Chemical conditioning was used to modify the triboelectrification of coal and mineral particles.The chemicals tested included starch,lignin,kerosene,ethanol,acetic acid,salicylic acid,sodium oleate,Sodium Hexametaphos...Chemical conditioning was used to modify the triboelectrification of coal and mineral particles.The chemicals tested included starch,lignin,kerosene,ethanol,acetic acid,salicylic acid,sodium oleate,Sodium Hexametaphosphate(SH),sodium silicate, Sodium Dodecylbenzenesulfonate(SDBS),Sodium Bicarbonate(SB) and ammonia.A high-speed,dry mixing method was employed.The charge-to-mass ratio of the coal and mineral samples,both untreated and treated,was tested using a Faraday cup. Dielectric constants were determined by measuring capacitance.It is found that the selectivity of the additives toward coal or minerals is not consistent.Salicylic acid is the optimal additive to enhance the triboelectrification performance of coal samples.Starch, lignin and sodium oleate are suitable for removal of pyrite.SH,sodium silicate,SDBS,SB and ammonia are suitable additives for the removal of ash-forming minerals.展开更多
Properties of hydroxyapatite (HA, Ca10(PO4)6(OH)2), including bioactivity, biocompatibility, solubility and adsorption could be tailored over wide ranges by the control of particle composition, particle size and...Properties of hydroxyapatite (HA, Ca10(PO4)6(OH)2), including bioactivity, biocompatibility, solubility and adsorption could be tailored over wide ranges by the control of particle composition, particle size and morphology. In order to satisfy various applications, well-crystallized pure HA nanoparticles were synthesized at moderate temperatures by hydrotherrnal synthesis, and HA nanoparticles with different lengths were obtained by adding organic additives. X-ray diffractometry (XRD) and Fourier transform infrared (FTIR) spectrometry were used to characterize these nanoparticles, and the morphologies of the HA particles were observed by transmission electron microscopy (TEM). The results demonstrate that shorter rod-like HA particles can be prepared by adding cetyltrimethylammonium bromide (CTAB), as the additive of CTAB can block the HA crystal growth along with c-axis. And whisker HA particles are obtained by adding ethylenediamine tetraacetic acid (EDTA), since EDTA may have effect on the dissolution-repreeipitation process of HA.展开更多
By using PAO-10 as the base oil, the tribological behavior of 11 additives under high vacuum condition was evaluated. By adopting some surface analytical instruments, such as scanning electron microscopy(SEM), energy ...By using PAO-10 as the base oil, the tribological behavior of 11 additives under high vacuum condition was evaluated. By adopting some surface analytical instruments, such as scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and X-ray photoelectron spectroscopy(XPS), the tribological mechanisms of these additives were studied. In air, O_2 can react with metal to form metal oxide that can protect the surfaces of rubbing pair during the tribological tests. According to the theory of the competitive adsorption, the function of some active elements is weakened. In a vacuum environment, the additives contributed more to the lubrication performance. The sulfur-containing additives could react with Fe to produce Fe Sx and "M—C" bonds("M" represents metal). They both had contributions to the lubrication. As for the phosphorus-containing additives, they only generated the phosphates during the tests. When the sulfur and phosphorus-containing additives were applied, the generated phosphates and Fe Sx had the primary contribution to the lubrication performance during the tests.展开更多
The experiment was conducted with 180 one-day-old AA broilers that were randomly divided into one control group and one trial group to study the effects of AsN1980 phytase on broilers growth performance and P utilizat...The experiment was conducted with 180 one-day-old AA broilers that were randomly divided into one control group and one trial group to study the effects of AsN1980 phytase on broilers growth performance and P utilization in low available phosphorus diets. Results showed that phytase supplement decreased F/W by 12.4%-13.4%and increased phosphorus availability by 7.63%-8.27%, both of which were significantly superior to the control group (P< 0.05).展开更多
Understanding how nitrogen(N) availability interacts with soil acidity and phosphorus(P) availability to affect soil-atmosphere exchanges in CO_2, CH_4 and N_2O in forest ecosystems is important for understanding ...Understanding how nitrogen(N) availability interacts with soil acidity and phosphorus(P) availability to affect soil-atmosphere exchanges in CO_2, CH_4 and N_2O in forest ecosystems is important for understanding the mechanisms driving ecosystem responses to enhanced N deposition. Here, we conducted an experiment with N, P and acid(H) addition in a mixed forest in subtropical China to investigate how acid and P addition affects CO_2, CH_4 and N_2O exchange under N addition. Our results showed that soil NH4^+-N and NO3^--N increased after N addition, but CO_2 emissions in N addition plots remained unaffected. CH_4 uptake in N–, P–, NP–, NH– and NPH–addition plots were reduced by 21.1%, 15.7%, 39.1%, 26.6%, and 28.4%, respectively. CH_4 uptake in NP–addition plots were lower compared to N–addition and P–addition plots, indicating that N and P addition had an additive effect on inhibiting CH_4 uptake. N_2O emission in N–, NP–, NH– and NPH–addition plots increased by 158.6%, 176.0%, 117.2%, and 91.8%, respectively. N_2O emissions in NPH–addition plots were lower compared to NP–addition plots while showed no difference between N–addition and NH–addition plots. This suggests that only under P rich conditions, acid addition would greatly mitigate N_2O emissions under N addition. Our results demonstrate that for N and P co-limited forest ecosystems with acidic soils, low P availability constrains the inhibition of soil CH_4 uptake by N deposition. When P availability is low, a weak soil acidation induced by N deposition may have less influence on the stimulation of N_2O emissions by N deposition.展开更多
基金supported by the National Natural Science Foundation of China(No. 50921002)the Key Laboratory of Coal Processing and Efficient Utilization,the Ministry of Education of China(No.CPEUKF08-05).
