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a,Fe掺杂La-Co-O系列混合导电型透氧膜研究 被引量:12
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作者 佟建华 杨维慎 +3 位作者 任焱杰 邵宗平 熊国兴 林励吾 《催化学报》 SCIE CAS CSCD 北大核心 2000年第5期505-509,共5页
采用改进的Pechini法合成了La(Ba)Co(Fe)O3-δ系列透氧膜材料 ,考察了Ba和Fe掺入量对材料的结构、氧脱附性能及透氧性能等的影响 ,并与材料的容限因子及平均结合能进行了关联 .结果表明 ,Ba的掺杂有利于透氧活化能的降低及透氧量的提高 ... 采用改进的Pechini法合成了La(Ba)Co(Fe)O3-δ系列透氧膜材料 ,考察了Ba和Fe掺入量对材料的结构、氧脱附性能及透氧性能等的影响 ,并与材料的容限因子及平均结合能进行了关联 .结果表明 ,Ba的掺杂有利于透氧活化能的降低及透氧量的提高 ;Fe的引入使材料在较高Ba掺杂量时也能保持稳定的钙钛矿结构 ,同时使材料的密封性能较好 ,稳定操作时间加长 。 展开更多
关键词 掺杂 钙钛矿 氧分离 混合导电型透氧膜
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无Co混合导电型陶瓷透氧膜的制备和性质研究 被引量:3
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作者 李思温 丛铀 +2 位作者 房廉清 杨维慎 林励吾 《膜科学与技术》 CAS CSCD 1997年第6期16-19,33,共5页
首次合成了Sr10-n/2BinFe20Om(n=2,4,6,8,10等)系列氧化物透氧膜,它们具有较高的透氧能力,其中,样品n=10在1100K时的透氧率为0.90ml(STD)/(cm2·min),比Sr1-... 首次合成了Sr10-n/2BinFe20Om(n=2,4,6,8,10等)系列氧化物透氧膜,它们具有较高的透氧能力,其中,样品n=10在1100K时的透氧率为0.90ml(STD)/(cm2·min),比Sr1-xBixFeO3高约两倍.Sr1-xBixFeO3(x=0.1,0.3,0.5)系列的透氧率随Bi含量增加而增大.通过两个系列氧化物的XRD和化学组成的对比,发现Bi离子含量和晶格空位浓度对透氧能力大小起决定性作用. 展开更多
关键词 透氧膜 混合导电型 透氧率 陶瓷 膜材料 膜分离
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A Novel Dense Mixed-Conducting Membrane for Oxygen Permeation 被引量:1
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作者 徐南平 李世光 +1 位作者 金万勤 时钧 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2000年第3期218-223,共6页
Perovskite type SrCo0.4Fe0.6O3-δ(SCF) membrane and a novel perovskite-related ZrO2 doped SrCo0.4Fe0.6O3-δ(SCFZ) membrane were successfully prepared by isostatic pressing. The sintered membranes were characterized b... Perovskite type SrCo0.4Fe0.6O3-δ(SCF) membrane and a novel perovskite-related ZrO2 doped SrCo0.4Fe0.6O3-δ(SCFZ) membrane were successfully prepared by isostatic pressing. The sintered membranes were characterized by high-temperature X-ray diffraction (HTXRD) and energy dispersive spectroscopy (EDS). The oxygen permeabilities of membranes have been measured in the temperature range of 923 K to 1243 K. The oxygen permeation flux at 1123K and activation energy of SCFZ membrane with the thickness of 2mm are respectively 2.68×10^-7 mol·cm^-2·min^-1 and 97.76 kJ·mol^-1. The results of HTXRD in argon atmosphere and the oxygen permeation experiment indicate that the SCFZ membrane is stable at elevated temperature and low oxygen partial pressure. 展开更多
关键词 dense membrane perovskite-related oxygen permeation stability
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Tunneling Conductance in d_(x^2-y^2)+id_(xy) Mixed Wave Superconductor Graphene Junctions
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作者 李晓薇 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第12期1139-1143,共5页
Using the extended Blonder-Tinkham-Klapwijk formalism, we investigate the conductance spectra of normal metal/dx2-y2 + idxy mixed wave superconductor graphene junctions. It is found that the conductance spectra vary ... Using the extended Blonder-Tinkham-Klapwijk formalism, we investigate the conductance spectra of normal metal/dx2-y2 + idxy mixed wave superconductor graphene junctions. It is found that the conductance spectra vary strongly with the orientation of the gap and the amplitude ratio (Δ1/Δ0) of two components for dx2-y2 + idxy mixed wave. The zero bias conductance is nearly 2 and the conductance peak vanishes in doped graphene for a = 0 and Δ1/Δ0 = 1. The conductance increases with increasing the amplitude ratio of two components for α =π/4 and Δ1/Δ0 -- 1. The ZBCP becomes observable wide with 1 〈 EF/Δ0 〈 100 for α= π/4 and Δ1/Δ0 = 1. This property is different from that in normal metal/dx2-y2 wave superconductor graphene junctions. 展开更多
关键词 dx2-y2+ idxy wave superconductor GRAPHENE tunneling conductance
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