碳捕获与封存技术是一种具有前景的CO2减排策略。本工作采用巨正则蒙特卡洛模拟研究了温度为298 K、压强在0~5 k Pa范围内三种混合超微孔材料SIFSIX-X-Cu(以SiF62–排列, Cu为金属中心, X=2, 3, O)中CO2/N2吸附与分离的行为。结果显示,...碳捕获与封存技术是一种具有前景的CO2减排策略。本工作采用巨正则蒙特卡洛模拟研究了温度为298 K、压强在0~5 k Pa范围内三种混合超微孔材料SIFSIX-X-Cu(以SiF62–排列, Cu为金属中心, X=2, 3, O)中CO2/N2吸附与分离的行为。结果显示,相比于SIFSIX-2-Cu, SIFSIX-3-Cu和SIFSIX-O-Cu中CO2在0.5 k Pa就达到吸附饱和,且在1 k Pa下的吸附量分别达到了2.70与2.39 mmol·g–1。CO2/N2混合气体中CO2的吸附量几乎没有下降。SIFSIX-3-Cu和SIFSIX-O-Cu具有接近于CO2分子动力学直径的孔径,对CO2亲和力较大,吸附热分别达到了59和66 k J·mol–1。密度泛函理论分析发现,在两种结构中每个孔隙只吸附一个CO2分子,且几乎处于孔道的中心。本工作为低压下吸附与分离CO2的混合超微孔材料的开发提供了理论指导。展开更多
The core-shell structure silicon-resin precursor powders were synthesized through coat-mix process and addition of Al2O3-SiO2-Y2O3 composite additives.A series of porous silicon carbide ceramics were produced after mo...The core-shell structure silicon-resin precursor powders were synthesized through coat-mix process and addition of Al2O3-SiO2-Y2O3 composite additives.A series of porous silicon carbide ceramics were produced after molding,carbonization and sintering.The phase,morphology,porosity,thermal conductivity,thermal expansion coefficient,and thermal shock resistance were analyzed.The results show that porous silicon carbide ceramics can be produced at low temperature.The grain size of porous silicon carbide ceramic is small,and the thermal conductivity is enhanced significantly.Composite additives also improve the thermal shock resistance of porous ceramics.The bending strength loss rate after 30 times of thermal shock test of the porous ceramics which were added Al2O3-SiO2-Y2O3 and sintered at 1 650 ℃ is only 6.5%.Moreover,the pore inside of the sample is smooth,and the pore size distribution is uniform.Composite additives make little effect on the thermal expansion coefficient of the porous silicon carbide ceramics.展开更多
Membrane filtration technology combined with coagulation is widely used to purify river water.In this study,microfiltration(MF)and ultrafiltration(UF)ceramic membranes were combined with coagulation to treat local riv...Membrane filtration technology combined with coagulation is widely used to purify river water.In this study,microfiltration(MF)and ultrafiltration(UF)ceramic membranes were combined with coagulation to treat local river water located at Xinghua,Jiangsu province,China.The operation parameters,fouling mechanism and pilot-scale tests were investigated.The results show that the pore size of membrane has small effect on the pseudo-steady flux for dead-end filtration,and the increase of flux in MF process is more than that in UF process for cross-flow filtration with the same increase of cross-flow velocity.The membrane pore size has little influence on the water quality.The analysis on membrane fouling mechanism shows that the cake filtration has significant influence on the pseudo-steady flux and water quality for the membrane with pore size of 50,200 and 500 nm.For the membrane with pore size of 200 nm and backwashing employed in our pilot study,a constant flux of 150L·m 2·h 1was reached during stable operation,with the removal efficiency of turbidity,total organic carbon(TOC)and UV254 higher than 99%,45%and 48%,respectively.The study demonstrates that coagulation-porous ceramic membrane hybrid process is a reliable method for river water purification.展开更多
Four fat and elongated(F&E)contents(0%,original,30%,and 40%)were investigated to evaluate the effects of F&Eparticles on the performance of porous asphalt mixture(P A).Laboratory tests including volumetric det...Four fat and elongated(F&E)contents(0%,original,30%,and 40%)were investigated to evaluate the effects of F&Eparticles on the performance of porous asphalt mixture(P A).Laboratory tests including volumetric determination,two-dimensional image analysis,Cantabro loss tests,breakdown tests,and permeability tests were conducted to evaluate the volumetric properties,the state of stone-onstone contact,durability,skeleton