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高磺化度三聚氰胺系高效减水剂的合成及应用 被引量:2
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作者 徐正林 王蔚 卞荣兵 《水利水电施工》 2001年第4期23-25,共3页
本文在三聚氰胺系高效减水剂(SM)的传统合成工艺基础上,提高了甲醛及磺化剂与三聚氰胺之投料比,合成了高磺化度的三聚氰胺系减水剂产品(HSM)。该产品与普通三聚氰胺系高效减水剂及其它一些同类产品相比,具有更高的减水率和更为显著的早... 本文在三聚氰胺系高效减水剂(SM)的传统合成工艺基础上,提高了甲醛及磺化剂与三聚氰胺之投料比,合成了高磺化度的三聚氰胺系减水剂产品(HSM)。该产品与普通三聚氰胺系高效减水剂及其它一些同类产品相比,具有更高的减水率和更为显著的早期增强效果。 展开更多
关键词 高磺化度三聚氰胺系减水剂 HSM 合成 混凝土高效减水剂
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几种复合减水剂的分散效应与作用机理 被引量:8
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作者 刘才林 任先艳 +1 位作者 杨海君 杨军校 《建筑材料学报》 EI CAS CSCD 北大核心 2011年第1期111-115,共5页
采用合适比例的聚羧酸系高效减水剂复合改性脂肪族系、三聚氰胺系和萘系高效减水剂,制备了3种复合减水剂,研究了它们对水泥净浆性能及混凝土性能的影响;通过Zeta电位测定和X射线光电子能谱(XPS)分析研究了复合减水剂的分散作用机理.结... 采用合适比例的聚羧酸系高效减水剂复合改性脂肪族系、三聚氰胺系和萘系高效减水剂,制备了3种复合减水剂,研究了它们对水泥净浆性能及混凝土性能的影响;通过Zeta电位测定和X射线光电子能谱(XPS)分析研究了复合减水剂的分散作用机理.结果表明:脂肪族系-聚羧酸系复合减水剂是静电斥力起了主导作用,三聚氰胺系-聚羧酸系复合减水剂和萘系-聚羧酸系复合减水剂是聚羧酸系减水剂的空间位阻效应起了主导作用. 展开更多
关键词 混凝土高效减水剂 ZETA电位 分散作用机理
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STUDY ON OPTIMIZATION OF HIGH PERFORMANCE CONCRETE ADMIXTURES 被引量:7
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作者 刘俊龙 麻海燕 +2 位作者 李强 陈树东 张云清 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2011年第2期206-210,共5页
Influences of admixtures on the workability and strength of high performance concrete (HPC) are in- vestigated. The types of investigated admixtures include naphthalene series high range water reducing agent, polyca... Influences of admixtures on the workability and strength of high performance concrete (HPC) are in- vestigated. The types of investigated admixtures include naphthalene series high range water reducing agent, polycarboxlic series high range water reduce agent and sodium sulfate hardening accelerating agent. Two kinds of curing condition, namely steam curing condition and standard curing condition, are adopted. The result shows that HPC, added with polycarboxlic series of high performance water reducer, has high workability and strength, while sodium sulfate accelerating agent causes poor workability and low strength. Thus for vapor-cured HPC and its formulations, naphthalene series high range water reducing agent with less sodium sulfate should be given pri- ority. Therefore, the differences of curing conditions should be considered when selecting HPC admixtures. 展开更多
关键词 high performance concrete high performance water reducer hardening accelerating agent SLUMP compressive strength
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改性木素磺酸盐泵送剂GCL1-3的制备及性能研究 被引量:5
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作者 庞煜霞 邱学青 +1 位作者 欧阳新平 杨东杰 《精细化工》 EI CAS CSCD 北大核心 2001年第10期595-598,共4页
通过研究缓凝高效减水剂GCL1与保水剂、引气剂的配伍性能 ,研制了混凝土泵送剂GCL1- 3。GCL1与保水剂HEC、引气剂复配时 ,改善了水泥净浆的保水性能 ,提高了硬化水泥的早期及后期抗压强度。实验测试了GCL1- 3的水泥净浆流动度、减水率... 通过研究缓凝高效减水剂GCL1与保水剂、引气剂的配伍性能 ,研制了混凝土泵送剂GCL1- 3。GCL1与保水剂HEC、引气剂复配时 ,改善了水泥净浆的保水性能 ,提高了硬化水泥的早期及后期抗压强度。实验测试了GCL1- 3的水泥净浆流动度、减水率、流动度损失和抗压强度等性能。结果表明 ,当w (水 )∶w(水泥 ) =0 4∶1 0 ,w (GCL1- 3) =0 .5 %时 ,水泥净浆流动度可达2 30mm ,减水率达 18% ,且无离析现象 ;2h内流动度损失仅为 2 4% ,而掺FDN的净浆已经失去流动性 ;w(GCL1- 3) =0 .5 %时 ,水泥净浆硬化 3d、7d、2 8d的抗压强度比分别达 146 %、15 8%与148% 。 展开更多
关键词 改性木钙 泵送剂 滤水 改性木素磺酸盐 混凝土缓凝高效减水剂 GCL1-3 制备
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Statistical modelling for effect of mix-parameters on properties of high-flowing sand-concrete 被引量:7
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作者 T.BOUZIANI A.BENMOUNAH M.BDRINA 《Journal of Central South University》 SCIE EI CAS 2012年第10期2966-2975,共10页
