Perovskite type SrCo0.4Fe0.6O3-δ(SCF) membrane and a novel perovskite-related ZrO2 doped SrCo0.4Fe0.6O3-δ(SCFZ) membrane were successfully prepared by isostatic pressing. The sintered membranes were characterized b...Perovskite type SrCo0.4Fe0.6O3-δ(SCF) membrane and a novel perovskite-related ZrO2 doped SrCo0.4Fe0.6O3-δ(SCFZ) membrane were successfully prepared by isostatic pressing. The sintered membranes were characterized by high-temperature X-ray diffraction (HTXRD) and energy dispersive spectroscopy (EDS). The oxygen permeabilities of membranes have been measured in the temperature range of 923 K to 1243 K. The oxygen permeation flux at 1123K and activation energy of SCFZ membrane with the thickness of 2mm are respectively 2.68×10^-7 mol·cm^-2·min^-1 and 97.76 kJ·mol^-1. The results of HTXRD in argon atmosphere and the oxygen permeation experiment indicate that the SCFZ membrane is stable at elevated temperature and low oxygen partial pressure.展开更多
Using the extended Blonder-Tinkham-Klapwijk formalism, we investigate the conductance spectra of normal metal/dx2-y2 + idxy mixed wave superconductor graphene junctions. It is found that the conductance spectra vary ...Using the extended Blonder-Tinkham-Klapwijk formalism, we investigate the conductance spectra of normal metal/dx2-y2 + idxy mixed wave superconductor graphene junctions. It is found that the conductance spectra vary strongly with the orientation of the gap and the amplitude ratio (Δ1/Δ0) of two components for dx2-y2 + idxy mixed wave. The zero bias conductance is nearly 2 and the conductance peak vanishes in doped graphene for a = 0 and Δ1/Δ0 = 1. The conductance increases with increasing the amplitude ratio of two components for α =π/4 and Δ1/Δ0 -- 1. The ZBCP becomes observable wide with 1 〈 EF/Δ0 〈 100 for α= π/4 and Δ1/Δ0 = 1. This property is different from that in normal metal/dx2-y2 wave superconductor graphene junctions.展开更多
基金Supported by the National Advanced Materials Committee of China(No.715-006-0120)and the National Natural Science Foundation of China(No.59789201).
文摘Perovskite type SrCo0.4Fe0.6O3-δ(SCF) membrane and a novel perovskite-related ZrO2 doped SrCo0.4Fe0.6O3-δ(SCFZ) membrane were successfully prepared by isostatic pressing. The sintered membranes were characterized by high-temperature X-ray diffraction (HTXRD) and energy dispersive spectroscopy (EDS). The oxygen permeabilities of membranes have been measured in the temperature range of 923 K to 1243 K. The oxygen permeation flux at 1123K and activation energy of SCFZ membrane with the thickness of 2mm are respectively 2.68×10^-7 mol·cm^-2·min^-1 and 97.76 kJ·mol^-1. The results of HTXRD in argon atmosphere and the oxygen permeation experiment indicate that the SCFZ membrane is stable at elevated temperature and low oxygen partial pressure.
基金Supported by the National Natural Science Foundation of China under Grant No. 11074088
文摘Using the extended Blonder-Tinkham-Klapwijk formalism, we investigate the conductance spectra of normal metal/dx2-y2 + idxy mixed wave superconductor graphene junctions. It is found that the conductance spectra vary strongly with the orientation of the gap and the amplitude ratio (Δ1/Δ0) of two components for dx2-y2 + idxy mixed wave. The zero bias conductance is nearly 2 and the conductance peak vanishes in doped graphene for a = 0 and Δ1/Δ0 = 1. The conductance increases with increasing the amplitude ratio of two components for α =π/4 and Δ1/Δ0 -- 1. The ZBCP becomes observable wide with 1 〈 EF/Δ0 〈 100 for α= π/4 and Δ1/Δ0 = 1. This property is different from that in normal metal/dx2-y2 wave superconductor graphene junctions.