The uncertainty of standard solution plays an important role in detection of pesticide residues. It may affect the accuracy of detection results. In this study, the 14 organophosphorus pesticides mixed standard soluti...The uncertainty of standard solution plays an important role in detection of pesticide residues. It may affect the accuracy of detection results. In this study, the 14 organophosphorus pesticides mixed standard solution was used as the material to analyze all the influencing factors for the preparation of mixed standard solution with uncertainty as the only judging index. The preparation uncertainty of mixed standard solution was calculated with the top-down calculation method. In the end, the expanded uncertainty was presented. The results showed that the preparation of mixed standard solution from stock solution with precise pipettes had a relatively low uncertainty.展开更多
Model is usually necessary for the design of a control loop. Due to simplification and unknown dynamics, model plant mismatch is inevitable in the control loop. In process monitoring, detection of mismatch and evaluat...Model is usually necessary for the design of a control loop. Due to simplification and unknown dynamics, model plant mismatch is inevitable in the control loop. In process monitoring, detection of mismatch and evaluation of its influences are demanded. In this paper several mismatch measures are presented based on different model descriptions. They are categorized into different groups from different perspectives and their potential in detection and diagnosis is evaluated. Two case studies on mixing process and distillation process demonstrate the efficacy of the framework of mismatch monitoring.展开更多
In this paper, the effect of the source of recycled coarse aggregate on the properties of concrete is investigated. The tests were conducted on concrete made from three sources of recycled aggregates: (1) old concr...In this paper, the effect of the source of recycled coarse aggregate on the properties of concrete is investigated. The tests were conducted on concrete made from three sources of recycled aggregates: (1) old concrete with unknown strength, (2) old concrete with a known compressive strength of 21 MPa, and (3) old concrete with a known strength of 42 MPa. The three sources of recycled aggregates were used to produce new concrete with a target compressive strength of 21 MPa. The first and third sources of recycled aggregates were used in producing concrete with target strength of 42 MPa. A control mix was designed with aggregates from natural sources. The research included two methods of making recycled concrete. One concrete mix was produced using the recycled aggregate and adding more water than the control mix, to reach the target slump, while the second concrete mix was produced using the same amount of water as the control mix but with additional superplasticizer to maintain the target slump. The results obtained in this research showed that the concrete compressive strength depends on the source of recycled aggregates; the stronger the source of recycled aggregate, the higher the compressive strength of the produced concrete. Furthermore, the compressive strength of the first concrete mix was about 10%-20% lower than the compressive strength of the control mix. However, when superplasticizers were used, the compressive strength was around the same value as the control mix.展开更多
A discrete centrosymmetric (H2O)20(CH3OH)4 binary cluster was confined in the cavity of a metaMigand hybrid [Ag4(bpda)2(bpp)4" 14H2O.2CH3OH], (1) (where bpp = 1,3-bis(4-pyridyl)propane and H2bpda = 2,2'...A discrete centrosymmetric (H2O)20(CH3OH)4 binary cluster was confined in the cavity of a metaMigand hybrid [Ag4(bpda)2(bpp)4" 14H2O.2CH3OH], (1) (where bpp = 1,3-bis(4-pyridyl)propane and H2bpda = 2,2'-biphenyldicarboxylic acid) The novel mixed water-methanol cluster consists of one grail-shaped hexadecameric cluster, four dangling water and four hanging methanol molecules. The (H2O)16 cluster is composed of two pairs of edge-sharing (H2O)5 rings attached to one (H2O)4 core with twenty hydrogen bonds. Alternatively, the (H2O)16 cluster is structurally similar to a complicated hydrocarbon generated by undergoing [2+2] cycloaddition of 1,2,3,4,5,6-hexahydropentalene, which reveals the resemblance between water clusters and organic compounds.展开更多
A strategy is proposed to control Lu It is implemented by using sliding mode control system with mismatch uncertainties. The proposed controller ensures the occurrence of the sliding mode motion. It is guaranteed that...A strategy is proposed to control Lu It is implemented by using sliding mode control system with mismatch uncertainties. The proposed controller ensures the occurrence of the sliding mode motion. It is guaranteed that under the proposed control law, the system state can be regulated to a specific point or in a predictable neighborhood of desired points in the state space even with mismatch uncertainties. Simulation results have illustrated the effectiveness and robustness of the proposed schemes even though the control input is nonlinear.展开更多
文摘The uncertainty of standard solution plays an important role in detection of pesticide residues. It may affect the accuracy of detection results. In this study, the 14 organophosphorus pesticides mixed standard solution was used as the material to analyze all the influencing factors for the preparation of mixed standard solution with uncertainty as the only judging index. The preparation uncertainty of mixed standard solution was calculated with the top-down calculation method. In the end, the expanded uncertainty was presented. The results showed that the preparation of mixed standard solution from stock solution with precise pipettes had a relatively low uncertainty.