The high-flowing sand-concrete (HFSC) containing natural sands as aggregate was carried out. The high fluidity and stability of HFSC can be achieved by tailoring the mix design parameters, such as fine to coarse san... The high-flowing sand-concrete (HFSC) containing natural sands as aggregate was carried out. The high fluidity and stability of HFSC can be achieved by tailoring the mix design parameters, such as fine to coarse sand ratio, dosage of additions, water to binder ratio and dosage of admixtures. Mini-cone slump test, v-fl.mnel time test and viscosity model parameters were used to characterize the behaviour of HFSC in fresh state. The mechanical compressive strength in 28 d was also determined. A factorial design approach was used to establish models highlighting the effect of each mix-parameter on measured properties of HFSC. The derived models are valid for mixtures made with 0 to 0.3 of dune sand to total sand ratio, 82 to 418 kg/m3 of marble powder, 0.42 to 0.46 of water/binder ratio and 1.3% to 1.9% of superplasticizer high water-reducer. The results show that the derived models constitute very efficient means for understanding the influence of key mix-parameters on HFSC properties and are useful in selecting the optimum mix proportions, by simulating their impact on fluidity, stability and compressive strength. 展开更多
关键词 high-flowing sand-concrete factorial design FLUIDITY VISCOSITY mix-design parameters
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Production and Properties of Superplasticized Concrete
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作者 Mohamed Attia Abd Elrahman M. A. Imam +1 位作者 Ahmed H. Abdel Reheem Ahmed Mohamed Tahwia 《Journal of Civil Engineering and Architecture》 2011年第4期341-352,共12页
The objective of this research is to study the effect of grinding powdered superplasticizer, Portland cement, sand, and silica fume on the properties of fresh and hardened concrete. Lose Angeles Machine was used to gr... The objective of this research is to study the effect of grinding powdered superplasticizer, Portland cement, sand, and silica fume on the properties of fresh and hardened concrete. Lose Angeles Machine was used to grind these constituents. The program was arranged to determine the effect of cycles' number, superplasticizer type and dosage, silica fume dosage and condition, and gravel to sand ratio on properties of concrete. Naphthalene sulphonated formaldehyde (NSF) superplasticizers in the forms of liquid and powdered were used. Silica fume may be grinded with the other constituents (grinded), or added to concrete mixer (normal). The water/cement (w/c) ratio varied from 0.35 to 0.55 to achieve a constant slump (50-90 mm). Slumps, bulk density and mechanical properties of concrete were measured. Scanning electron microscope (SEM) was also used to show the differences between traditional and superplasticized concrete. The results showed that grinding the mixture enhances fresh and hardened concrete properties. It is also observed that grinding the mixture for 500 cycles is more effective than other numbers of grinding. In addition, superplasticized concrete exhibits compressive strength higher than traditional one at varied ages. Moreover, using powdered superplasticizer has a remarkable effect on enhancing concrete properties rather than using it in a liquid form. A dosage of 1% by weight of cement gave the highest results of compressive strength. Silica fume has an essential role in improving concrete strength and durability since it acts as very efficient void filler and as a super pozzolana. SEM observations illustrate that grinding the mixture enhances transition zone (TZ) properties and makes it denser. On the other hand, grinded mixture can be packaged in bags and transported for use in crowded cities, and so, enhances quality control, since the only requirement to obtain superplasticized concrete is to add water and gravel. This technique has many benefits such as; saving cement, labor and noise, high quality control, and enhancing concrete permeability and durability. There are many fields of application of superplasticized concrete such as; in locations which are not easily accessible by ordinary concreting techniques, in repairing and strengthen, thin coating, and for small projects when ready mix supply is not feasible. 展开更多
