble column reactor (EBCR) is a kind of aerated reactor in which the reaction heat is removed by the evaporation of volatile reaction mixture. In this paper, a mathematical model that accounts for the gas-liquid exothermic reaction and axial dispersions of both gas and liquid phase is employed to study the performance of EBCR for the process of p-xylene(PX) oxidation. The computational results show that there are remarkable concentration and temperature gradients in EBCR for high ratio of height to diameter (H/DT). The temperature is lower at the bottom of column and higher at the top, due to rapid evaporation induced by the feed gas near the bottom. The concentration profiles in the gas phase are more nonuniform than those (except PX) in the liquid phase, which causes more solvent burning consumption at high H/DT ratio. For p-xylene oxidation, theo ptimal H/DT is around 5.展开更多
The dissolution kinetics of diatomite in alkaline solution is the theoretical basis for the process optimization of alkali-diatomite reaction and its applications.In this study,the dissolution kinetics of diatomite in...The dissolution kinetics of diatomite in alkaline solution is the theoretical basis for the process optimization of alkali-diatomite reaction and its applications.In this study,the dissolution kinetics of diatomite in NaOH solution is investigated.The results indicate that the dissolution reaction fits well the unreacted shrinking core model for solid-liquid heterogeneous reactions.The apparent reaction order for NaOH is 2 and the apparent activation energy for the reaction(Ea) is 28.06 kJ·mol-1.The intra-particle diffusion through the sodium silicate layer is the rate-controlling step.When the dissolution reaction occurs at the interface of unreacted diatomite solid core,the diffusion in the trans-layer(the liquid film around the wetted particle) reduces the rate of whole dissolution process.展开更多
Although hydraulic drives have an advantage of high power density, volumetric shrinkage of hydraulic fluids due to pressure causes various disadvantages such as delay of hydraulic response and compression energy loss....Although hydraulic drives have an advantage of high power density, volumetric shrinkage of hydraulic fluids due to pressure causes various disadvantages such as delay of hydraulic response and compression energy loss. Hydraulic fluids of new concept, high bulk modulus oils, have been developed as a new approach to improve the performance of a hydraulic servo system and verified. In this paper, practical performances of high bulk modulus oil, such as oil temperature rise during pump test, air bubbles generation by ultrasonic wave vibration, oxidation stability and anti-wear property, were studied. And the new oil was confirmed to have excellent practical performances besides advantages in pressure response and volumetric efficiency of pumps. Various new applications of the new oil are promising.展开更多
Liquid ternary Fe47.5Cu47.5Sn5 alloy displayed dual solidification mechanisms when it was undercooled by up to 329 K （0.19TL）. Below a critical undercooling of about 196 K, it solidified just like a normal peritecti...Liquid ternary Fe47.5Cu47.5Sn5 alloy displayed dual solidification mechanisms when it was undercooled by up to 329 K （0.19TL）. Below a critical undercooling of about 196 K, it solidified just like a normal peritectic alloy, even though metastable phase separation occurred to a microscopic extent. Once bulk undercooling exceeds 196 K, macroscopic segregation played a domi- nant role in solidification. In both cases, the solidification process was always characterized by two successive peritectic trans- formations： firstly primary yFe dendrites reacted with liquid phase to form （Cu） phase, and subsequently the （Cu） phase reacted with residual liquid phase to yield β-Cu5.6Sn intermetallic compound. The primary yFe dendrites achieved a maximum growth velocity of 400 mm/s and experienced a growth kinetics transition as a result of macrosegregation. Since the （Cu） phase was both the product phase of the first peritectic transformation and also the reactant phase for the second peritectic transformation, it appeared as two layers in solidification microstructures due to the microsegregation of Sn solute. The boundary continuity between the macroscopically separated Fe-rich and Cu-ricb zones was enhanced with the increase of undercooling.展开更多
文摘The thermokinetics of liquid-liqui d reaction of samarium nitrate /dysp rosium nitrate /erbium nitrate with histidine are studied using a microcalorimeter.On the basis of experime ntal and calculated results,three t hermo-dynamic parameters(the activation enthalpy,the active entropy and the activation free energy),the rate constant,three kinetic parameters(the activation energy,the pre-exponential constant and the reaction order)are obtained.The influence of temperature on the t itled reaction and the synthetic con dition of the complex have been discu ssed.
