土体几何因素(粒径比、细粒含量、相对密实度等)不仅影响土体内部稳定性,同时对侵蚀进程有着重要影响。基于离散单元法(discrete element method,简称DEM)与计算流体动力学(computational fluid dynamics,简称CFD)耦合方法,建立了内部...土体几何因素(粒径比、细粒含量、相对密实度等)不仅影响土体内部稳定性,同时对侵蚀进程有着重要影响。基于离散单元法(discrete element method,简称DEM)与计算流体动力学(computational fluid dynamics,简称CFD)耦合方法,建立了内部不稳定土渗流-侵蚀三维计算模型。考虑细粒含量及相对密实度对内部侵蚀过程的耦合影响,对细观变量:土体孔径分布曲线、颗粒接触数目以及内部传力机制进行分析,以揭示细粒含量与相对密实度的影响的细观机制。研究结果表明:相对密实度的增加降低了侵蚀质量比,且该影响程度与细粒含量相关,细粒含量越高,相对密实度的影响更加明显;内部不稳定土体渗蚀后沿渗流方向可分为上游侵蚀区、中部稳定区及下游侵蚀区。土体渗透性在侵蚀过程中的增长幅度随相对密实度的降低而逐渐增加,随细粒含量的增加而增加;相对密实度对渗蚀过程的影响可归因于三方面:相同水力梯度下渗流流量不同,内部孔隙尺寸分布存在差异,以及细颗粒对土体内部应力传递的贡献不同。研究结果加深了土体几何因素对内部渗蚀过程影响的理解,并为宏观侵蚀本构的建立提供了参考。展开更多
The development of advanced aircraft relies on high performance thermal-structural materials,and carbon/carbon com-posites(C/C)composited with ultrahigh-temperature ceramics are ideal candidates.However,the traditiona...The development of advanced aircraft relies on high performance thermal-structural materials,and carbon/carbon com-posites(C/C)composited with ultrahigh-temperature ceramics are ideal candidates.However,the traditional routes of compositing are either inefficient and expensive or lead to a non-uniform distribution of ceramics in the matrix.Compared with the traditional C/C-ZrC-SiC composites prepared by the reactive melt infiltration of ZrSi_(2),C/C-ZrB_(2)-ZrC-SiC composites prepared by the vacuum infiltration of ZrB_(2) combined with reactive melt infiltration have the higher content and more uniform distribution of the introduced ceramic phases.The mass and linear ablation rates of the C/C-ZrB_(2)-ZrC-SiC composites were respectively 68.9%and 29.7%lower than those of C/C-ZrC-SiC composites prepared by reactive melt infiltration.The ablation performance was improved because the volatilization of B_(2)O_(3),removes some of the heat,and the more uniformly distributed ZrO_(2),that helps produce a ZrO2-SiO2 continu-ous protective layer,hinders oxygen infiltration and decreases ablation.展开更多
Square piles of reinforced concrete(RC)in marine environments are susceptible to chloride-inducedcorrosion.A novel reverse-seepage technique(RST)is applied to square piles to block the intrusion of chlorides.Thisresea...Square piles of reinforced concrete(RC)in marine environments are susceptible to chloride-inducedcorrosion.A novel reverse-seepage technique(RST)is applied to square piles to block the intrusion of chlorides.Thisresearch introduces a computational model designed to predict the lifespan of corrosion initiation in reinforced concretesquare piles when applied reverse-seepage pressure.The model considers the impacts of chloride binding and the tripletime-dependence property among the permeability,the corrected surface chloride concentration,and the diffusioncoefficient.The proposed numerical model is solved using the alternating direction implicit(ADI)approach,and itsaccuracy and reliability are evaluated by contrasting the computational outcomes with the analytical solution andexperimental results.Furthermore,the primary factors contributing to the corrosion of reinforced concrete square pilesare analyzed.The results indicate that applying RST can decrease the chloride penetration depth and prolong the lifespanof corrosion initiation in square piles.The water-cement ratio and reverse seepage pressure are the most influentialfactors.A water pressure of 0.4 MPa can double the life of concrete,and the durable life of concrete with a water-cementratio of 0.3 can reach 100 years.展开更多
