有气流扰动下管流油水混合物粘度实验测量与计算模型

采用局部即时取样方法对水平管内油气水三相流动情况下各种混合比例的复杂混合物的流动粘度进行了实验研究,实验工质采用46号机械油、自来水和空气。以实验数据为基础提出了考虑流动参数变化影响的反相点预测关联式。考虑到管内油水两相的混合发展过程,以局部即时取样的实验数据为基础,提出了一个气流扰动下管内流动条件下油水混合物粘度的预测关系式,该模型考虑了油水两相本身的物性以及流动因素的影响。指出考虑流动参数影响的粘度预测模型能大大提高油气水三相流动情况下油水混合物实测粘度的预测精度。

浅谈集输工艺设计中原油及其混合物粘度确定方法

本文介绍了原油及其混合物粘度计算公式及根据室内实验如何确定原油及其乳状液的粘度，并提出了几点看法，以供设计人员参考。

Densities and Viscosities of the Ionic Liquid [C4mim][PF6]＋ N,N-dimethylformamide Binary Mixtures at 293.15 K to 318.15 K

Viscosities and densities for 1-butyl-3-methylimidazolium hexafluorophosphate （[C4mim][PF6]） and N, N-dimethylformamide （DMF） binary mixtures have been measured at the temperature range from 293.15 K to 318.15 K. It is shown that the viscosities and densities decrease monotonously with temperature and the content of DMF. Various correlation methods including Arrhenius-like equation, Sedclon et al.＇s equation, Redlich-Kister equation with four parameters, and other empirical equations were applied to evaluate these experimental data. A model based on an equation of state Ior estimating the viscosity of mixtures containing ionic liquids were proposed by coupling with the excess Gibbs free energy model of viscosity, which can synchronously calculate the viscosity and the molar volume. The results show that the model gives a deviation of 8.29% for the viscosity, and a deviation of 1.05% for the molar volume when only one temperature-independent adjustable parameter is adopted. The correlation accuracy is further improved when two parameters or one temperature-dependent parameter is used.

Production of a Mathematic Equation Using Statistical Data for the Determination of Kinematic Viscosity in Blends of Diesel Fuel with Biodiesel

In this paper, the authors try to export an equation which describes the variation of kinematic viscosity in blends of diesel fuel with biodiesel. Using specific volume of these blends, the authors determine kinematic viscosity via method ASTM D 445-06 using a capillary glass viscometer in order to study the contribution of quantity of biodiesel and convert the statistical data into mathematic relation as a specific formula, attempting to achieve an empirical evaluation. Trying to accomplish this, the authors studied the way how the values of variables are changed and whether a relation exists using dispersion diagrams. From the graphic depiction, the authors realized that the relation is linear and they proceeded to regression analysis. The analysis extracted the conclusion that the relation was strong and the values of the dependent variable kinematic viscosity was depended on a large percentage of the values of the mixture of fuels.

The Influence of Paraffinic Base Oil on Low-temperature Viscosity of Naphthenic Base Oil

Low-temperature viscosity of lube oils mixed with paraffinic base oil and naphthenic base oil at different mass ratios has been tested by experiments. The influence of paraffinic base oil on the performance of naphthenic base oil was investigated by studying the low-temperature viscosity of tested oils. The viscosity of lube oils increased with an increasing content of high-viscosity paraffinic base oil in the oil mixture. And the low-temperature viscosity was less influenced when the content of paraffinic base oil in the mixture was insignificant. In order to reduce the cost for formulating lubricating oil, a small fraction of paraffinic base oil can be added into naphthenic base oil as far as the property of lubricating oil can meet the specification. According to the study on low-temperature viscosity of the oil mixed with paraffinic base oil and naphthenic base oil, a basic rule was worked out for the preparation of qualified lubricating oils.

Synthesis of Polyalphaolefins on AlCl_3/TiCl_4 Catalyst

The oligomerzation reactions on different catalysts were investigated and discussed. 1-Octene, 1-decene, 1-do- decene, a mixture of olefins （with a mass ratio of w（l-octene）： w（1-decenc）：w（1-dodecene） equating to 30：40：30）, and the products from paraffin cracking were oligomerized on the AlCl3/TiC14 catalyst. The results indicated that the AlCl3 catalyst led to severe coking reaction. With an increase in carbon number of alpha-olefins, the freezing point of oligomers increased and the kinematic viscosity decreased. The oligomers formed from the mixed olefins and the paraffin cracking products showed higher kinematic viscosity. Normal paraffins contained in the cracked products could increase the freezing point of oligomers. Furthermore, the distillation range of oligomers obtained from the cracked products was close to those of oligo- mers originated from 1-octene and 1-decene, while the oligomers obtained from the mixed olefins and 1-dodecene had simi- lar distillation ranges.

Densities and viscosities of binary mixtures of n-decane + 1-pentanol,+1-hexanol,+1-heptanol at temperatures from 293.15 to 363.15 K and atmospheric pressure

Densities(ρ) and dynamic viscosities(η) for three binary mixtures of n-decane with 1-pentanol,1-hexanol and1-heptanol are presented at temperatures from 293.15 to 363.15 K and atmospheric pressure over the entire composition range.The density and viscosity are measured using a vibrating tube densimeter and a cylindrical Couette type rotating viscometer,respectively.Excess molar volumes(V^E),viscosity deviations(△η) and excess Gibbs energy of activation of viscous flow(△G^(*E)) are calculated from the experimental measurements.Intermolecular and structural interactions are indicated by the sign and magnitude of these properties.Partial molar volumes and infinity dilution molar partial volumes are also calculated for each binary system.These results are correlated using Redlich-Kister type equations.

Excess Molar Volume, Viscosity and Heat Capacity for the Binary Mixture of p-Xylene and Acetic Acid at Different Temperatures

Experimental densities, viscosities and heat capacities atdifferent temperatures were presented over the entire range of molefraction for the binary mixture of p-xylene and acetic acid. Densityvalues were used in the determination of excess molar volumes, V^E.At the same time, the excess viscosity and excess molar heatcapacities were calculated. The values of V^E, η~E and c^E_p werefitted to the Redlich-Kister equation. Good agreements were observed.The excess molar volumes are positive with a large maximum valuelocated in the central concentration range.

Calculation of Viscosity and Diffusion Coefficients for Two Binary Gaseous Mixtures Using the Semi-empirical Inversion Method

The accurate reduced potential energies for two binary gas mixtures including benzene- methanol and methane-tetrafluoromethane at low density have been obtained by direct inversion of the viscosity collision integral equations. The kinetic theory along with the extended principle of corresponding-states has been used to calculate the viscosity and dif- fusion coefficients over a wide range of temperature and composition. Good agreements between calculated and experimental data are obtained.

Particle removal by a single cavitation bubble

In the paper,the behavior of the particle acted by the oscillating bubble is studied using a high-speed video camera.The bubble is generated using a very low voltage of 55 V.Images are captured at a speed of 15000 fps(frames per second).It is found that the velocity of the particle is dependent on the liquid viscosity,particle size,and tube diameter.Particle velocity decreases with the increase of the glycron-water mixture viscosity.A model is presented to predict the velocity and verified by experimental results.These observations may be beneficial for the application in medical treatment.