基金Supported in part by the National Basic Research Program of China (2012CB720500)the Erasmus Mundus Europe Asia(EMEA) Scholarship Program
文摘Model is usually necessary for the design of a control loop. Due to simplification and unknown dynamics, model plant mismatch is inevitable in the control loop. In process monitoring, detection of mismatch and evaluation of its influences are demanded. In this paper several mismatch measures are presented based on different model descriptions. They are categorized into different groups from different perspectives and their potential in detection and diagnosis is evaluated. Two case studies on mixing process and distillation process demonstrate the efficacy of the framework of mismatch monitoring.
文摘In this paper, the effect of the source of recycled coarse aggregate on the properties of concrete is investigated. The tests were conducted on concrete made from three sources of recycled aggregates: (1) old concrete with unknown strength, (2) old concrete with a known compressive strength of 21 MPa, and (3) old concrete with a known strength of 42 MPa. The three sources of recycled aggregates were used to produce new concrete with a target compressive strength of 21 MPa. The first and third sources of recycled aggregates were used in producing concrete with target strength of 42 MPa. A control mix was designed with aggregates from natural sources. The research included two methods of making recycled concrete. One concrete mix was produced using the recycled aggregate and adding more water than the control mix, to reach the target slump, while the second concrete mix was produced using the same amount of water as the control mix but with additional superplasticizer to maintain the target slump. The results obtained in this research showed that the concrete compressive strength depends on the source of recycled aggregates; the stronger the source of recycled aggregate, the higher the compressive strength of the produced concrete. Furthermore, the compressive strength of the first concrete mix was about 10%-20% lower than the compressive strength of the control mix. However, when superplasticizers were used, the compressive strength was around the same value as the control mix.
基金supported by the National Natural Science Foundation of China(50971063,21053001)the Natural Science Foundation of Fujian Province(2011J01047,2010J01042)+1 种基金the Scientific Research Foundation for the Returned Overseas Chinese Scholars,Education of Ministrythe Startup Package Funding of Huaqiao University (10BS210)
文摘A discrete centrosymmetric (H2O)20(CH3OH)4 binary cluster was confined in the cavity of a metaMigand hybrid [Ag4(bpda)2(bpp)4" 14H2O.2CH3OH], (1) (where bpp = 1,3-bis(4-pyridyl)propane and H2bpda = 2,2'-biphenyldicarboxylic acid) The novel mixed water-methanol cluster consists of one grail-shaped hexadecameric cluster, four dangling water and four hanging methanol molecules. The (H2O)16 cluster is composed of two pairs of edge-sharing (H2O)5 rings attached to one (H2O)4 core with twenty hydrogen bonds. Alternatively, the (H2O)16 cluster is structurally similar to a complicated hydrocarbon generated by undergoing [2+2] cycloaddition of 1,2,3,4,5,6-hexahydropentalene, which reveals the resemblance between water clusters and organic compounds.
文摘A strategy is proposed to control Lu It is implemented by using sliding mode control system with mismatch uncertainties. The proposed controller ensures the occurrence of the sliding mode motion. It is guaranteed that under the proposed control law, the system state can be regulated to a specific point or in a predictable neighborhood of desired points in the state space even with mismatch uncertainties. Simulation results have illustrated the effectiveness and robustness of the proposed schemes even though the control input is nonlinear.