stability and permeability of PA,respectively.The test results indicate that the F&E content was a significant factor for total air voids,aggregate skeleton break down,and permeability.The functionality,rutting resistance,long-term durability,and skeleton stability decrease with the increase of F&E content since F&E aggregates in porous asphalt mixtures have a tendency to breakdown.Compared with traditional dense graded mixtures,PA is more sensitive to the F&E content due to an open graded aggregate structure.Therefore,the stricter requiement for F&E content should be met for porous asphalt mixtures than the one for traditional deese graded mixture.展开更多
The viscosity-time curve of a single-component polyurethane(PU)was examined to determine the mixing and compacting temperatures of its mixture and investigate the curing and mechanical properties of single-component P...The viscosity-time curve of a single-component polyurethane(PU)was examined to determine the mixing and compacting temperatures of its mixture and investigate the curing and mechanical properties of single-component PU porous elastic mixture(PPEM).The curing properties of the single-component PU and PPEM were studied with Fourier transform infrared spectroscopy(FTIR)and Marshall test.The mechanical properties of PPEM were explored via the following tests:rutting test,3-point bending test,soaked Marshall stability test,freeze-thaw splitting test,and Cantabro test.The effects of a water bath on the stability of aggregate-PU/asphalt mortar-aggregate systems were evaluated through a pull-out test and a shear test.The results show that the recommended mixing temperatures of toluene diisocyanate and methylene diphenyl diisocyanate range from 75 to 80℃and from 64 to 68℃,respectively.Room temperature(25℃)can be adopted as the compacting temperature of PPEM.PPEM can be fully cured in 4 d.Nevertheless,the water sprinkle method can obviously shorten the full curing time of PPEM.PPEM exhibites good resistance to rutting,brittle cracking,and raveling.The adhesive and shear strength of aggregate-PU/asphalt mortar-aggregate systems are negatively related to water bath duration.展开更多
We study the macromixing behavior of single and multi-orifice-impinging transverse(MOIT) jet mixers with crossflow, in particular, the overall mixing time and the back-splash mixing time of the injected flow with the ...We study the macromixing behavior of single and multi-orifice-impinging transverse(MOIT) jet mixers with crossflow, in particular, the overall mixing time and the back-splash mixing time of the injected flow with the crossflow, using the PLIF technique. It is found that for a given mixer configuration, there is a critical jet-tocrossflow velocity ratio rcat which the back-splash begins to occur. Further increase in the velocity ratio r leads to sharp increase in the back-splash mixing time, which can offset the intensification of the downstream mixing. The dimensionless overall mixing time decreases as r increases to reach either a plateau or a local minimum, and the corresponding r value represents the optimal velocity ratio roptfor the macromixing. The momentum ratio of the two liquid streams is a key factor determining rcand ropt. For a larger scale mixer, a higher momentum ratio is required to achieve the optimal macromixing with the minimum dimensionless overall mixing time.展开更多
