The results of experimental works aimed on finding the optimal composition of concretes containing alternative materials as mineral additives for assurance their high resistance to chemical aggressive attack are prese...The results of experimental works aimed on finding the optimal composition of concretes containing alternative materials as mineral additives for assurance their high resistance to chemical aggressive attack are presented in the paper. 4 kinds of additives （blast furnace slag, fly ash, non-treated and treated serpentinite waste） and 4 kinds of aggressive environments （distilled water, HCI, MgSO4 and NaOH） representing the concrete corrosive processes was checked within experimental process. The open laboratory curing was used as a reference environment. Moreover, the amounts of additives were varied, so 16 various recipes were checked on the whole. The resistance of samples was tested in the terms of flexural strength, compressive strength and evaluation of decrease/increase of strengths after long time （28 months） exposition in monitored aggressive media. Based on obtained results, it is possible for each of aggressive environments recommend the most promising recipe from various points of view, in accordance with user＇s priorities. From the percentage increase of 28-day compressive strengths point of view, there are： for HCI action - recipe with 20% of non treated serpentinite waste with plasticizer application, for MgSO4 action - recipe with 20% of blast furnace slag without plasticizer application and for NaOH action - recipe with 10% of non treated serpentinite waste without plasticizer application. Application of alternative materials as partial substitution of cement appears to be beneficial for achievement the resistance to aggressive chemical actions. With the keeping or enhancement of technical parameters it extra represents both the environmental and economic benefit.展开更多
Monophasic mullite gel with composition 3Al2O3·2SiO2 was prepared by the sol-gel method using aluminium nitrate nonahydrate, aluminium-tri-isopropoxide, and tetraethylorthosili-cate as reagents. Gels with differe...Monophasic mullite gel with composition 3Al2O3·2SiO2 was prepared by the sol-gel method using aluminium nitrate nonahydrate, aluminium-tri-isopropoxide, and tetraethylorthosili-cate as reagents. Gels with different drying control chemical additives(DCCAs) and polyvinylpyrrolidone(PVP) as spinning assistant were dried at several temperatures. The influences of temperature, DCCAs and PVP in the drying process were investigated. N,N-dimethylformamide(DMF) was the optimum DCCA at 70℃ in the drying process. PVP decreased the solvent volatilization speed and prevented gel crack to a certain extent. FTIR results revealed that free water, ethanol, and isopropanol were completely removed by the drying procedure.展开更多
This paper is concerned with the estimating problem of seemingly unrelated(SU)nonparametric additive regression models.A polynomial spline based two-stage efficient approach is proposed to estimate the nonparametric c...This paper is concerned with the estimating problem of seemingly unrelated(SU)nonparametric additive regression models.A polynomial spline based two-stage efficient approach is proposed to estimate the nonparametric components,which takes both of the additive structure and correlation between equations into account.The asymptotic normality of the derived estimators are established.The authors also show they own some advantages,including they are asymptotically more efficient than those based on only the individual regression equation and have an oracle property,which is the asymptotic distribution of each additive component is the same as it would be if the other components were known with certainty.Some simulation studies are conducted to illustrate the finite sample performance of the proposed procedure.Applying the proposed procedure to a real data set is also made.展开更多
文摘The results of experimental works aimed on finding the optimal composition of concretes containing alternative materials as mineral additives for assurance their high resistance to chemical aggressive attack are presented in the paper. 4 kinds of additives （blast furnace slag, fly ash, non-treated and treated serpentinite waste） and 4 kinds of aggressive environments （distilled water, HCI, MgSO4 and NaOH） representing the concrete corrosive processes was checked within experimental process. The open laboratory curing was used as a reference environment. Moreover, the amounts of additives were varied, so 16 various recipes were checked on the whole. The resistance of samples was tested in the terms of flexural strength, compressive strength and evaluation of decrease/increase of strengths after long time （28 months） exposition in monitored aggressive media. Based on obtained results, it is possible for each of aggressive environments recommend the most promising recipe from various points of view, in accordance with user＇s priorities. From the percentage increase of 28-day compressive strengths point of view, there are： for HCI action - recipe with 20% of non treated serpentinite waste with plasticizer application, for MgSO4 action - recipe with 20% of blast furnace slag without plasticizer application and for NaOH action - recipe with 10% of non treated serpentinite waste without plasticizer application. Application of alternative materials as partial substitution of cement appears to be beneficial for achievement the resistance to aggressive chemical actions. With the keeping or enhancement of technical parameters it extra represents both the environmental and economic benefit.
文摘Monophasic mullite gel with composition 3Al2O3·2SiO2 was prepared by the sol-gel method using aluminium nitrate nonahydrate, aluminium-tri-isopropoxide, and tetraethylorthosili-cate as reagents. Gels with different drying control chemical additives(DCCAs) and polyvinylpyrrolidone(PVP) as spinning assistant were dried at several temperatures. The influences of temperature, DCCAs and PVP in the drying process were investigated. N,N-dimethylformamide(DMF) was the optimum DCCA at 70℃ in the drying process. PVP decreased the solvent volatilization speed and prevented gel crack to a certain extent. FTIR results revealed that free water, ethanol, and isopropanol were completely removed by the drying procedure.
基金supported by National Natural Science Funds for Distinguished Young Scholar under Grant No.70825004National Natural Science Foundation of China under Grant Nos.10731010 and 10628104+3 种基金the National Basic Research Program under Grant No.2007CB814902Creative Research Groups of China under Grant No.10721101supported by leading Academic Discipline Program,211 Project for Shanghai University of Finance and Economics(the 3rd phase)and project number:B803supported by grants from the National Natural Science Foundation of China under Grant No.11071154
文摘This paper is concerned with the estimating problem of seemingly unrelated(SU)nonparametric additive regression models.A polynomial spline based two-stage efficient approach is proposed to estimate the nonparametric components,which takes both of the additive structure and correlation between equations into account.The asymptotic normality of the derived estimators are established.The authors also show they own some advantages,including they are asymptotically more efficient than those based on only the individual regression equation and have an oracle property,which is the asymptotic distribution of each additive component is the same as it would be if the other components were known with certainty.Some simulation studies are conducted to illustrate the finite sample performance of the proposed procedure.Applying the proposed procedure to a real data set is also made.
