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关于化学平衡存在的教学讨论
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作者 柴兴泉 《邯郸学院学报》 1992年第Z1期48-52,共5页
实践告诉人们,绝大多数的化学反应都不能进行到底,都不能把反应物完全地转化成产物,化学平衡必然存在.这也是化学热力学告知人们的重要结论.现行物理化学教材以及一些参考书在给出此结论时,大都采用叙述的方法,缺乏说服力,难以使人置信... 实践告诉人们,绝大多数的化学反应都不能进行到底,都不能把反应物完全地转化成产物,化学平衡必然存在.这也是化学热力学告知人们的重要结论.现行物理化学教材以及一些参考书在给出此结论时,大都采用叙述的方法,缺乏说服力,难以使人置信.在教学中给予必要的数学论证,是十分有益的. 展开更多
关键词 化学平衡 教学讨论 反应物 实际反应 正向反应 逆向反应 混和态 反应进度 反应体系 参加反应
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Analytic Expression of Geometric Discord in Arbitrary Mixture of any Two Bi-qubit Product Pure States
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作者 谢传梅 刘益民 +1 位作者 邢航 张战军 《Communications in Theoretical Physics》 SCIE CAS CSCD 2015年第4期439-444,共6页
Quantum correlations in a family of states comprising any mixture of a pair of arbitrary bi-qubit product pure states are studied by employing geometric discord [Phys. Rev. Lett. 105(2010) 190502] as the quantifier. F... Quantum correlations in a family of states comprising any mixture of a pair of arbitrary bi-qubit product pure states are studied by employing geometric discord [Phys. Rev. Lett. 105(2010) 190502] as the quantifier. First, the inherent symmetry in the family of states about local unitary transformations is revealed. Then, the analytic expression of geometric discords in the states is worked out. Some concrete discussions and analyses on the captured geometric discords are made so that their distinct features are exposed. It is found that, the more averagely the two bi-qubit product states are mixed, the bigger geometric discord the mixed state owns. Moreover, the monotonic relationships of geometric discord with different parameters are revealed. 展开更多
关键词 mixture of a pair of arbitrary bi-qubit product pure state geometric discord inherent symmetry of local unitary transformation m
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Electrochemical solid-state amorphization in the immiscible Cu-Li system 被引量:3
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作者 Muhua Sun Jiake Wei +4 位作者 Zhi Xu Qianming Huang Yu Zhao Wenlong Wang Xuedong Bai 《Science Bulletin》 SCIE EI CSCD 2018年第18期1208-1214,共7页
As a typical immiscible binary system, copper (Cu) and lithium (Li) show no alloying and chemical intermixing under normal circumstances. Here we show that, when decreasing Cu nanoparticle sizes into ultrasmall range,... As a typical immiscible binary system, copper (Cu) and lithium (Li) show no alloying and chemical intermixing under normal circumstances. Here we show that, when decreasing Cu nanoparticle sizes into ultrasmall range, the nanoscale size effect can play a subtle yet critical role in mediating the chemical activity of Cu and therefore its miscibility with Li, such that the electrochemical alloying and solidstate amorphization will occur in such an immiscible system. This unusual observation was accomplished by performing in-situ studies of the electrochemical lithiation processes of individual CuO nanowires inside a transmission electron microscopy (TEM). Upon lithiation, CuO nanowires are first electrochemically reduced to form discrete ultrasmall Cu nanocrystals that, unexpectedly, can in turn undergo further electrochemical lithiation to form amorphous Cu Lixnanoalloys. Real-time TEM imaging unveils that there is a critical grain size (ca. 6 nm), below which the nanocrystalline Cu particles can be continuously lithiated and amorphized. The possibility that the observed solid-state amorphization of Cu-Li might be induced by electron beam irradiation effect can be explicitly ruled out; on the contrary, it was found that electron beam irradiation will lead to the dealloying of as-formed amorphous Cu Lixnanoalloys. 展开更多
关键词 Immiscible Cu-Li system Electrochemical solid-state amorphization Nanoscale size effect In-situ TEM Lithium ion battery
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Decomposition Properties of Quantum Discord
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作者 Sunho Kim 武俊德 Minhyung Cho 《Communications in Theoretical Physics》 SCIE CAS CSCD 2016年第4期441-446,共6页
The quantum discord was introduced by Ollivier,Zurek,Henderson,and Vedral as an indicator of the degree of quantumness of mixed states.In this paper,we provide a decomposition condition for quantum discord.Moreover,we... The quantum discord was introduced by Ollivier,Zurek,Henderson,and Vedral as an indicator of the degree of quantumness of mixed states.In this paper,we provide a decomposition condition for quantum discord.Moreover,we show that under the condition,the quantum correlations between the quantum systems can be captured completely by the entanglement measure.Finally,we present examples of our conclusions. 展开更多
关键词 quantum state quantum measurement quantum discord
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