Four fat and elongated(F&E)contents(0%,original,30%,and 40%)were investigated to evaluate the effects of F&Eparticles on the performance of porous asphalt mixture(P A).Laboratory tests including volumetric det...Four fat and elongated(F&E)contents(0%,original,30%,and 40%)were investigated to evaluate the effects of F&Eparticles on the performance of porous asphalt mixture(P A).Laboratory tests including volumetric determination,two-dimensional image analysis,Cantabro loss tests,breakdown tests,and permeability tests were conducted to evaluate the volumetric properties,the state of stone-onstone contact,durability,skeleton stability and permeability of PA,respectively.The test results indicate that the F&E content was a significant factor for total air voids,aggregate skeleton break down,and permeability.The functionality,rutting resistance,long-term durability,and skeleton stability decrease with the increase of F&E content since F&E aggregates in porous asphalt mixtures have a tendency to breakdown.Compared with traditional dense graded mixtures,PA is more sensitive to the F&E content due to an open graded aggregate structure.Therefore,the stricter requiement for F&E content should be met for porous asphalt mixtures than the one for traditional deese graded mixture.展开更多
Novel dual-responsive superhydrophobic hybrid materials, ZnO/SAMs （self-assembled monolayers） of ionic liquids （ILs） with different counter-anions （I^-, BF4^-, PF6^- and Tf2N^-）, were synthesized and characteriz...Novel dual-responsive superhydrophobic hybrid materials, ZnO/SAMs （self-assembled monolayers） of ionic liquids （ILs） with different counter-anions （I^-, BF4^-, PF6^- and Tf2N^-）, were synthesized and characterized. ZnO nanoparticles were first deposited on glass surfaces to produce roughness. Next, SAMs of fluorinated-alkyl-3-（3-triethoxysilylpropyl）-4,5-dihydro-imidazoliumiodide （abb. [C8Ftespim]I） were grafted onto these surfaces via -Si-O- covalent bonds using self-assembly technique. The I- ion could be subsequently exchanged with BF4, PF6-or Tf2N- through a simple aqueous anion-exchange reaction. The ZnO/ILs hybrid layers were characterized by atomic-force microscopy （AFM）, scanning-electron microscopy （SEM） and X-ray photoelectron spectroscopy （XPS）. Their wettability was estimated through the measurements of static and dynamic contact angles （CAs）. Compared to corresponding films of ZnO/[CsFtespim]I with CAs 140.7° ±2.0°, films of ZnO/[CsFtespim]PF6 and ZnO/[CsFtespim]Tf2N showed CAs with 154.0° ± 2.0° and 152.0° ± 2.0°, respectively that remained for a long time. This result suggests that anion-exchange can afford superhydrophobic materials. In addition, the wettability of ZnO/[CsFtespim]X hybrid layers can be reversibly switched by altering ultraviolet （UV） irradiation and dark storage, which shows a photo-induced reversible switch of wettability. The synergistic action of ZnO nanoparticles and SAMs of ILs produced light-anion dual-responsive superhydrophobic materials with ideal stability.展开更多
基金Transportation Science and Technology Project of Jiangsu Province(No.7621000115)Science and Technology Project of Nanjing Committee of Housing and Urban-Rural Development(No.ks1611)
文摘Four fat and elongated(F&E)contents(0%,original,30%,and 40%)were investigated to evaluate the effects of F&Eparticles on the performance of porous asphalt mixture(P A).Laboratory tests including volumetric determination,two-dimensional image analysis,Cantabro loss tests,breakdown tests,and permeability tests were conducted to evaluate the volumetric properties,the state of stone-onstone contact,durability,skeleton stability and permeability of PA,respectively.The test results indicate that the F&E content was a significant factor for total air voids,aggregate skeleton break down,and permeability.The functionality,rutting resistance,long-term durability,and skeleton stability decrease with the increase of F&E content since F&E aggregates in porous asphalt mixtures have a tendency to breakdown.Compared with traditional dense graded mixtures,PA is more sensitive to the F&E content due to an open graded aggregate structure.Therefore,the stricter requiement for F&E content should be met for porous asphalt mixtures than the one for traditional deese graded mixture.
基金financially supported by the National Natural Science Foundation of China(21033005,21273134)the National Basic Research Program of China(2009CB930103)+2 种基金the Natural Science Foundation of Shandong Province(Combination Research Projects,ZR2013EML003&ZR2013BL001)National Undergraduate Training Programs for Innovation and Entrepreneurship(201310448008)Research Projects of Solar Energy of Dezhou University(311416&SYJS-B13003)
文摘Novel dual-responsive superhydrophobic hybrid materials, ZnO/SAMs （self-assembled monolayers） of ionic liquids （ILs） with different counter-anions （I^-, BF4^-, PF6^- and Tf2N^-）, were synthesized and characterized. ZnO nanoparticles were first deposited on glass surfaces to produce roughness. Next, SAMs of fluorinated-alkyl-3-（3-triethoxysilylpropyl）-4,5-dihydro-imidazoliumiodide （abb. [C8Ftespim]I） were grafted onto these surfaces via -Si-O- covalent bonds using self-assembly technique. The I- ion could be subsequently exchanged with BF4, PF6-or Tf2N- through a simple aqueous anion-exchange reaction. The ZnO/ILs hybrid layers were characterized by atomic-force microscopy （AFM）, scanning-electron microscopy （SEM） and X-ray photoelectron spectroscopy （XPS）. Their wettability was estimated through the measurements of static and dynamic contact angles （CAs）. Compared to corresponding films of ZnO/[CsFtespim]I with CAs 140.7° ±2.0°, films of ZnO/[CsFtespim]PF6 and ZnO/[CsFtespim]Tf2N showed CAs with 154.0° ± 2.0° and 152.0° ± 2.0°, respectively that remained for a long time. This result suggests that anion-exchange can afford superhydrophobic materials. In addition, the wettability of ZnO/[CsFtespim]X hybrid layers can be reversibly switched by altering ultraviolet （UV） irradiation and dark storage, which shows a photo-induced reversible switch of wettability. The synergistic action of ZnO nanoparticles and SAMs of ILs produced light-anion dual-responsive superhydrophobic materials with ideal stability.