基金State Key Project of Basic Research of China(TG2000026406)National Natural Science Foundation of China(No.50071053)
文摘The kinetics of liquid-phase hydrogenation of benzene in misch metai nickel-five (MINi5) and benzene slurry system was studied by investigating the influences of the reaction temperature, pressure, alloy concentration and stirring speed on the mass transfer-reaction processes inside the slurry. The results show that the whole process is controlled by the reaction at the surface of the catalyst. The mass transfer resistance at gas-liquid interface and that from the bulk liquid phase to the surface of the catalyst particles are negligible. The apparent reaction rate is zero order for benzene concentration and first order for hydrogen concentration in the liquid phase. The kinetic modei obtained fits the experimental data very well. The apparent activation energy of the hydrogen absorption reaction of MINi5-C6H6 slurry system is 42.16kJ·mol-1.
基金Project(50774094) supported by the National Natural Science Foundation of China
文摘The co-extraction behavior of galena-pyrolusite in a sodium chloride solution and the electrochemical mechanism of this process were investigated,and some factors affecting the leaching rate of Pb and Mn were optimized.The results show that all the factors such as the concentration of NaCl,HCl and pyrolusite ore,reaction time,temperature,adding times of HCl,affect the leaching rate of Pb.The main affecting factors are the concentration of NaCl,reaction time and temperature.The Tafel polarization curves and EIS plots of the galena and pyrolusite in the NaCl solution demonstrate that during the oxidation process of galena mineral electrode,film forms on the galena surface,which prevents galena from deeper oxidation.However,the film resistance can be greatly reduced in the presence of sodium chloride,thus promoting the reaction rate of galena.
文摘In this work, the effects of injecting an evaporating liquid jet into solid-gas flow are experimentally investigated. A new model （SHED model） and a supplementary model （spray model） have also been proposed to investigate some flow-field characteristics in three-phase fluidized bed with the mean relative error 4.3% between model and measured results. Some experiments were conducted to study the influences of flow-field parameters such as liquid volumetric flow rate, injection velocity, jet angle and gas superficial velocity as well as solid mass flux on the jet penetration depth （JPD）. In addition, independent variables were experimentally employed to propose two empirical correlations for JPD by using multiple regression method and spray cone angle （SCA） by using dimensional analysis technique. The mean relative errors between the JPD and SCA correlations versus ex- perimental data were 7.5% and 3.9%, respectively. In addition, in order to identify the variable effect, a parametric study was carried out. Applying the proposed model can avoid direct use of expensive devices to measureJPD and to nredict dronlet size.
基金This work was supported by the National Natural Science Foundation of China （No.21177041 and No.21107026）, the Fundamental Research Funds for the Central Universities （No.2013ZZ0073）, and the Scientific Research Foundation for Returned Overseas Chinese Scholars, State Education Ministry.
文摘Trans-sobrerol （Sob） and 8-p-menthen-1,2-diol （Limo-diol） are the primary products in the atmospheric oxidation of α-pinene and limonene, respectively. Because of their low volatility, they associate more likely to the liquid particles in the atmosphere, where they are subject to the aqueous phase oxidation by the atmospheric oxidants. In this work, through experimental and theoretical study, we first provide the rate constants of Sob and Limo-diol reacting with hydroxyl radical （.OH） in aqueous solution at room temperature of 3044-3 K and 1 atm pressure, which are （3.05±0.5）×10 9 and （4.57±0.2）×10 9 L/（mol.s）, respectively. Quantum chemistry calculations have also been employed to demonstrate the solvent effect on the rate constants in aqueous phase and the calculated results agree well with the measurements. Some reaction products have been identified based on liquid chromatography combined with mass spectroscopy and theoretical calculations.