关键词 SUPERPLASTICIZER silica fume Los Angeles Machine cycles' number scanning electron microscope transition zone properties of fresh and hardened concrete.
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Analysis of the Influence of Type, Amount and Way of Introduction of Anti-foaming Admixture (AFA) on the Properties of Self-compacting Concrete (SCC) Mix
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作者 Beata Lazniewska-Piekarczyk 《Journal of Civil Engineering and Architecture》 2010年第1期1-10,共10页
The properties of the self-compacting concrete mix depend on an automatic introduction of air bubbles caught during the process of mixing. What is interesting, the criterion for self-compactibility is not taken into c... The properties of the self-compacting concrete mix depend on an automatic introduction of air bubbles caught during the process of mixing. What is interesting, the criterion for self-compactibility is not taken into consideration in commonly used self-compacting tests. On the basis of different tests concerning self-compacting concrete mixes, it has been found out that too high air content in their volume was the result of superplasticizer, in spite of meeting the self-compactibility criteria (i.e., self-venting). For the decrease of too high air volume in SCC, the use of anti-foaming admixture (AFA) is proposed. As a result, the effect of AFA mix flow diameter is increased and the flow time is decreased. Moreover, the workability loss is lower. In case of mix incorporating AFA, their high flowability does not cause segregation of the mix, what is possible in case of SCC incorporating only superplasticizer. However, the time of the introduction of AFA and its type is essential to get higher flowability degree, but it is not important to achieve low air volume in SCC. 展开更多
关键词 SUPERPLASTICIZER anti-foaming admixture methodology decreasing the air-volume self-compacting concrete rheological properties.
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Rheological Properties of Recycled Aggregate Concrete Using Superplasticizers
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作者 Sandrine Braymand Pierre Francois +1 位作者 Francoise Feugeas Christophe Fond 《Journal of Civil Engineering and Architecture》 2015年第5期591-597,共7页
The mechanical properties of recycled aggregates concrete from demolition have been studied for several years. It has been documented that rheological properties of these concrete are generally affected by use of recy... The mechanical properties of recycled aggregates concrete from demolition have been studied for several years. It has been documented that rheological properties of these concrete are generally affected by use of recycled aggregates. They could present mechanical properties less affected by the presence of recycled aggregates if the initial concrete were of good quality. However, manufacturing problems, mainly attributed to the angular character of these aggregates and to the granulometry of recycled sand, limit their industrial use. The worth point of this study consists in the optimization of the concrete formulation using specific admixture, adapted to this aggregates in order to facilitate its manufacturing. It shows that the new generation of superplasticizers containing some copolymer polycarboxylate makes it possible to significantly improve the fluidity of the recycled aggregates concrete in its fresh state. The aim of this research is to control rheologica] properties of fresh recycled aggregates concrete with fine and coarse recycled aggregates to limit the negative influence of aggregates on mechanical properties of concrete. 展开更多
关键词 SUPERPLASTICIZER recycled aggregate concrete WORKABILITY VISCOSITY mechanical strength grading.
