The biggest insufficiency of the present mathematics is that it consists, in fact, of the eclectic mixture of two different models. In the first model, the world is taken as infinity and what is chosen as an element h...The biggest insufficiency of the present mathematics is that it consists, in fact, of the eclectic mixture of two different models. In the first model, the world is taken as infinity and what is chosen as an element here is the unit. Everything is measured by the multiples of the unit. According to the second model, this world is in unity and its mathematical manifestation is the unit. The world is between zero and one. Everything here is measured by fraction The simplified variants of the mathematical model of the world paves the way for the comparative analysis of its alternative philosophical interpretations.展开更多
Li-ion hybrid supercapacitors(Li-HSCs) have attracted increasing attention as a promising energy storage device with both high power and energy densities. We report a facile two-step hydrothermal method to prepare t...Li-ion hybrid supercapacitors(Li-HSCs) have attracted increasing attention as a promising energy storage device with both high power and energy densities. We report a facile two-step hydrothermal method to prepare the orthorhombic niobium oxide(T-Nb2O5) nanosheets supported on nitrogen and sulfur co-doped graphene(T-Nb205/NS-G) as anode for Li-HSCs. X-ray diffraction and morphological analysis show that the T-Nb2O5 nano sheets successfully and uniformly distributed on the NS-G sheets. The T-Nb2O5/NS-G hybrid exhibits great rate capability(capacity retention of63.1% from 0.05 to 5 A g^-1) and superior cycling stability(a low capacity fading of ~6.4% after 1000 cycles at 0.5 A g^-1).The full-cell consisting of T-Nb2O5/NS-G and active carbon(AC) results in high energy density(69.2 W h kg^-1 at0.1 A g^-1), high power density(9.17 kW kg^-1) and excellent cycling stability(95% of the initial energy after 3000 cycles).This excellent performance is mainly attributed to the highly conductive NS-G sheets, the uniformly distributed T-Nb2O5 nano sheets and the synergetic effects between them. These encouraging performances confirm that the obtained TNb2O5/NS-G has promising prospect as the anode for Li-HSCs.展开更多
TiNb2O7 anode materials(TNO)have unique potential for applications in Li-ion capacitors(LICs)due to their high specific capacity of ca.280 mA h g^-1 over a wide anodic Li-insertion potential window.However,their highr...TiNb2O7 anode materials(TNO)have unique potential for applications in Li-ion capacitors(LICs)due to their high specific capacity of ca.280 mA h g^-1 over a wide anodic Li-insertion potential window.However,their highrate capability is limited by their poor electronic and ionic conductivity.In particular,studies on TNO for LICs are lacking and that for flexible LICs have not yet been reported.Herein,a unique TNO porous electrode with cross-linked nanorods tailored by post-annealing and its application in flexible LICs are reported.This binder-free TNO anode exhibits superior rate performance(~66.3%capacity retention as the rate increases from 1 to 40 C),which is ascribed to the greatly shortened ion-diffusion length in TNO nanorods,facile electrolyte penetration and fast electron transport along the continuous single-crystalline nanorod network.Furthermore,the TNO anode shows an excellent cycling stability up to 2000 cycles and good flexibility(no capacity loss after continuous bending for 500 times).Model flexible LIC assembled with the TNO anode and activated carbon cathode exhibits increased gravimetric and volumetric energy/power densities(~100.6 W h kg^-1/4108.8 W kg^-1;10.7 mW h cm^-3/419.3 mW cm^-3),more superior to previously reported hybrid supercapacitors.The device also efficiently powers an LED light upon 180°bending.展开更多
Li-ion hybrid supercapacitors (Li-HECs) facilitate effective combination of the advantages of supercapacitors and Li-ion batteries (LIBs). However, challenges remain in designing and preparing suitable anode and c...Li-ion hybrid supercapacitors (Li-HECs) facilitate effective combination of the advantages of supercapacitors and Li-ion batteries (LIBs). However, challenges remain in designing and preparing suitable anode and cathode materials, which often require tedious and expensive procedures. Herein, we demonstrated that hollow N-doped carbon capsules (HNC) with and without a Fe304 nanoparticle core can respectively function as the anode and the cathode in very-high-performance Li-HECs. The Fe3Oa@NC anode exhibited a high reversible specific capacity exceeding 1530 mA h g^-1 at 100 mA g^-1 and excellent rate capability (45% capacity retention from 0.1 to 5 A g^-1) and cycle stability (〉97% retention after 100 cycles). Moreover, high rate performance was achieved in a full-cell using the HNC cathode. By combining the respective structural advantages of the components, the hybrid device with Fe3Oa@NC//HN C exhibited a remark- able energy density of 185 W h kg^-1 at a power density of 39 W kg^-1. The hybrid device furnished a battery-inaccessible power density of 28 kW kg^-1 with rapid charging/discharging within 9 s at an energy density of 95 W h kg^-1.展开更多
文摘The biggest insufficiency of the present mathematics is that it consists, in fact, of the eclectic mixture of two different models. In the first model, the world is taken as infinity and what is chosen as an element here is the unit. Everything is measured by the multiples of the unit. According to the second model, this world is in unity and its mathematical manifestation is the unit. The world is between zero and one. Everything here is measured by fraction The simplified variants of the mathematical model of the world paves the way for the comparative analysis of its alternative philosophical interpretations.
