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随机取向内外混合凝聚粒子辐射特性 被引量:2
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作者 类成新 吴振森 冯东太 《红外与激光工程》 EI CSCD 北大核心 2013年第10期2692-2696,共5页
采用离散偶极子近似方法对随机取向混合凝聚粒子在内外混合状态下的光学截面、单次散射反照率以及非对称因子等辐射特性参量进行了数值计算,详细讨论了混合方式、混合比等因素对混合凝聚粒子辐射特性的影响。研究表明,混合凝聚粒子的混... 采用离散偶极子近似方法对随机取向混合凝聚粒子在内外混合状态下的光学截面、单次散射反照率以及非对称因子等辐射特性参量进行了数值计算,详细讨论了混合方式、混合比等因素对混合凝聚粒子辐射特性的影响。研究表明,混合凝聚粒子的混合方式对非对称因子的影响非常大,对散射截面和单次散射反照率的影响比较大,但是对吸收和消光截面的影响不明显。随着凝聚粒子中基本粒子粒径和数量的增大,非对称因子、散射截面以及单次散射反照率受混合方式的影响变得愈加明显。此外,混合比的变化对不同混合状态下的凝聚粒子的辐射特性参量均存在不同程度的影响,并且此影响随着基本粒子粒径和数量的变化而显著变化。混合比相同情况下,所有外混合凝聚粒子的散射截面均大于内混合凝聚粒子的散射截面,而单次散射反照率却相应减小。 展开更多
关键词 混合凝聚粒子 辐射特性 Bruggeman有效介质理论 离散偶极子近似方法
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用于三维软组织实时切割的混合凝聚有限元模型
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作者 吴雯 孙剑 王平安 《计算机学报》 EI CSCD 北大核心 2002年第9期953-958,共6页
随着近几年来微创外科的迅速发展 ,虚拟内窥镜手术模拟系统作为手术训练、规划的有效手段 ,已逐渐成为研究的热点 .根据实际手术的需要 ,虚拟手术系统应该不仅能够实时模拟软组织的变形 ,而且也同样可以对软组织的切割、缝合操作进行实... 随着近几年来微创外科的迅速发展 ,虚拟内窥镜手术模拟系统作为手术训练、规划的有效手段 ,已逐渐成为研究的热点 .根据实际手术的需要 ,虚拟手术系统应该不仅能够实时模拟软组织的变形 ,而且也同样可以对软组织的切割、缝合操作进行实时模拟 .该文提出了一个用于虚拟手术模拟、三维软组织变形及切割的有限元模型——混合凝聚有限元模型 .该模型的显著优点在于其可以在当前的 PC机平台上有效地对软组织变形及具有拓扑改变的切割操作进行实时模拟 . 展开更多
关键词 三维软组织 实时切割 混合凝聚 有限元模型 虚拟内窥镜手术 线性弹性模型 外科手术 医学
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随机分布黑碳-硅酸盐混合凝聚粒子的消光特性研究 被引量:5
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作者 类成新 吴振森 冯东太 《光学学报》 EI CAS CSCD 北大核心 2012年第4期269-274,共6页
基于分形理论,采用蒙特卡罗方法对随机分布的混合凝聚粒子的空间结构进行了仿真模拟。利用Bruggeman有效介质理论得到了占有不同体积份额黑碳的内混合凝聚粒子的等效复折射率。采用离散偶极子近似方法对随机分布混合凝聚粒子在内外混合... 基于分形理论,采用蒙特卡罗方法对随机分布的混合凝聚粒子的空间结构进行了仿真模拟。利用Bruggeman有效介质理论得到了占有不同体积份额黑碳的内混合凝聚粒子的等效复折射率。采用离散偶极子近似方法对随机分布混合凝聚粒子在内外混合状态下的吸收、散射和消光效率因子等消光特性参量进行了数值计算,深入探讨了混合方式、容积含量、入射波长以及基本粒子粒径和数量对混合凝聚粒子消光特性的影响规律。通过将所得数值结果与T矩阵方法的数值结果进行比较发现,两种数值方法计算的结果非常相近。结果表明,随机分布混合凝聚粒子的散射效率因子对混合方式非常敏感,消光效率因子对混合方式较敏感,而吸收效率因子对混合方式不敏感。随着凝聚粒子尺度参数的增大,混合方式对散射和消光效率因子的影响逐渐显著。内外混合方式下,随着黑碳体积比的增大随机分布混合凝聚粒子的吸收、散射和消光效率因子均近似线性增大,并且增大的幅度随着粒子尺度参数的增大而增大。 展开更多
关键词 散射 混合凝聚粒子 Bruggeman有效介质理论 离散偶极子近似方法 消光特性
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关于夸克凝聚和混合凝聚平移不变性的讨论
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作者 卞建国 《高能物理与核物理》 CSCD 北大核心 1994年第6期534-540,共7页
讨论夸克凝聚和混合凝聚在Lorentz规范下的泰勒展开式,这两个展开式可用来计算算符乘积展开中非微扰修正项的Wilson系数.与目前在QCD求和规则方法中所应用的、在固定点规范下的相应展开式相比,新的展开式具有平移不... 讨论夸克凝聚和混合凝聚在Lorentz规范下的泰勒展开式,这两个展开式可用来计算算符乘积展开中非微扰修正项的Wilson系数.与目前在QCD求和规则方法中所应用的、在固定点规范下的相应展开式相比,新的展开式具有平移不变性的优点. 展开更多