基金Supported by the National Natural Science Foundation of China (No. 20076039) and SINOPEC.
文摘Evaporating bubble column reactor (EBCR) is a kind of aerated reactor in which the reaction heat is removed by the evaporation of volatile reaction mixture. In this paper, a mathematical model that accounts for the gas-liquid exothermic reaction and axial dispersions of both gas and liquid phase is employed to study the performance of EBCR for the process of p-xylene(PX) oxidation. The computational results show that there are remarkable concentration and temperature gradients in EBCR for high ratio of height to diameter (H/DT). The temperature is lower at the bottom of column and higher at the top, due to rapid evaporation induced by the feed gas near the bottom. The concentration profiles in the gas phase are more nonuniform than those (except PX) in the liquid phase, which causes more solvent burning consumption at high H/DT ratio. For p-xylene oxidation, theo ptimal H/DT is around 5.
基金Supported by the National lqatural Science Foundation of China （50674080）.
文摘The dissolution kinetics of diatomite in alkaline solution is the theoretical basis for the process optimization of alkali-diatomite reaction and its applications.In this study,the dissolution kinetics of diatomite in NaOH solution is investigated.The results indicate that the dissolution reaction fits well the unreacted shrinking core model for solid-liquid heterogeneous reactions.The apparent reaction order for NaOH is 2 and the apparent activation energy for the reaction(Ea) is 28.06 kJ·mol-1.The intra-particle diffusion through the sodium silicate layer is the rate-controlling step.When the dissolution reaction occurs at the interface of unreacted diatomite solid core,the diffusion in the trans-layer(the liquid film around the wetted particle) reduces the rate of whole dissolution process.
文摘Although hydraulic drives have an advantage of high power density, volumetric shrinkage of hydraulic fluids due to pressure causes various disadvantages such as delay of hydraulic response and compression energy loss. Hydraulic fluids of new concept, high bulk modulus oils, have been developed as a new approach to improve the performance of a hydraulic servo system and verified. In this paper, practical performances of high bulk modulus oil, such as oil temperature rise during pump test, air bubbles generation by ultrasonic wave vibration, oxidation stability and anti-wear property, were studied. And the new oil was confirmed to have excellent practical performances besides advantages in pressure response and volumetric efficiency of pumps. Various new applications of the new oil are promising.
基金supported by the National Natural Science Foundation of China (Grant Nos. 51101123 and 50971105)the Fundamental Research Fund of Northwestern Polytechnical University (GrantNo. JC201050)
文摘Liquid ternary Fe47.5Cu47.5Sn5 alloy displayed dual solidification mechanisms when it was undercooled by up to 329 K （0.19TL）. Below a critical undercooling of about 196 K, it solidified just like a normal peritectic alloy, even though metastable phase separation occurred to a microscopic extent. Once bulk undercooling exceeds 196 K, macroscopic segregation played a domi- nant role in solidification. In both cases, the solidification process was always characterized by two successive peritectic trans- formations： firstly primary yFe dendrites reacted with liquid phase to form （Cu） phase, and subsequently the （Cu） phase reacted with residual liquid phase to yield β-Cu5.6Sn intermetallic compound. The primary yFe dendrites achieved a maximum growth velocity of 400 mm/s and experienced a growth kinetics transition as a result of macrosegregation. Since the （Cu） phase was both the product phase of the first peritectic transformation and also the reactant phase for the second peritectic transformation, it appeared as two layers in solidification microstructures due to the microsegregation of Sn solute. The boundary continuity between the macroscopically separated Fe-rich and Cu-ricb zones was enhanced with the increase of undercooling.
