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基于钛酸盐敏感电极的混合位型SO_(2)传感器研究
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作者 常祎露 王岭 +2 位作者 戴磊 李跃华 孟维薇 《传感器与微系统》 CSCD 北大核心 2023年第10期5-8,共4页
采用溶胶凝胶法合成了系列钛酸盐(ZnTiO_(3)、SrTiO_(3)、NiTiO_(3)),并将其作为敏感电极,同时以钇稳定的氧化锆(YSZ)为固体电解质制备了混合电位型二氧化硫(SO_(2))传感器用于高温下SO_(2)体积分数的在线监测。敏感电极的相组成和传感... 采用溶胶凝胶法合成了系列钛酸盐(ZnTiO_(3)、SrTiO_(3)、NiTiO_(3)),并将其作为敏感电极,同时以钇稳定的氧化锆(YSZ)为固体电解质制备了混合电位型二氧化硫(SO_(2))传感器用于高温下SO_(2)体积分数的在线监测。敏感电极的相组成和传感器的微观形貌分别采用X射线衍射仪(XRD)和配备了能谱仪(EDS)的扫描电镜(SEM)表征。敏感性能测试结果表明:在系列钛酸盐当中,NiTiO_(3)敏感电极表现出更佳的敏感性能,其在400~500℃的温度范围内,可以有效检测3×10^(-6)~30×10^(-6)的SO_(2),传感器的响应值与SO_(2)体积分数的对数之间呈现良好的线性关系。此外,传感器表现出优异的重现性和抗干扰性能。 展开更多
关键词 二氧化硫传感器 混合位型 NiTiO_(3)敏感电极 灵敏度 抗干扰性能
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基于纳米CuO敏感电极混合位型NO_2传感器的研究 被引量:1
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作者 王运飞 王岭 +4 位作者 朱靖 戴磊 李跃华 周会珠 吴印林 《功能材料》 EI CAS CSCD 北大核心 2013年第15期2138-2142,共5页
采用溅射法制备的纳米结构CuO为敏感电极,钇稳定氧化锆(YSZ)为固体电解质制成了一种混合位型NO2传感器。采用X射线衍射仪(XRD)和扫描电子显微镜(SEM)分别表征了CuO敏感电极的相组成和微观形貌。研究了Cu的不同溅射时间对CuO敏感电极微... 采用溅射法制备的纳米结构CuO为敏感电极,钇稳定氧化锆(YSZ)为固体电解质制成了一种混合位型NO2传感器。采用X射线衍射仪(XRD)和扫描电子显微镜(SEM)分别表征了CuO敏感电极的相组成和微观形貌。研究了Cu的不同溅射时间对CuO敏感电极微观结构及传感器敏感性能的影响。结果表明,CuO颗粒随着Cu溅射时间的增长而增大,制成的传感器在600~700℃范围内对25~400mL/m3的NO2具有较好的敏感性能,传感器响应信号与NO2浓度的对数呈现良好的线性关系,其中60min,Cu传感器在650℃时灵敏度达41.47mV/decade,对于400mL/m3的NO2,90%的响应时间和恢复时间分别约为160、260s,体积分数0~10%的CO2对传感器的响应几乎没有影响,传感器具有较好的敏感度、重现性和稳定性。 展开更多
关键词 溅射法 混合位型 NO2传感器 CuO纳米颗粒 YSZ
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CuCr_2O_4-CuO复合敏感电极混合位型NO_2传感器的研究
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作者 李跃华 侯欢欢 +2 位作者 韩文 戴磊 王岭 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2018年第S1期435-439,共5页
采用具有致密层/多孔层双层结构的6%Y_2O_3(质量分数)添加的La_(10)Si_6O_(27)为固体电解质,在多孔层内丝网印刷的Cu Cr_2O_4-Cu O复合物为敏感材料,制备了混合位型NO_2传感器。采用XRD、SEM对NO_2传感器敏感材料的相组成和微观形貌进... 采用具有致密层/多孔层双层结构的6%Y_2O_3(质量分数)添加的La_(10)Si_6O_(27)为固体电解质,在多孔层内丝网印刷的Cu Cr_2O_4-Cu O复合物为敏感材料,制备了混合位型NO_2传感器。采用XRD、SEM对NO_2传感器敏感材料的相组成和微观形貌进行了表征,应用电化学工作站测试了传感器的敏感性能和响应机理。结果表明:粒径200~300 nm的Cu Cr_2O_4-Cu O均匀分布在约20μm厚的多孔层中;极化曲线和交流阻抗结果表明该传感器为混合位型,在600~700℃、NO_2浓度25~300 ppm,传感器响应信号值与NO_2浓度之间呈良好线性关系,600℃时具有最好的敏感性、重现性和稳定性;共存的NH_3、CH_4、H_2及CO_2对传感器敏感性能几乎没有影响,O_2在5 vol%~21 vol%浓度范围内随浓度的增大电位值线性减小。在实际应用中可以通过O_2传感器进行校正。 展开更多
关键词 NO2传感器 混合位型 CuCr2O4-CuO La10Si6O27
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基于球磨法制备的WO_(3)敏感电极的NH_(3)传感器
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作者 宋家轩 朱靖 +2 位作者 孟维薇 戴磊 王岭 《微纳电子技术》 CAS 2024年第1期102-109,共8页
采用球磨法预处理了WO_(3)颗粒并将其作为敏感电极,将钇稳定的氧化锆(YSZ)作为固体电解质制备了混合位型NH_(3)传感器。采用X射线衍射仪(XRD)和扫描电子显微镜(SEM)对预处理的材料进行了表征。经球磨法处理的WO_(3)粉末颗粒尺寸减小,比... 采用球磨法预处理了WO_(3)颗粒并将其作为敏感电极,将钇稳定的氧化锆(YSZ)作为固体电解质制备了混合位型NH_(3)传感器。采用X射线衍射仪(XRD)和扫描电子显微镜(SEM)对预处理的材料进行了表征。经球磨法处理的WO_(3)粉末颗粒尺寸减小,比表面积增大。以WO_(3)为敏感电极,在550~700℃内对传感器的响应-恢复特性、循环稳定性、湿度和氧气体积分数的干扰、交叉气体干扰等敏感性能进行了测试。敏感性能测试结果表明:该传感器在550~700℃之间表现出优异的NH_(3)敏感性能,响应信号与NH_(3)体积分数的对数之间线性关系良好。同时该传感器还表现出良好的循环稳定性,在不同氧气体积分数和湿度的气氛下都能稳定工作。此外,该传感器对CO_(2)、H_(2)、CH_(4)和NO均表现出良好的抗干扰能力,且采用CuO参比电极成功降低了对NO_(2)的交叉干扰。 展开更多
关键词 NH_(3)传感器 混合位型 WO_(3) 固体电解质 敏感电极
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固体电解质基VOCs传感器的研究进展
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作者 赵艳琴 刘永光 +3 位作者 戴磊 周会珠 王岭 曹吉林 《传感器与微系统》 CSCD 2016年第11期1-5,共5页
综述了混合位型、阻抗型和电流型三类固体电解质基挥发性有机物(VOCs)传感器在检测VOCs方面的主要研究进展,并对固体电解质基VOCs传感器的发展方向和研究趋势进行了展望。
关键词 固体电解质 挥发性有机物传感器 混合位型 阻抗 电流
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Disentanglement of Qubit in Dephasing Model
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作者 YANG Qing YANG Ming CAO Zhuo-Liang 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第4期627-630,共4页
We investigate the entanglement evolution of two qubits that are initially in Werner state under the classical phase noise. We discuss the influence of mixture degree on disentanglement. It is showed that the more mix... We investigate the entanglement evolution of two qubits that are initially in Werner state under the classical phase noise. We discuss the influence of mixture degree on disentanglement. It is showed that the more mixed the state, the shorter is the time of disentanglement. 展开更多
