Cobalt-free perovskite-type oxides BaFel_yTayO3-6 （0 _〈 y -〈 0.2） were synthesized via a simple solid state reac- tion. The cubic perovskite structure can be obtained when y is over 0.1. BaFeo.Ta0.lO3-6 （BFT0.1）...Cobalt-free perovskite-type oxides BaFel_yTayO3-6 （0 _〈 y -〈 0.2） were synthesized via a simple solid state reac- tion. The cubic perovskite structure can be obtained when y is over 0.1. BaFeo.Ta0.lO3-6 （BFT0.1） membrane shows the highest oxygen permeation flux, which can reach 1.6 ml. min- 1. cm-2 at 950 ℃ under the gradient of air/He. The O2-TPD results reveal that BaFe0.9Ta0.lO3-a material shows an excellent reversibility and phase structure stability in air. The oxygen permeation flux is limited by the bulk diffusion when the membrane thick- ness is over 0.8 mm, and it is limited by both the bulk diffusion and the surface exchange when the membrane thickness is below 0.5 mm. Stable oxygen permeation fluxes are obtained during 180 h operation.展开更多
Method of direct osmosis （also known as nonequivalent ion transfer through semipermeable membrane） was developed in 1971 and patented in 1974 by one of authors. There were no publications because the patent was secr...Method of direct osmosis （also known as nonequivalent ion transfer through semipermeable membrane） was developed in 1971 and patented in 1974 by one of authors. There were no publications because the patent was secreted. Moreover, necessary quality of membranes--high negative selectivity and apparatus for this process was provided only in 2000s （patented in 2008）. Technology of direct osmosis is able to solve a number of problems of industry, such as extracting of rare elements （Re, Ge, U, etc.） from natural and manufacturing water. The authors need to mention that direct osmosis makes possible to create rentable technology of greenhouse gases trapping and burying. It will be shown in the next article. And this article is about the basic idea--nonequivalent ion transfer through semipermeable membrane or direct osmosis.展开更多
基金the National Science Fund for Distinguished Young Scholars of China(No.21225625)the National Natural Science Foundation of China(No.21176087)the Specialized Research Fund for the Doctoral Program of Higher Education(No.20110172110013)
文摘Cobalt-free perovskite-type oxides BaFel_yTayO3-6 （0 _〈 y -〈 0.2） were synthesized via a simple solid state reac- tion. The cubic perovskite structure can be obtained when y is over 0.1. BaFeo.Ta0.lO3-6 （BFT0.1） membrane shows the highest oxygen permeation flux, which can reach 1.6 ml. min- 1. cm-2 at 950 ℃ under the gradient of air/He. The O2-TPD results reveal that BaFe0.9Ta0.lO3-a material shows an excellent reversibility and phase structure stability in air. The oxygen permeation flux is limited by the bulk diffusion when the membrane thick- ness is over 0.8 mm, and it is limited by both the bulk diffusion and the surface exchange when the membrane thickness is below 0.5 mm. Stable oxygen permeation fluxes are obtained during 180 h operation.
文摘Method of direct osmosis （also known as nonequivalent ion transfer through semipermeable membrane） was developed in 1971 and patented in 1974 by one of authors. There were no publications because the patent was secreted. Moreover, necessary quality of membranes--high negative selectivity and apparatus for this process was provided only in 2000s （patented in 2008）. Technology of direct osmosis is able to solve a number of problems of industry, such as extracting of rare elements （Re, Ge, U, etc.） from natural and manufacturing water. The authors need to mention that direct osmosis makes possible to create rentable technology of greenhouse gases trapping and burying. It will be shown in the next article. And this article is about the basic idea--nonequivalent ion transfer through semipermeable membrane or direct osmosis.