Worldwide environment has resulted in a limit on the sulfur content of gasoline.It is urgent to investigate the desulfurization of gasoline.The polydimethylsiloxane(PDMS)/polyetherimide(PEI)composite membranes were pr...Worldwide environment has resulted in a limit on the sulfur content of gasoline.It is urgent to investigate the desulfurization of gasoline.The polydimethylsiloxane(PDMS)/polyetherimide(PEI)composite membranes were prepared by casting a PDMS solution onto porous PEI substrates and characterized by scanning electron microscope(SEM).The membranes were used for sulfur removal from gasoline by pervaporation.The effects of feed temperature,sulfur content in the feed and PDMS layer thickness on membrane performance were investigated,and an activation energy of permeation was obtained.Experimental results indicated that higher feed temperature yielded higher total flux and lower sulfur enrichment factor.The total flux varied little with the increase of sulfur content in the feed,but the sulfur enrichment factor first increased with the amount of thiophene added into the gasoline,and then the variation was little.The increase of PDMS layer thickness resulted in a smaller flux but a larger sulfur enrichment factor.The result indicates that the PDMS/PEI composite membranes are promising for desulfurization by pervaporation.展开更多
文摘碳捕获与封存技术是一种具有前景的CO2减排策略。本工作采用巨正则蒙特卡洛模拟研究了温度为298 K、压强在0~5 k Pa范围内三种混合超微孔材料SIFSIX-X-Cu(以SiF62–排列, Cu为金属中心, X=2, 3, O)中CO2/N2吸附与分离的行为。结果显示,相比于SIFSIX-2-Cu, SIFSIX-3-Cu和SIFSIX-O-Cu中CO2在0.5 k Pa就达到吸附饱和,且在1 k Pa下的吸附量分别达到了2.70与2.39 mmol·g–1。CO2/N2混合气体中CO2的吸附量几乎没有下降。SIFSIX-3-Cu和SIFSIX-O-Cu具有接近于CO2分子动力学直径的孔径,对CO2亲和力较大,吸附热分别达到了59和66 k J·mol–1。密度泛函理论分析发现,在两种结构中每个孔隙只吸附一个CO2分子,且几乎处于孔道的中心。本工作为低压下吸附与分离CO2的混合超微孔材料的开发提供了理论指导。
基金Project(50802052)supported by the National Natural Science Foundation of China
文摘The core-shell structure silicon-resin precursor powders were synthesized through coat-mix process and addition of Al2O3-SiO2-Y2O3 composite additives.A series of porous silicon carbide ceramics were produced after molding,carbonization and sintering.The phase,morphology,porosity,thermal conductivity,thermal expansion coefficient,and thermal shock resistance were analyzed.The results show that porous silicon carbide ceramics can be produced at low temperature.The grain size of porous silicon carbide ceramic is small,and the thermal conductivity is enhanced significantly.Composite additives also improve the thermal shock resistance of porous ceramics.The bending strength loss rate after 30 times of thermal shock test of the porous ceramics which were added Al2O3-SiO2-Y2O3 and sintered at 1 650 ℃ is only 6.5%.Moreover,the pore inside of the sample is smooth,and the pore size distribution is uniform.Composite additives make little effect on the thermal expansion coefficient of the porous silicon carbide ceramics.
基金Supported by the National Natural Science Foundation of China(21276124,21125629,21076102)Research Project of Natural Science for Universities Affiliated with Jiangsu Province(10KJB530002)+1 种基金Key Projects in the National Science&Technology Pillar Program(2011BAE07B09-3)Jiangsu Province Industrial Supporting Project(BE2011831)
文摘Membrane filtration technology combined with coagulation is widely used to purify river water.In this study,microfiltration(MF)and ultrafiltration(UF)ceramic membranes were combined with coagulation to treat local river water located at Xinghua,Jiangsu province,China.The operation parameters,fouling mechanism and pilot-scale tests were investigated.The results show that the pore size of membrane has small effect on the pseudo-steady flux for dead-end filtration,and the increase of flux in MF process is more than that in UF process for cross-flow filtration with the same increase of cross-flow velocity.The membrane pore size has little influence on the water quality.The analysis on membrane fouling mechanism shows that the cake filtration has significant influence on the pseudo-steady flux and water quality for the membrane with pore size of 50,200 and 500 nm.For the membrane with pore size of 200 nm and backwashing employed in our pilot study,a constant flux of 150L·m 2·h 1was reached during stable operation,with the removal efficiency of turbidity,total organic carbon(TOC)and UV254 higher than 99%,45%and 48%,respectively.The study demonstrates that coagulation-porous ceramic membrane hybrid process is a reliable method for river water purification.