关键词 DISENTANGLEMENT dephase
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Turbulence and mixing in a freshwater-influenced tidal bay: Observations and numerical modeling 被引量:1
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作者 LIAN Qiang LIU ZhiYu 《Science China Earth Sciences》 SCIE EI CAS CSCD 2015年第11期2049-2058,共10页
In situ observations and numerical simulations of turbulence are essential to understanding vertical mixing processes and their dynamical controls on both physical and biogeochemical processes in coastal embayments. U... In situ observations and numerical simulations of turbulence are essential to understanding vertical mixing processes and their dynamical controls on both physical and biogeochemical processes in coastal embayments. Using in situ data collected by bottom-mounted acoustic Doppler current profilers(ADCPs) and a free-falling microstructure profiler, as well as numerical simulations with a second-moment turbulence closure model, we studied turbulence and mixing in the Xiamen Bay, a freshwater-influenced tidal bay located at the west coast of the Taiwan Strait. Dynamically, the bay is driven predominantly by the M2 tide, and it is under a significant influence of the freshwater discharged from the Jiulong River. It is found that turbulence quantities such as the production and dissipation rates of the turbulent kinetic energy(TKE) were all subject to significant tidal variations, with a pronounced ebb-flood asymmetry. Turbulence was stronger during flood than ebb. During the flooding period, the whole water column was nearly well mixed with the depth-averaged TKE production rate and vertical eddy viscosity being up to 5?10?6 W kg?1 and 2?10?2 m2 s?1, respectively. In contrast, during the ebb strong turbulence was confined only to a 5?8 m thick bottom boundary layer, where turbulence intensity generally decreases with distance from the seafloor. Diagnosis of the potential energy anomaly showed that the ebb-flood asymmetry in turbulent dissipation and mixing was due mainly to tidal straining process as a result of the interaction between vertically shared tidal currents and horizontal density gradients. The role of vertical mixing in generating the asymmetry was secondary. A direct comparison of the modeled and observed turbulence quantities confirmed the applicability of the second-moment turbulence closure scheme in modeling turbulent processes in this weakly stratified tidally energetic environment, but also pointed out the necessity of further refinements of the model. 展开更多
关键词 tidal bay turbulent mixing second-moment turbulence closure model turbulent kinetic energy dissipation rate vertical eddy viscosity
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Ruan's conjecture on singular symplectic flops of mixed type
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作者 CHEN BoHui LI AnMin +1 位作者 LI XiaoBin ZHAO GuoSong 《Science China Mathematics》 SCIE 2014年第6期1121-1148,共28页
In this paper,we study the global singular symplectic flops related to the following affine hypersurface with cyclic quotient singularities,Vr,b={(x,y,z,t)∈C4|xy-z2r+t2=0}/μr(a,-a,b,0),r 2,where b=1 appears in Mori... In this paper,we study the global singular symplectic flops related to the following affine hypersurface with cyclic quotient singularities,Vr,b={(x,y,z,t)∈C4|xy-z2r+t2=0}/μr(a,-a,b,0),r 2,where b=1 appears in Mori’s minimal model program and b=1 is a new class of singularities in symplectic birational geometry.We prove that two symplectic 3-orbifolds which are singular flops to each other have isomorphic Ruan cohomology rings.The proof is based on the symplectic cutting argument and virtual localization technique. 展开更多
关键词 Ruan's conjecture singular symplectic flops (r b)-orbiconifold singularity Ruan cohomology virtual localization
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