The production of dump leaching of the Dexing Copper Mine was affected by a preferential solution flow. Formative mechanism of the preferential solution flow was investigated by analyzing the relationship between both...The production of dump leaching of the Dexing Copper Mine was affected by a preferential solution flow. Formative mechanism of the preferential solution flow was investigated by analyzing the relationship between both dump permeability and surface tension and ore diameter. The preferential solution flow occured in the fine ore area when the application rate was low. The preferential solution flow entered into the coarse ore area because the negative pore water pressure disappeared with an increase of the application rate. The preferential solute transportation experiment was conducted by selecting NaCl as mineral. Results of the experiment showed that the concentration of the outflow solution reduced over time. The concentration of the coarse ore area outflow solution was greater than that of the fine ore area. The process of NaCl leaching can be divided into two stages. NaCl was carried out directly by diffusion--convection during the first stage, so the leaching rate increased sharply. But in the second stage, only a small amount of NaCl dissolved in the immobile water. The leaching rate increased slowly because NaC1, dissolved in the immobile water, can only be leached by diffusion.展开更多
In order to quantify the effect of matrix shrinkage on reservoir permeability during coalbed methane production, coal samples from Huozhou, Changzhi and Jincheng areas in Shanxi province （classified as high-volatile ...In order to quantify the effect of matrix shrinkage on reservoir permeability during coalbed methane production, coal samples from Huozhou, Changzhi and Jincheng areas in Shanxi province （classified as high-volatile bituminous coal, low-volatile bituminous coal and anthracite, respectively） were collected, and adsorption-induced coal swelling in methane were determined by an optical method at 40 ℃ and pressure up to 12 MPa. All three coals showed similar behavior-that swelling increased as a function of pressure up to about 10 MPa but thereafter no further increase in swelling was observed. Swelling in the direction perpendicular to the bedding plane is greater than that parallel to the bedding plane, and the differences are about 7.77-8.33%. The maximum volumetric swelling ranges from 2.73% to 3.21 %-increasing with increasing coal rank. The swelling data can be described by a modified DR model. In addition, swelling increases with the amount of adsorption. However, the increase shows a relatively slower stage followed by a relatively faster stage instead of a linear increase. Based on the assumption that sorption-induced swelling/shrinkage of coal in methane is reversible, the permeability increases induced by coal shrinkage during methane desorption was analyzed, and the results indicate that the permeability change is larger for higher rank coal in the same unit of pressure depletion.展开更多
基金Project 50325415 supported by the National Science Fund for Distinguished Young Scholars, 50574099 and 50321402 by the National Natural ScienceFoundation of China and 2004CB619205 by the National Key Fundamental Research and Development Program
文摘The production of dump leaching of the Dexing Copper Mine was affected by a preferential solution flow. Formative mechanism of the preferential solution flow was investigated by analyzing the relationship between both dump permeability and surface tension and ore diameter. The preferential solution flow occured in the fine ore area when the application rate was low. The preferential solution flow entered into the coarse ore area because the negative pore water pressure disappeared with an increase of the application rate. The preferential solute transportation experiment was conducted by selecting NaCl as mineral. Results of the experiment showed that the concentration of the outflow solution reduced over time. The concentration of the coarse ore area outflow solution was greater than that of the fine ore area. The process of NaCl leaching can be divided into two stages. NaCl was carried out directly by diffusion--convection during the first stage, so the leaching rate increased sharply. But in the second stage, only a small amount of NaCl dissolved in the immobile water. The leaching rate increased slowly because NaC1, dissolved in the immobile water, can only be leached by diffusion.
基金funded by the National Key Technology Support Program of China (No. 2014BAC18B02)the National Natural Science Foundation of China (Nos. 41272176 and 41202116)
文摘In order to quantify the effect of matrix shrinkage on reservoir permeability during coalbed methane production, coal samples from Huozhou, Changzhi and Jincheng areas in Shanxi province （classified as high-volatile bituminous coal, low-volatile bituminous coal and anthracite, respectively） were collected, and adsorption-induced coal swelling in methane were determined by an optical method at 40 ℃ and pressure up to 12 MPa. All three coals showed similar behavior-that swelling increased as a function of pressure up to about 10 MPa but thereafter no further increase in swelling was observed. Swelling in the direction perpendicular to the bedding plane is greater than that parallel to the bedding plane, and the differences are about 7.77-8.33%. The maximum volumetric swelling ranges from 2.73% to 3.21 %-increasing with increasing coal rank. The swelling data can be described by a modified DR model. In addition, swelling increases with the amount of adsorption. However, the increase shows a relatively slower stage followed by a relatively faster stage instead of a linear increase. Based on the assumption that sorption-induced swelling/shrinkage of coal in methane is reversible, the permeability increases induced by coal shrinkage during methane desorption was analyzed, and the results indicate that the permeability change is larger for higher rank coal in the same unit of pressure depletion.