Specimens of ZM5 magnesium alloy were dipped into the mixed powder of Al and Zn at (390±5) ℃ for 8 h in argon gas protective environment and subjected to surface diffusion alloying processing (SDAP). The ero...Specimens of ZM5 magnesium alloy were dipped into the mixed powder of Al and Zn at (390±5) ℃ for 8 h in argon gas protective environment and subjected to surface diffusion alloying processing (SDAP). The erosion wear behaviors of ZM5 magnesium alloy before and after SDAP were investigated in two different erosion wear environments: oil and quartz environment; tap water and quartz environment. The surfaces of erosion wear specimens exhibited cutting scratch grooves in the oil and quartz environment. Corrosive attack was weak and cutting wear mechanism was responsible for the mass loss. When the erosion wear medium was changed to tap water and quartz environment, corrosion pits and cracks were obviously observed after erosion wear test. The corrosion from tap water and the scour from quartz intensified mass losses. Compared with the untreated specimens, the application of SDAP improved the erosion wear resistance in the same environment.展开更多
Chromium coatings with and without Al_2O_3 or Y_2O_3 particles were prepared by chromizing the as-deposited Ni-film with and without Al_2O_3 or Y_2O_3 particles using a conventional pack-cementation method at 800 ℃. ...Chromium coatings with and without Al_2O_3 or Y_2O_3 particles were prepared by chromizing the as-deposited Ni-film with and without Al_2O_3 or Y_2O_3 particles using a conventional pack-cementation method at 800 ℃. The cyclic oxidation at 800 ℃ and hot corrosion in molten 75% Na2SO4+25% NaC1 at 800 ℃ of the three different chromizing coatings were investigated. The effects of Al_2O_3 or Y_2O_3 on the cyclic oxidation and hot corrosion behavior of the chromizing coatings were discussed. Microstructure results show that the codeposited Al_2O_3 or Y_2O_3 particles significantly retard the grain growth of the chromizing coating, which increases the cyclic oxidation and hot corrosion resistance of the chromizing coatings, due to the more rapid formation of purer and denser chromia scnle展开更多
Vacuum thermal diffusion technique was applied to preparing alloying coating on AZ31 B magnesium alloy. The microstructure and phase composition of the coatings prepared at different holding time were investigated in ...Vacuum thermal diffusion technique was applied to preparing alloying coating on AZ31 B magnesium alloy. The microstructure and phase composition of the coatings prepared at different holding time were investigated in detail using optical microscopy(OM), scanning electron microscopy(SEM), energy dispersive spectrometer(EDS) and X-ray diffraction(XRD), and so on. The microhardness tester and electrochemical workstation(PS-168a) were used to measure the microhardness and corrosion resistance of the alloying coating. The results showed that the alloying coatings gradually generated with the extension of holding time under constant temperature. And the obvious bonding interface between the coating and substrate was observed, and the bonding interface was changed from smooth to zigzag. EDS and XRD analyses showed that the microstructure of alloying coating mainly consisted of eutectic α-Mg phase and continuous network β-Al(12)Mg(17) phase. The average microhardness of the coatings increased by 113% in comparison to the substrate, and the self-corrosion potential increased from-1.389 to-1.268 V at the same time.展开更多
Al-containing coatings were prepared on AZ31 magnesium alloy by pack-cementation technology.X-ray diffraction(XRD),backscattered electron imaging(BSEI)and energy dispersive spectroscopy(EDS)were jointly employed to ch...Al-containing coatings were prepared on AZ31 magnesium alloy by pack-cementation technology.X-ray diffraction(XRD),backscattered electron imaging(BSEI)and energy dispersive spectroscopy(EDS)were jointly employed to characterize the phases,microstructure and composition of the coated samples.The results show that the feedstock composition has a significant impact on the phases,microstructure and thickness of the coatings.For the sample with AlCl3 powder as the activator,the coating is very thick and composed of gradient phases and structures from surface to inside,including small amount ofb-Mg2Al3,coarse eutectic-like structure ofγ-Mg17Al12+δ-Mg,and fineγ-Mg17Al12 precipitations.In contrast,for the sample with AlCl3 and pure Al composite powders as the activator,the coating is relatively thin and contains a thin Al2O3 layer and a small amount of fineγ-Mg17Al12 precipitates.For the pack-cementation aluminizing that is not protected by high-vacuum or inert gas,the addition of pure Al powders can easily introduce the Al2O3 layer into the coating to prevent active Al ions further penetrating into the magnesium matrix,resulting in the thin Al-containing coating.The microhardness and corrosion behavior of the two kinds of aluminized coatings were also studied and discussed.展开更多