文摘Chemical conditioning was used to modify the triboelectrification of coal and mineral particles.The chemicals tested included starch,lignin,kerosene,ethanol,acetic acid,salicylic acid,sodium oleate,Sodium Hexametaphosphate(SH),sodium silicate, Sodium Dodecylbenzenesulfonate(SDBS),Sodium Bicarbonate(SB) and ammonia.A high-speed,dry mixing method was employed.The charge-to-mass ratio of the coal and mineral samples,both untreated and treated,was tested using a Faraday cup. Dielectric constants were determined by measuring capacitance.It is found that the selectivity of the additives toward coal or minerals is not consistent.Salicylic acid is the optimal additive to enhance the triboelectrification performance of coal samples.Starch, lignin and sodium oleate are suitable for removal of pyrite.SH,sodium silicate,SDBS,SB and ammonia are suitable additives for the removal of ash-forming minerals.
基金Project(20070410304) supported by Postdoctoral Foundation of ChinaProject(07JJ3105) supported by Hunan Provincial Natural Science Foundation of China
文摘Properties of hydroxyapatite (HA, Ca10(PO4)6(OH)2), including bioactivity, biocompatibility, solubility and adsorption could be tailored over wide ranges by the control of particle composition, particle size and morphology. In order to satisfy various applications, well-crystallized pure HA nanoparticles were synthesized at moderate temperatures by hydrotherrnal synthesis, and HA nanoparticles with different lengths were obtained by adding organic additives. X-ray diffractometry (XRD) and Fourier transform infrared (FTIR) spectrometry were used to characterize these nanoparticles, and the morphologies of the HA particles were observed by transmission electron microscopy (TEM). The results demonstrate that shorter rod-like HA particles can be prepared by adding cetyltrimethylammonium bromide (CTAB), as the additive of CTAB can block the HA crystal growth along with c-axis. And whisker HA particles are obtained by adding ethylenediamine tetraacetic acid (EDTA), since EDTA may have effect on the dissolution-repreeipitation process of HA.
基金Financial support from the SINOPEC Research Program(No.ST13164-19]) is gratefully acknowledged
文摘By using PAO-10 as the base oil, the tribological behavior of 11 additives under high vacuum condition was evaluated. By adopting some surface analytical instruments, such as scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and X-ray photoelectron spectroscopy(XPS), the tribological mechanisms of these additives were studied. In air, O_2 can react with metal to form metal oxide that can protect the surfaces of rubbing pair during the tribological tests. According to the theory of the competitive adsorption, the function of some active elements is weakened. In a vacuum environment, the additives contributed more to the lubrication performance. The sulfur-containing additives could react with Fe to produce Fe Sx and "M—C" bonds("M" represents metal). They both had contributions to the lubrication. As for the phosphorus-containing additives, they only generated the phosphates during the tests. When the sulfur and phosphorus-containing additives were applied, the generated phosphates and Fe Sx had the primary contribution to the lubrication performance during the tests.
文摘The experiment was conducted with 180 one-day-old AA broilers that were randomly divided into one control group and one trial group to study the effects of AsN1980 phytase on broilers growth performance and P utilization in low available phosphorus diets. Results showed that phytase supplement decreased F/W by 12.4%-13.4%and increased phosphorus availability by 7.63%-8.27%, both of which were significantly superior to the control group (P< 0.05).
基金Natural Sciences Foundation of China(No.31290221)
文摘Understanding how nitrogen(N) availability interacts with soil acidity and phosphorus(P) availability to affect soil-atmosphere exchanges in CO_2, CH_4 and N_2O in forest ecosystems is important for understanding the mechanisms driving ecosystem responses to enhanced N deposition. Here, we conducted an experiment with N, P and acid(H) addition in a mixed forest in subtropical China to investigate how acid and P addition affects CO_2, CH_4 and N_2O exchange under N addition. Our results showed that soil NH4^+-N and NO3^--N increased after N addition, but CO_2 emissions in N addition plots remained unaffected. CH_4 uptake in N–, P–, NP–, NH– and NPH–addition plots were reduced by 21.1%, 15.7%, 39.1%, 26.6%, and 28.4%, respectively. CH_4 uptake in NP–addition plots were lower compared to N–addition and P–addition plots, indicating that N and P addition had an additive effect on inhibiting CH_4 uptake. N_2O emission in N–, NP–, NH– and NPH–addition plots increased by 158.6%, 176.0%, 117.2%, and 91.8%, respectively. N_2O emissions in NPH–addition plots were lower compared to NP–addition plots while showed no difference between N–addition and NH–addition plots. This suggests that only under P rich conditions, acid addition would greatly mitigate N_2O emissions under N addition. Our results demonstrate that for N and P co-limited forest ecosystems with acidic soils, low P availability constrains the inhibition of soil CH_4 uptake by N deposition. When P availability is low, a weak soil acidation induced by N deposition may have less influence on the stimulation of N_2O emissions by N deposition.