关键词 夸克凝聚 混合凝聚 平移不变性
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混合Bose-Einstein凝聚的解的整体稳定性 被引量:3
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作者 邓艳萍 张健 《四川师范大学学报(自然科学版)》 CAS CSCD 2003年第3期225-227,共3页
在三维空间中研究描述混合Bose Einstein凝聚(BEC)的耦合Gross Pitaevskii(GP)方程组,讨论了其Cauchy问题解的局部适定性,建立了由GP方程组产生的流形下的不变集合,利用不变集理论得到了Cauchy问题解的整体稳定性的一个充分条件.
关键词 混合的Bose-Einstein凝聚 耦合 Gross-Pitaevakii方程组 整体稳定性
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混合Bose-Einstein凝聚的不稳定性
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作者 邓艳萍 张健 《工程数学学报》 CSCD 北大核心 2004年第5期680-684,共5页
本文研究描述混合Bose-Einstein凝聚的耦合Gross-Pitaevskii方程组的Cauchy问题,利用不变集理论,得到了混合Bose-Einstein凝聚的不稳定性。
关键词 混合Bose-Einstein凝聚 不稳定性 耦合 Gross-Pitaevskii方程组 不变集
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在Dyson-Schwinger方程中夸克-胶子的混合真空凝聚(英文) 被引量:1
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作者 周丽娟 马维兴 《高能物理与核物理》 EI CSCD 北大核心 2005年第8期757-760,共4页
基于夸克传播子的DysonSchwinger方程,计算了夸克胶子混合真空凝聚和夸克真空凝聚.这些凝聚不仅联系着夸克在真空态中的虚度,而且也表征了真空中夸克分布的空间宽度.真空凝聚的存在直接反映着QCD真空的非微扰结构.计算表明上夸克与下夸... 基于夸克传播子的DysonSchwinger方程,计算了夸克胶子混合真空凝聚和夸克真空凝聚.这些凝聚不仅联系着夸克在真空态中的虚度,而且也表征了真空中夸克分布的空间宽度.真空凝聚的存在直接反映着QCD真空的非微扰结构.计算表明上夸克与下夸克的虚度为λ2u,d=0.7GeV2,奇异夸克的虚度为λ2s=1.6GeV2.这些结果与许多用完全不同的方法得到的结果一致. 展开更多
关键词 DYSON-SCHWINGER方程 夸克-胶子 混合真空凝聚 DSEs 虚度 非微扰QCD
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改善ZnO酸浸矿浆澄清过滤性能的机理和方法
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作者 刘一宁 《湖南有色金属》 CAS 北大核心 1992年第2期106-110,96,共6页
本文叙述了添加混合凝聚剂改善 ZnO 酸浸矿浆的澄清特性和提高置换矿浆压滤速度的机理和效果。在酸浸矿浆中加入适量的混合凝聚剂,可使酸上清含固量下降至2—3g/l,置换压滤速度提高2—4倍、锢的回收率提高3.9%以上,具有明显的社会效益... 本文叙述了添加混合凝聚剂改善 ZnO 酸浸矿浆的澄清特性和提高置换矿浆压滤速度的机理和效果。在酸浸矿浆中加入适量的混合凝聚剂,可使酸上清含固量下降至2—3g/l,置换压滤速度提高2—4倍、锢的回收率提高3.9%以上,具有明显的社会效益和经济效益。 展开更多
关键词 ZNO 酸浸矿浆 澄清 置换压滤 混合凝聚
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改善氧化锌酸浸矿浆澄清过滤性能的研究
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作者 刘一宁 《株冶科技》 1992年第1期54-59,共6页
关键词 氧化锌 酸浸矿浆 澄清 混合凝聚
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非线性Schrdinger方程组初值问题的驻波解 被引量:4
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作者 邓艳萍 周钰谦 《四川师范大学学报(自然科学版)》 CAS CSCD 北大核心 2013年第2期243-246,共4页
研究了三维空间中带调和势的非线性Schringer方程组,即耦合Gross-Pitaevskii方程组.该方程组在物理学上用来描述Bose-Einstein凝聚.从一个紧性引理出发,利用变分法得到方程组初值问题驻波解的存在性,并证明了驻波解的稳定性.
