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基于电化学重氮还原的碳膜电极表面修饰及功函调控
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作者 许晓娜 史成乾 +6 位作者 丁小海 薛俊红 王冬 田丽贤 李柏力 朱艳英 于曦 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2021年第6期1908-1913,共6页
基于高温裂解光刻胶制备的碳薄膜(PPF)是一种新型的性能优异的碳基电极.为了拓展其在功能器件中的应用,利用电化学重氮还原法在PPF电极表面生长了三氟甲基苯胺重氮盐(CF3-PD)和对氨基苯甲醚重氮盐(OCH3-PD)两种组分的混合膜.通过调节两... 基于高温裂解光刻胶制备的碳薄膜(PPF)是一种新型的性能优异的碳基电极.为了拓展其在功能器件中的应用,利用电化学重氮还原法在PPF电极表面生长了三氟甲基苯胺重氮盐(CF3-PD)和对氨基苯甲醚重氮盐(OCH3-PD)两种组分的混合膜.通过调节两组分溶液在混合膜中的摩尔浓度比例,实现了对PPF电极功函的可控调节.紫外光电子能谱(UPS)和开尔文探针显微镜(KPFM)对修饰前后PPF电极功函(φ)的表征表明,随着混合溶液中CF3-PD组分的摩尔分数从0增至100%,PPF电极的φ(4.75 eV)从4.5 eV梯度增至5.14 eV.研究结果实现了可在一定范围内"定制"PPF电极功函,为碳膜电极在分子光电器件中的应用奠定了基础. 展开更多
关键词 碳膜电极 重氮还原反应 混合分子层 功函数
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Direct Numerical Simulation of Gas-Solid Two-Phase Mixing Layer
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作者 WenchunLI GuilinHU ZheZHOU JianrenFAN KefaCEN 《Journal of Thermal Science》 SCIE EI CAS CSCD 2005年第1期41-47,共7页
In this paper, the spatially evolving of the higher Reynolds numbers gas-solid mixing layer under compressible conditions was investigated by a new direct numerical simulation technology. A high-resolution solver was ... In this paper, the spatially evolving of the higher Reynolds numbers gas-solid mixing layer under compressible conditions was investigated by a new direct numerical simulation technology. A high-resolution solver was performed for the gas-phase flow-field, particles with different Stokes numbers were traced by the Lagrangian approach based on one-way coupling. The processes of the vortex rolling up and pairing in the two-dimensional mixing layer were captured precisely. The large-scale structures developed from the initial inflow are characterized by the counter-rotating vortices. The mean velocity and the fluctuation intensities profiles agree well with the experimental data. Particles with smaller Stokes numbers accumulate at the vortex centers due to the smaller aerodynamic response time; particles with moderate Stokes numbers tend to orbit around individual streamwise vortices and in the periphery of paring vortices; particles with larger Stokes numbers disperse less evenly, showing a concentration distribution in the flow field. 展开更多
关键词 direct numerical simulation gas-solid mixing layer VORTEX particle dispersion.
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