The relationships between soil erodibility factor (K) and soil saturated permeability (gfs) for cultivated Acrisols derived from Quaternary red clay and Cambisols derived from red sandstone were studied and quanti...The relationships between soil erodibility factor (K) and soil saturated permeability (gfs) for cultivated Acrisols derived from Quaternary red clay and Cambisols derived from red sandstone were studied and quantified using a rainfall simulator and Guelph permeameter in a hilly area of subtropical China. A negative correlation existed between Kfs of the topsoil (0-5 cm) and K. The empirical expression K ≈ α × Kfs^-b+c, where a, b and c are the structural coefficients related to soil properties, such as soil type, soil parent material, organic matter, pH and mechanical composition, best described the relationship between soil saturated permeability and soil erodibility.展开更多
In order to obtain a high-performance surface on TiAl alloy that can meet the requirements in hot corrosion environment,Si-Al-Y coatings were fabricated by pack cementation process at 1050℃for 4 h.Corrosion behaviors...In order to obtain a high-performance surface on TiAl alloy that can meet the requirements in hot corrosion environment,Si-Al-Y coatings were fabricated by pack cementation process at 1050℃for 4 h.Corrosion behaviors of the TiAl alloy with and without Si-Al-Y coatings are compared to illustrate the factors and corresponding mechanism in molten salt environment of 25 wt%K2SO4 and 75 wt%Na2SO4 at 900°C.The obtained Si-Al-Y coating was mainly composed of a TiSi2 outer layer,a(Ti,X)5Si4 and(Ti,X)5Si3(X represents Nb or Cr element)middle layer,a TiAl2 inner layer and a Al-rich inter-diffusion zone.The inter-phase selective corrosion containing corrosion pits extending alongα2 phase from lamellar interfaces in hot corrosion tested TiAl alloy was observed.However,by being coated with Si-Al-Y coating,the hot corrosion performance of TiAl alloy was improved remarkably.展开更多
文摘土体几何因素(粒径比、细粒含量、相对密实度等)不仅影响土体内部稳定性,同时对侵蚀进程有着重要影响。基于离散单元法(discrete element method,简称DEM)与计算流体动力学(computational fluid dynamics,简称CFD)耦合方法,建立了内部不稳定土渗流-侵蚀三维计算模型。考虑细粒含量及相对密实度对内部侵蚀过程的耦合影响,对细观变量:土体孔径分布曲线、颗粒接触数目以及内部传力机制进行分析,以揭示细粒含量与相对密实度的影响的细观机制。研究结果表明:相对密实度的增加降低了侵蚀质量比,且该影响程度与细粒含量相关,细粒含量越高,相对密实度的影响更加明显;内部不稳定土体渗蚀后沿渗流方向可分为上游侵蚀区、中部稳定区及下游侵蚀区。土体渗透性在侵蚀过程中的增长幅度随相对密实度的降低而逐渐增加,随细粒含量的增加而增加;相对密实度对渗蚀过程的影响可归因于三方面:相同水力梯度下渗流流量不同,内部孔隙尺寸分布存在差异,以及细颗粒对土体内部应力传递的贡献不同。研究结果加深了土体几何因素对内部渗蚀过程影响的理解,并为宏观侵蚀本构的建立提供了参考。
文摘The development of advanced aircraft relies on high performance thermal-structural materials,and carbon/carbon com-posites(C/C)composited with ultrahigh-temperature ceramics are ideal candidates.However,the traditional routes of compositing are either inefficient and expensive or lead to a non-uniform distribution of ceramics in the matrix.Compared with the traditional C/C-ZrC-SiC composites prepared by the reactive melt infiltration of ZrSi_(2),C/C-ZrB_(2)-ZrC-SiC composites prepared by the vacuum infiltration of ZrB_(2) combined with reactive melt infiltration have the higher content and more uniform distribution of the introduced ceramic phases.The mass and linear ablation rates of the C/C-ZrB_(2)-ZrC-SiC composites were respectively 68.9%and 29.7%lower than those of C/C-ZrC-SiC composites prepared by reactive melt infiltration.The ablation performance was improved because the volatilization of B_(2)O_(3),removes some of the heat,and the more uniformly distributed ZrO_(2),that helps produce a ZrO2-SiO2 continu-ous protective layer,hinders oxygen infiltration and decreases ablation.