关键词 混合Bose—Einstein凝聚 耦合Gross—Pitaevskii方程组 变分法 驻波解 存在性 稳定性
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Utilization of Concrete Waste Aggregates Using Geopolymer Cement 被引量:1
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作者 Sotya Astutiningsih Henki Wibowo Ashadi +2 位作者 Hendra Widhatra Kresnadya Desha Rousstia Maria Elizabeth Suryatriyastuti 《Journal of Civil Engineering and Architecture》 2010年第6期11-15,共5页
Reuse of concrete waste, especially in large quantity, can save not only material but also cost for its disposal. This paper presents experiment results on the use of fine and coarse aggregates from concrete waste in ... Reuse of concrete waste, especially in large quantity, can save not only material but also cost for its disposal. This paper presents experiment results on the use of fine and coarse aggregates from concrete waste in geopolymer mortars and concretes. Geopolymeric cement is an inorganic compounds of aluminosilicates synthesized from precursors with high content of silica and alumina activated by alkali silicate solutions. Geopolymer in this experiment was synthesized from fly ash as the precursor and sodium silicate solution as the activator. Hardening of geopolymers was performed by heating the casted paste in an oven at -60~Cfor 3 to 36 hours. Compressive strength of geopolymer pastes and mortars using either fresh or waste fine aggregates were in the range of 19-26 MPa. Hardening time of 3 hours at 60~C followed by leaving the test pieces at room temperature for 7 day before testing results in similar strength to that of mortars cured for 36 hours at 60~C followed by leaving the samples at room temperature for 3 days. It suggests that optimum strength can be achieved by combination of heating time and rest period before testing, i.e the specimens age. Applying mix design with a target strength of 40 MPa, conventional Portland cement concretes using fresh aggregates reached 70% of its target strength at day-7. Compressive strength of geopolymer concretes with waste aggregates was -25 MPa at day-3 while geopolymer concretes with fresh aggregates achieved -39 MPa at day-3. It can be concluded that geopolymer concretes can achieve the target strength in only 3 days. However, the expected reinforcing effect of coarse aggregates in concrete was ineffective if waste coarse aggregates were used as the strength of the concretes did not increase significantly from that of the mortars. On the other hand, waste fine aggregates can be reused for making geopolymer mortars having the same strength as the geopolymer mortars using fresh aggregates. 展开更多
关键词 GEOPOLYMER concrete waste aggregates MORTAR CONCRETE compressive strength.
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Water Permeability in Fly Ash-Based Geopolymer Concrete 被引量:1
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作者 Charin Sanawong Wichian Chalee 《Journal of Civil Engineering and Architecture》 2010年第3期15-19,共5页
This research investigated the water permeability coefficient of fly ash-based geopolymer concrete. The effect of sodium hydroxide (Na(OH)) concentrations and Si/AI ratios on water permeability and compressive str... This research investigated the water permeability coefficient of fly ash-based geopolymer concrete. The effect of sodium hydroxide (Na(OH)) concentrations and Si/AI ratios on water permeability and compressive strength of geopolymer concretes were studied. The geopolymer concrete were prepared from Mae Moh fly ash with sodium silicate (Na2SiO3) and sodium hydroxide (Na(OH)) solutions. In the first group, concentration of Na(OH) was varied at 8, 10, 12, and 14 molar and the Si/AI ratio was kept constant at 1.98. In the second group, a concentration of Na(OH) was kept constant at 14 molar and the Si/AI ratio was varied at 2.2, 2.4, 2.6, and 2.8. The hardened concretes were air-cured in laboratory. The compressive strength and water permeability were tested at the age of 28 and 60 days. The results showed that compressive strengths of geopolymer concrete significantly increased with the increase of a concentration of Na(OH) and Si/AI ratio. The water permeability coefficients increase with the decrease of compressive strength. In addition, the high reduction of water permeability coefficients with time was found in geopolymer concrete with lower Na(OH) concentration than that higher Na(OH) concentration. 展开更多
关键词 Fly ash-based geopolymer concrete water permeability Na(OH) concentration Si/AI ratio
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Preparation and properties of geopolymer-lightweight aggregate refractory concrete 被引量:1
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作者 胡曙光 吴静 +3 位作者 杨文 何永佳 王发洲 丁庆军 《Journal of Central South University》 SCIE EI CAS 2009年第6期914-918,共5页