基金Transportation Science and Technology Project of Jiangsu Province(No.7621000115)Science and Technology Project of Nanjing Committee of Housing and Urban-Rural Development(No.ks1611)
文摘Four fat and elongated(F&E)contents(0%,original,30%,and 40%)were investigated to evaluate the effects of F&Eparticles on the performance of porous asphalt mixture(P A).Laboratory tests including volumetric determination,two-dimensional image analysis,Cantabro loss tests,breakdown tests,and permeability tests were conducted to evaluate the volumetric properties,the state of stone-onstone contact,durability,skeleton stability and permeability of PA,respectively.The test results indicate that the F&E content was a significant factor for total air voids,aggregate skeleton break down,and permeability.The functionality,rutting resistance,long-term durability,and skeleton stability decrease with the increase of F&E content since F&E aggregates in porous asphalt mixtures have a tendency to breakdown.Compared with traditional dense graded mixtures,PA is more sensitive to the F&E content due to an open graded aggregate structure.Therefore,the stricter requiement for F&E content should be met for porous asphalt mixtures than the one for traditional deese graded mixture.
基金The Fundamental Research Funds for the Central Research Institute (No. 2020-9054)。
文摘The viscosity-time curve of a single-component polyurethane(PU)was examined to determine the mixing and compacting temperatures of its mixture and investigate the curing and mechanical properties of single-component PU porous elastic mixture(PPEM).The curing properties of the single-component PU and PPEM were studied with Fourier transform infrared spectroscopy(FTIR)and Marshall test.The mechanical properties of PPEM were explored via the following tests:rutting test,3-point bending test,soaked Marshall stability test,freeze-thaw splitting test,and Cantabro test.The effects of a water bath on the stability of aggregate-PU/asphalt mortar-aggregate systems were evaluated through a pull-out test and a shear test.The results show that the recommended mixing temperatures of toluene diisocyanate and methylene diphenyl diisocyanate range from 75 to 80℃and from 64 to 68℃,respectively.Room temperature(25℃)can be adopted as the compacting temperature of PPEM.PPEM can be fully cured in 4 d.Nevertheless,the water sprinkle method can obviously shorten the full curing time of PPEM.PPEM exhibites good resistance to rutting,brittle cracking,and raveling.The adhesive and shear strength of aggregate-PU/asphalt mortar-aggregate systems are negatively related to water bath duration.
基金Supported by the National Natural Science Foundation of China(21476048,21006011)the Fundamental Research Funds for the Central University(104.205.2.5)
文摘We study the macromixing behavior of single and multi-orifice-impinging transverse(MOIT) jet mixers with crossflow, in particular, the overall mixing time and the back-splash mixing time of the injected flow with the crossflow, using the PLIF technique. It is found that for a given mixer configuration, there is a critical jet-tocrossflow velocity ratio rcat which the back-splash begins to occur. Further increase in the velocity ratio r leads to sharp increase in the back-splash mixing time, which can offset the intensification of the downstream mixing. The dimensionless overall mixing time decreases as r increases to reach either a plateau or a local minimum, and the corresponding r value represents the optimal velocity ratio roptfor the macromixing. The momentum ratio of the two liquid streams is a key factor determining rcand ropt. For a larger scale mixer, a higher momentum ratio is required to achieve the optimal macromixing with the minimum dimensionless overall mixing time.
基金Supported by the National Basic Research Program of China(2009CB623404)the National Natural Science Foundation of China(50708109,20736003)the National High Technology Research and Development Program of China(2007AA06Z317)
文摘Worldwide environment has resulted in a limit on the sulfur content of gasoline.It is urgent to investigate the desulfurization of gasoline.The polydimethylsiloxane(PDMS)/polyetherimide(PEI)composite membranes were prepared by casting a PDMS solution onto porous PEI substrates and characterized by scanning electron microscope(SEM).The membranes were used for sulfur removal from gasoline by pervaporation.The effects of feed temperature,sulfur content in the feed and PDMS layer thickness on membrane performance were investigated,and an activation energy of permeation was obtained.Experimental results indicated that higher feed temperature yielded higher total flux and lower sulfur enrichment factor.The total flux varied little with the increase of sulfur content in the feed,but the sulfur enrichment factor first increased with the amount of thiophene added into the gasoline,and then the variation was little.The increase of PDMS layer thickness resulted in a smaller flux but a larger sulfur enrichment factor.The result indicates that the PDMS/PEI composite membranes are promising for desulfurization by pervaporation.