基金Projects(52178371,52108355,52178321)supported by the National Natural Science Foundation of ChinaProject(202305)supported by the Research Project of Engineering Research Centre of Rock-Soil Drilling&Excavation and Protection,Ministry of Education,China。
文摘Square piles of reinforced concrete(RC)in marine environments are susceptible to chloride-inducedcorrosion.A novel reverse-seepage technique(RST)is applied to square piles to block the intrusion of chlorides.Thisresearch introduces a computational model designed to predict the lifespan of corrosion initiation in reinforced concretesquare piles when applied reverse-seepage pressure.The model considers the impacts of chloride binding and the tripletime-dependence property among the permeability,the corrected surface chloride concentration,and the diffusioncoefficient.The proposed numerical model is solved using the alternating direction implicit(ADI)approach,and itsaccuracy and reliability are evaluated by contrasting the computational outcomes with the analytical solution andexperimental results.Furthermore,the primary factors contributing to the corrosion of reinforced concrete square pilesare analyzed.The results indicate that applying RST can decrease the chloride penetration depth and prolong the lifespanof corrosion initiation in square piles.The water-cement ratio and reverse seepage pressure are the most influentialfactors.A water pressure of 0.4 MPa can double the life of concrete,and the durable life of concrete with a water-cementratio of 0.3 can reach 100 years.
基金Project (2011JY009) supported by Education Department of Shaanxi Province, China
文摘Specimens of ZM5 magnesium alloy were dipped into the mixed powder of Al and Zn at (390±5) ℃ for 8 h in argon gas protective environment and subjected to surface diffusion alloying processing (SDAP). The erosion wear behaviors of ZM5 magnesium alloy before and after SDAP were investigated in two different erosion wear environments: oil and quartz environment; tap water and quartz environment. The surfaces of erosion wear specimens exhibited cutting scratch grooves in the oil and quartz environment. Corrosive attack was weak and cutting wear mechanism was responsible for the mass loss. When the erosion wear medium was changed to tap water and quartz environment, corrosion pits and cracks were obviously observed after erosion wear test. The corrosion from tap water and the scour from quartz intensified mass losses. Compared with the untreated specimens, the application of SDAP improved the erosion wear resistance in the same environment.
基金Project(11531319)supported by Scientific Research Fund of Heilongjiang Provincial Education Department,China
文摘Chromium coatings with and without Al_2O_3 or Y_2O_3 particles were prepared by chromizing the as-deposited Ni-film with and without Al_2O_3 or Y_2O_3 particles using a conventional pack-cementation method at 800 ℃. The cyclic oxidation at 800 ℃ and hot corrosion in molten 75% Na2SO4+25% NaC1 at 800 ℃ of the three different chromizing coatings were investigated. The effects of Al_2O_3 or Y_2O_3 on the cyclic oxidation and hot corrosion behavior of the chromizing coatings were discussed. Microstructure results show that the codeposited Al_2O_3 or Y_2O_3 particles significantly retard the grain growth of the chromizing coating, which increases the cyclic oxidation and hot corrosion resistance of the chromizing coatings, due to the more rapid formation of purer and denser chromia scnle
基金Project(2015GY167)supported by the Science and Technology Department of Shaanxi Province,ChinaProject(2014cxy-05-1)supported by the Science and Technology Bureau of Yulin,China
文摘Vacuum thermal diffusion technique was applied to preparing alloying coating on AZ31 B magnesium alloy. The microstructure and phase composition of the coatings prepared at different holding time were investigated in detail using optical microscopy(OM), scanning electron microscopy(SEM), energy dispersive spectrometer(EDS) and X-ray diffraction(XRD), and so on. The microhardness tester and electrochemical workstation(PS-168a) were used to measure the microhardness and corrosion resistance of the alloying coating. The results showed that the alloying coatings gradually generated with the extension of holding time under constant temperature. And the obvious bonding interface between the coating and substrate was observed, and the bonding interface was changed from smooth to zigzag. EDS and XRD analyses showed that the microstructure of alloying coating mainly consisted of eutectic α-Mg phase and continuous network β-Al(12)Mg(17) phase. The average microhardness of the coatings increased by 113% in comparison to the substrate, and the self-corrosion potential increased from-1.389 to-1.268 V at the same time.