基金supported by the National Natural Science Foundation of China(21576138 and 51572127)China-Israel Cooperative Program (2016YFE0129900)+5 种基金Program for NCET-12-0629,PhD Program Foundation of Ministry of Education of China (20133219110018)the Natural Science Foundation of Jiangsu Province (BK20160828)Post-Doctoral Foundation(1501016B)Six Major Talent Summit (XNY-011)PAPD of Jiangsu Provincethe program for Science and Technology Innovative Research Team in Universities of Jiangsu Province,China
文摘Li-ion hybrid supercapacitors(Li-HSCs) have attracted increasing attention as a promising energy storage device with both high power and energy densities. We report a facile two-step hydrothermal method to prepare the orthorhombic niobium oxide(T-Nb2O5) nanosheets supported on nitrogen and sulfur co-doped graphene(T-Nb205/NS-G) as anode for Li-HSCs. X-ray diffraction and morphological analysis show that the T-Nb2O5 nano sheets successfully and uniformly distributed on the NS-G sheets. The T-Nb2O5/NS-G hybrid exhibits great rate capability(capacity retention of63.1% from 0.05 to 5 A g^-1) and superior cycling stability(a low capacity fading of ~6.4% after 1000 cycles at 0.5 A g^-1).The full-cell consisting of T-Nb2O5/NS-G and active carbon(AC) results in high energy density(69.2 W h kg^-1 at0.1 A g^-1), high power density(9.17 kW kg^-1) and excellent cycling stability(95% of the initial energy after 3000 cycles).This excellent performance is mainly attributed to the highly conductive NS-G sheets, the uniformly distributed T-Nb2O5 nano sheets and the synergetic effects between them. These encouraging performances confirm that the obtained TNb2O5/NS-G has promising prospect as the anode for Li-HSCs.
基金supported by the National Natural Science Foundation of China (51672205, 21673169 and 51972257)the National Key R&D Program of China (2016YFA0202602)the Natural Science Foundation of Hubei Province (2018CFB581)
文摘TiNb2O7 anode materials(TNO)have unique potential for applications in Li-ion capacitors(LICs)due to their high specific capacity of ca.280 mA h g^-1 over a wide anodic Li-insertion potential window.However,their highrate capability is limited by their poor electronic and ionic conductivity.In particular,studies on TNO for LICs are lacking and that for flexible LICs have not yet been reported.Herein,a unique TNO porous electrode with cross-linked nanorods tailored by post-annealing and its application in flexible LICs are reported.This binder-free TNO anode exhibits superior rate performance(~66.3%capacity retention as the rate increases from 1 to 40 C),which is ascribed to the greatly shortened ion-diffusion length in TNO nanorods,facile electrolyte penetration and fast electron transport along the continuous single-crystalline nanorod network.Furthermore,the TNO anode shows an excellent cycling stability up to 2000 cycles and good flexibility(no capacity loss after continuous bending for 500 times).Model flexible LIC assembled with the TNO anode and activated carbon cathode exhibits increased gravimetric and volumetric energy/power densities(~100.6 W h kg^-1/4108.8 W kg^-1;10.7 mW h cm^-3/419.3 mW cm^-3),more superior to previously reported hybrid supercapacitors.The device also efficiently powers an LED light upon 180°bending.
基金supported by the National Natural Science Foundation of China (51601127, 21603162 and 51671145)China Post-doctoral Science Fund (2015M581304)+1 种基金Tianjin Municipal Education Commission, Tianjin Municipal Science and Technology Commission (16ZXCLGX00120)the Fundamental Research Funds of Tianjin University of Technology
文摘Li-ion hybrid supercapacitors (Li-HECs) facilitate effective combination of the advantages of supercapacitors and Li-ion batteries (LIBs). However, challenges remain in designing and preparing suitable anode and cathode materials, which often require tedious and expensive procedures. Herein, we demonstrated that hollow N-doped carbon capsules (HNC) with and without a Fe304 nanoparticle core can respectively function as the anode and the cathode in very-high-performance Li-HECs. The Fe3Oa@NC anode exhibited a high reversible specific capacity exceeding 1530 mA h g^-1 at 100 mA g^-1 and excellent rate capability (45% capacity retention from 0.1 to 5 A g^-1) and cycle stability (〉97% retention after 100 cycles). Moreover, high rate performance was achieved in a full-cell using the HNC cathode. By combining the respective structural advantages of the components, the hybrid device with Fe3Oa@NC//HN C exhibited a remark- able energy density of 185 W h kg^-1 at a power density of 39 W kg^-1. The hybrid device furnished a battery-inaccessible power density of 28 kW kg^-1 with rapid charging/discharging within 9 s at an energy density of 95 W h kg^-1.