Geopolymer-lightweight aggregate refractory concrete (GLARC) was prepared with geopolymer and lightweight aggregate. The mechanical property and heat-resistance (950 ℃) of GLARC were investigated. The effects of size... Geopolymer-lightweight aggregate refractory concrete (GLARC) was prepared with geopolymer and lightweight aggregate. The mechanical property and heat-resistance (950 ℃) of GLARC were investigated. The effects of size of aggregate and mass ratio of geopolymer to aggregate on mechanical and thermal properties were also studied. The results show that the highest compressive strength of the heated refractory concrete is 43.3 MPa,and the strength loss is only 42%. The mechanical property and heat-resistance are influenced by the thickness of geopolymer covered with aggregate,which can be expressed as the quantity of geopolymer on per surface area of aggregate. In order to show the relationship between the thickness of geopolymer covered with aggregate and the thermal property of concrete,equal thickness model is presented,which provides a reference for the mix design of GLARC. For the haydite sand with size of 1.18-4.75 mm,the best amount of geopolymer per surface area of aggregate should be in the range of 0.300-0.500 mg/mm2. 展开更多
关键词 refractory concrete GEOPOLYMER lightweight aggregate thermal property equal thickness model
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Bond strength improvement of GFRP rebars with different rib geometries 被引量:12
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作者 HAO Qing-duo WANG Yan-lei +1 位作者 ZHANG Zhi-chun OU Jin-ping 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2007年第9期1356-1365,共10页
Based on the Canadian Standards Association (CSA) criteria,105 pullout specimens were tested to investigate the effect of different rib geometries on bond strength of glass fiber reinforced polymer (GFRP) rebars embed... Based on the Canadian Standards Association (CSA) criteria,105 pullout specimens were tested to investigate the effect of different rib geometries on bond strength of glass fiber reinforced polymer (GFRP) rebars embedded in concrete. Two kinds of conventional reinforcing rebars were also studied for comparison. Each rebar was embedded in a 150 mm concrete cube,with the embedded length being four times the rebar diameter. The experimental parameters were the rebar type,rebar component,rebar diameter,rebar surface texture,rib height,rib spacing and rib width. Theoretical analysis was also carried out to explain the experimental phenomena and results. The experimental and theoretical results indicated that the bond strength of GFRP rebars was about 13%~35% lower than that of steel rebars. The bond strength and bond-slip behavior of the specially machined rebars varied with the rebar type,rebar diameter,rebar surface texture,rib height,rib spacing and rib width. Using the results,design recom-mendations were made concerning optimum rib geometries of GFRP ribbed rebars with superior bond-slip characteristics,which concluded that the optimal rib spacing of ribbed rebars is the same as the rebar diameter,and that the optimal rib height is 6% of the rebar diameter. 展开更多
关键词 GFRP rebars CONCRETE Pullout test Bond strength Rib geometries Optimal surface configuration
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Coagulation behavior of polyaluminum chloride: Effects of pH and coagulant dosage 被引量:12
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作者 魏宁 张忠国 +3 位作者 刘丹 吴月 王军 汪群慧 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第6期1041-1046,共6页
Coagulation mechanisms of polyaluminum chloride(PACl) at various dosages were studied using a conventional jar test at different final and initial pH values during treating kaolin suspension. The optimal final pH and ... Coagulation mechanisms of polyaluminum chloride(PACl) at various dosages were studied using a conventional jar test at different final and initial pH values during treating kaolin suspension. The optimal final pH and dosages for PACl were obtained based on residual turbidity and zeta potential of flocs. The coagulation zones at various PACl dosages and solution p H values were developed and compared with those of alum. It is found that the optimal mechanism under acidic condition is charge neutralization, while alkaline condition will facilitate the coagulation of PACl. Both charge neutralization coagulation and sweep coagulation can achieve high coagulation efficiency under the alkaline condition ranging from final p H 7.0 to 10.0. Stabilization, charge neutralization destabilization, restabilization and sweep zones occur successively with increasing PACl dosages with the final p H values fixed at 7.0 and 8.0, but restabilization zone disappears at final p H 10.0. When the final p H is not controlled and consequently decreases with increasing PACl dosage, no typical sweep zone can be observed and the coagulant efficiency decreases at high PACl dosage. It seems that the final pH is more meaningful than the initial p H for coagulation. Charge neutralization coagulation efficiency is dominated by zeta potential of flocs and PACl precipitates. The charge neutralization and sweep coagulation zones of PACl are broader in the ranges of coagulant dosage and p H than those of alum. The results are helpful for us to treat water and wastewater using PACl and to understand the coagulation process of PACl. 展开更多