基金the National Natural Science Foundation of China(No.51575073)International Cooperation Special Project in Science and Technology of China(No.2015DFR70480)Scientific and Technological Research Program of Chongqing,China(Nos.cstc2017jcyjBX0031,cstc2018jszx-cyzdX0126).
文摘Al-containing coatings were prepared on AZ31 magnesium alloy by pack-cementation technology.X-ray diffraction(XRD),backscattered electron imaging(BSEI)and energy dispersive spectroscopy(EDS)were jointly employed to characterize the phases,microstructure and composition of the coated samples.The results show that the feedstock composition has a significant impact on the phases,microstructure and thickness of the coatings.For the sample with AlCl3 powder as the activator,the coating is very thick and composed of gradient phases and structures from surface to inside,including small amount ofb-Mg2Al3,coarse eutectic-like structure ofγ-Mg17Al12+δ-Mg,and fineγ-Mg17Al12 precipitations.In contrast,for the sample with AlCl3 and pure Al composite powders as the activator,the coating is relatively thin and contains a thin Al2O3 layer and a small amount of fineγ-Mg17Al12 precipitates.For the pack-cementation aluminizing that is not protected by high-vacuum or inert gas,the addition of pure Al powders can easily introduce the Al2O3 layer into the coating to prevent active Al ions further penetrating into the magnesium matrix,resulting in the thin Al-containing coating.The microhardness and corrosion behavior of the two kinds of aluminized coatings were also studied and discussed.
基金Project supported by the National Natural Sciences Foundation of China (No. 40471081)the National Key Basic Research Support Foundation (No. G1999011810)the Knowledge Innovation Program of the Chinese Academy of Sciences (No. KZCX3-SW-422)
文摘The relationships between soil erodibility factor (K) and soil saturated permeability (gfs) for cultivated Acrisols derived from Quaternary red clay and Cambisols derived from red sandstone were studied and quantified using a rainfall simulator and Guelph permeameter in a hilly area of subtropical China. A negative correlation existed between Kfs of the topsoil (0-5 cm) and K. The empirical expression K ≈ α × Kfs^-b+c, where a, b and c are the structural coefficients related to soil properties, such as soil type, soil parent material, organic matter, pH and mechanical composition, best described the relationship between soil saturated permeability and soil erodibility.
基金Project(2020AAC02025)supported by the Natural Science Foundation of Ningxia Province,ChinaProject(51961003)supported by the National Natural Science Foundation of China+1 种基金Project(TJGC2019040)supported by the Ningxia Youth Talents Supporting Program,ChinaProject(2020xyzc103)supported by the Foundation of North Minzu University,China。
文摘In order to obtain a high-performance surface on TiAl alloy that can meet the requirements in hot corrosion environment,Si-Al-Y coatings were fabricated by pack cementation process at 1050℃for 4 h.Corrosion behaviors of the TiAl alloy with and without Si-Al-Y coatings are compared to illustrate the factors and corresponding mechanism in molten salt environment of 25 wt%K2SO4 and 75 wt%Na2SO4 at 900°C.The obtained Si-Al-Y coating was mainly composed of a TiSi2 outer layer,a(Ti,X)5Si4 and(Ti,X)5Si3(X represents Nb or Cr element)middle layer,a TiAl2 inner layer and a Al-rich inter-diffusion zone.The inter-phase selective corrosion containing corrosion pits extending alongα2 phase from lamellar interfaces in hot corrosion tested TiAl alloy was observed.However,by being coated with Si-Al-Y coating,the hot corrosion performance of TiAl alloy was improved remarkably.