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Effect of Curing Temperature on Mortar Based on Sustainable Concrete Material's and Poly-Carboxylate Superplasticizer
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作者 Ilham Aguida Belia Aissa Asroun Nabil Bella 《Journal of Civil Engineering and Architecture》 2014年第1期66-72,共7页
Nowadays, technologies in construction field have offered several kinds of chemical admixtures, which offer different behaviors at the fresh state of the batch and by consequence, it is resulted with different mechani... Nowadays, technologies in construction field have offered several kinds of chemical admixtures, which offer different behaviors at the fresh state of the batch and by consequence, it is resulted with different mechanical behaviors at the solid state of the mix. This study focused on the behavior of a new kind of admixture at fresh and solid states. Currently, the concrete material has become a very expensive material because the high price mostly of aggregates, representing the three quarters of the concrete components. By consequence, it costs money and on the other hand, it produces a lot of wastes. The main aspect which guides this study is to make a kind of concrete based mainly on local material and sustainable concrete material (SCM or waste material), which is one very abundant material in quality and quantity, under the current tendency the results obtained in this study summarize up the importance of the temperature during the development of the mechanical characteristics of mortar, mainly on compressive strength at age of 28 days. This is in the case of the addition of limestone crushed additive by percentage of substitution. 展开更多
关键词 MORTAR crushed limestone additive substitution ADMIXTURE temperature.
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Preparation of Rapid Hardening Mortars Using Ultrafine Portland Cement
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作者 Obed Arnoldo Chimal-Valencia Juan Carlos Arteaga-Arcos +2 位作者 David Joaquin Delgado-Hernaindez Hernani Yee-Madeira Sebastian Diaz de la Torte 《Journal of Civil Engineering and Architecture》 2010年第8期63-69,共7页
During the hydration process, the Ultra-fine Cements present specific physical and chemical characteristics; they are, very short setting time and high heat release. For special applications, such as rapid hardening a... During the hydration process, the Ultra-fine Cements present specific physical and chemical characteristics; they are, very short setting time and high heat release. For special applications, such as rapid hardening and early high strength mortars or concretes, these characteristics can be considered advantageous. Some commercial products used for concrete reinforcement and repairs are the Rapid Hardening Mortars, these mortars must develop a time of setting up to 3 h and an initial compressive strength of about 3.5 MPa once the hardening of the paste is reached. The objective of the present research work is to use Ultra-fine Cement for the preparation of a series of different Rapid Hardening Mortars (with different percentages of Ultra-fine Cement), these mortars required the addition of a polycarboxylate-base specification F Superplasticizer. It was observed that the optimum water/cement (W/C) ratio for the hydration of the Ultra-fine Cements is W/C = 0.385. The Ultra-fine Cements were obtained by the High Energy Ball-milling technique at laboratory scale, 90% of the Particle Size Distribution is below 11 μm and the Blaine Specific Surface Area is over 9000 cm^2/g. 展开更多
关键词 Ultra fine portland cement high energy ball milling superplastizicer rapid hardening mortars
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C80预拌泵送砼的试验研制
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作者 冼伟华 《广东土木与建筑》 1997年第4期35-38,共4页
本项目分别用525、625两种水泥,试用了14种减水剂、5种超细矿物粉料,进行了51组试配,找出了利用当地原材料配制C80预拌泵送混凝土的配合比。
关键词 超细矿物粉料 高效减水剂高性能混凝土
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