关键词 SEPARATION COAGULATION AGGREGATION PRECIPITATION Charge neutralization Sweep flocculation Polyaluminum chloride
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Coagulation-flocculation process for combined sewage in Shanghai 被引量:1
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作者 黄天寅 《Journal of Chongqing University》 CAS 2004年第2期25-29,共5页
The effects of the coagulation-flocculation process using polyaluminium chloride (PAC) and its aids on the removal of organics and nutrient in the combined sewage from Shanghai Zhuyuan First Municipal Wastewater Treat... The effects of the coagulation-flocculation process using polyaluminium chloride (PAC) and its aids on the removal of organics and nutrient in the combined sewage from Shanghai Zhuyuan First Municipal Wastewater Treatment Plant are studied. The coagulant aids include cationic polyacrylamide (PAM), polyvinyl alcohol (PVA), activated silica (AS) and a kind of polyelectrolyte called AN prepared by the authors. The coagulating solution was added to the glass jar holding 1 L wastewater and stirred to a uniform mixture which was stilled to let the supernatant turn out. The supernatant was analyzed to see the removal efficiencies of suspended solid (SS), chemical oxygen demand (COD), soluble chemical oxygen demand (S-COD), total phosphorus (TP) and orthophosphate (PO4 -P). It is found that PAC is efficient in reducing those five matters, PAM, PVA and 3? AN each faciliates the reduction of TP, SS, COD and S-COD and has little contribution to the removal of ammonia nitrigen and orthophosphate, and AS is noneffective at all. The coagulation-flocculation process with PAC has demonstrated applicable to the treatment of combined sewage in Shanghai, and it involves mainly the sweep coagulation mechanism and maybe some more complicated mechanism as well. 展开更多
关键词 COAGULATION polyaluminium chloride coagulant aids combined sewage
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Effects of Slow-Mixing on the Coagulation Performance of Polyaluminum Chloride (PACI) 被引量:3
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作者 张忠国 刘丹 +4 位作者 胡丹丹 李多 任晓晶 程言君 栾兆坤 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第3期318-323,共6页
Conventional jar tests and on-line size monitoring were used to investigate the effects of slow-mixing intensity and duration on residual turbidity and floc size during charge neutralization coagulation and sweep floc... Conventional jar tests and on-line size monitoring were used to investigate the effects of slow-mixing intensity and duration on residual turbidity and floc size during charge neutralization coagulation and sweep floc- culation with polyaluminum chloride. The compensatory effect of slow-mixing on coagulation performance fol- low!ng inadequate_or excessive rapid-mi_xing was also examined. It is found that slowTmixing intensity has a more marked positive ettect on charge neutralization coas;ulatlon tlaan on sweep tlocculatlon. llle optimal root-mean- square velocity gradient, G, for slow-mixing is 15 s-' for both coagulation mechanisms, and charge neutralization coagulation requires a longer slow-mixing duration. The optimal slow-mixing duration, based on residual turbidity,is longer than the time to tbrm the largest mean Ilocs. The optimal product of G and mixing duration, GT, lbr slow-mixing during charge neutralization coagulation (13500) are higher than that during sweep flocculation (4500) and both are less than the range of values recommended by the American Water Works Association (24000-84000).The optimal GT value under various slow-mixing conditions increases with G. Appropriate extension'of slow-mixing duration during charge neutralization coagulation can improve coagulation performance after an inadequate or excessive rapid-mixing duration, but during sweep flocculation, appropriate shortening of slow-mixing duration after an excessive rapid-mixing or appropriate extension of slow-mixing duration after an inadequate rapid-mixing is favorable. 展开更多
关键词 slow-mixing polyaluminum chloride charge neutralization coagulation -sweep-flocculati-on GT value
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Mechanical properties of pervious cement concrete 被引量:6
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作者 陈瑜 王科进 梁地 《Journal of Central South University》 SCIE EI CAS 2012年第11期3329-3334,共6页
Compressive and flexural strength,fracture energy,as well as fatigue property of pervious cement concrete with either supplementary cementitious materials (SCMs) or polymer intensified,were analyzed.Test results show ... Compressive and flexural strength,fracture energy,as well as fatigue property of pervious cement concrete with either supplementary cementitious materials (SCMs) or polymer intensified,were analyzed.Test results show that the strength development of SCM-modified pervious concrete (SPC) differs from that of polymer-intensified pervious concrete (PPC),and porosity has little effect on their strength growth.PPC has higher flexural strength and remarkably higher flexural-to-compressive strength ratio than SPC at the same porosity level.Results from fracture test of pervious concrete mixes with porosity around 19.5% show that the fracture energy increases with increasing the dosage of polymer,reflecting the ductile damage features rather than brittleness.PPC displays far longer fatigue life than SPC for any given failure probability and at any stress level.It is proved that two-parameter Weibull probability function describes the flexural fatigue of pervious concrete. 展开更多
关键词 pervious concrete STRENGTH FRACTURE fatigue life
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Retrofitting of RC Slabs Against Explosive Loads 被引量:1
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作者 WU Chengqing 0EHLERS Deric John XIA Shaohua 《Transactions of Tianjin University》 EI CAS 2006年第B09期88-93,共6页
With the increase of terrorist bomb attacks on buildings, there is a need to develop advanced retrofitting techniques to strengthen structures against blast loads. Currently, several guidelines including an Australian... With the increase of terrorist bomb attacks on buildings, there is a need to develop advanced retrofitting techniques to strengthen structures against blast loads. Currently, several guidelines including an Australian version for retrofitting reinforced concrete (RC) structures are available for the design of retrofitting systems against seismic and monotonic loads using steel or fibre reinforced polymer (FRP) plates that can be either adhesively bonded to the surface or near surface mounted to the concrete cover. However, none of these guidelines provide advice suitable for retrofitting structures subjected to blast loads. In this paper, numerical models are used to simulate the performance of retrofitted RC slabs subjected to blast loads. Airblast pressure distributions on the surface of the slabs estimated in a previous study are used as input in the analysis. A material damage model developed previously for concrete and an elastoplastic model for steel bars are employed in this research for modelling reinforced concrete behaviour due to explosive loads. The material models and blast loading are coded into a finite element computer program LS-DYNA3D to do the analysis. With the numerical model, parametric studies are conducted to investigate RC slabs retrofitted by either externally bonded or near-surface mounted plates or GFRP sheets subjected to blast loads. Discussion is made on the effectiveness of the retrofitting system for RC slabs against blast loads. 展开更多
关键词 RETROFIT explosion fibre reinforced polymer SLAB
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Influence of polyethylene glycol on pore structure and electric double-layer capacitance of carbon xerogel
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作者 侯朝辉 李新海 +2 位作者 何则强 刘恩辉 邓凌峰 《Journal of Central South University of Technology》 2004年第3期255-260,共6页
Mesoporous polyethylene glycol-resorcinol and formaldehyde(PEG-RF) carbon xerogels were prepared by a new polymer blend method in which PEG-RF mixed organic xerogels were synthesized by blending thermally unstable p... Mesoporous polyethylene glycol-resorcinol and formaldehyde(PEG-RF) carbon xerogels were prepared by a new polymer blend method in which PEG-RF mixed organic xerogels were synthesized by blending thermally unstable polyethylene glycol with organic monomers, resorcinol and formaldehyde and then subjected to pyrolization at 1 000 ℃. The influences of mass ratio of PEG to the theoretical yield of RF xerogel, m(PEG)/m(RF) and the (relative) molecular mass of PEG on the pore structure and electric double layer capacitance(EDLC) performance of PEG-RF carbon xerogels were investigated. The results show that PEG under different conditions leads to the difference of phase separation structure of the polymer blend and thus the change of pore structure of PEG-RF carbon xerogels. Specific surface area and capacity of PEG-RF carbon xerogels in 30% H2SO4 solution can reach (755 m2/g) and 150 F/g, respectively. Their surface can be fully utilized to form electric double layer. However, the pore structure differences of PEG-RF carbon xerogels result in their different EDLC performances. The distributed capacitance effect increases with decreasing the pore size of PEG-RF carbon xerogels. 展开更多
关键词 polymer blend method polyethylene glycol carbon xerogel electric double-layer capacitance
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