SAPO-34 was synthesized with n-butylamine（BA） as a template for the first time.Crystallization temperature and initial Si amount were important factors leading to successful syntheses.Lamellar AlPO-kanemite tends to...SAPO-34 was synthesized with n-butylamine（BA） as a template for the first time.Crystallization temperature and initial Si amount were important factors leading to successful syntheses.Lamellar AlPO-kanemite tends to form as the major phase or as an impurity of SAPO-34 at lower crystallization temperatures,though a higher initial Si amount may offer a positive effect on the crystallization of SAPO-34 that mitigates the low temperature.Higher temperature（240℃） can effectively suppress the generation of lamellar materials and allow the synthesis of pure SAPO-34 with a wider range of Si incorporation.The crystallization processes at 200 and 240℃ were investigated and compared.We used the aminothermal method to synthesize SAPO-34-BA at 240℃ and also found n-propylamine is a suitable template for the synthesis of SAPO-34.The SAPO-34-BA products were characterized by many techniques.SAPO-34-BA has good thermal stability,crystallinity and porosity.BA remained intact in the crystals with ~1.8 BA molecule per chabazite cage.The catalytic performance of SAPO-34 was tested in the methanol amination reaction,which showed high methanol conversion and selectivity for methylamine plus dimethylamine under the conditions investigated,suggesting that this material is a good candidate for the synthesis of methylamines.展开更多
This study investigates the major patterns of large-scale tilted ridges(LSTRS)over the Eurasian continent and their connections with large-scale surface air temperature during boreal winter.A total number of 134 LSTR ...This study investigates the major patterns of large-scale tilted ridges(LSTRS)over the Eurasian continent and their connections with large-scale surface air temperature during boreal winter.A total number of 134 LSTR events with zonal extent exceeding 90°of longitude on the peak day are identified.Using self-organizing map(SOM),the LSTRs are classified into five clusters that are characterized by different spatial distributions and orientations.The leading two clusters are closely associated with extensive and persistent cold events over different places.Considering the first cluster,LSTRs extend from the Ural Mountains to Northeast Asia and are favorable for the amplification and southeastward extension of the Siberian high.Therefore,this cluster is closely associated with the occurrence of extensive and persistent cold events in china.In comparison with the first cluster,the LSTRs of second group are situated to the west,with starting points from the Kola Peninsula,and cause extensive and persistent cold events over Eastern Europe,central Asia,and central Siberia.The results suggest that the vertical coupling between LSTRs and the corresponding anomalous sea level pressure is crucial for the persistent cold temperature events associated with the leading two SOM clusters.展开更多
In this work we show that homogeneous Neumann boundary conditions inhibit the Coleman-Weinberg mechanism for spontaneous symmetry breaking in the scalar electrodynamics if the length of the finite region is small enou...In this work we show that homogeneous Neumann boundary conditions inhibit the Coleman-Weinberg mechanism for spontaneous symmetry breaking in the scalar electrodynamics if the length of the finite region is small enough （a = e2Mφ-1, where M, is the mass of the scalar field generated by the Coleman-Weinberg mechanism）.展开更多
The dinoflagellate Noctiluca scintillans is one of the most important and abundant red tide organisms and it is distributed world-wide. It occurs in two forms. Red Noctiluca is heterotrophic and fills the role of one ...The dinoflagellate Noctiluca scintillans is one of the most important and abundant red tide organisms and it is distributed world-wide. It occurs in two forms. Red Noctiluca is heterotrophic and fills the role of one of the microzooplankton grazers in the foodweb. In contrast, green Noctiluca contains a photosynthetic symbiont Pedinomonas noctilucae （a prasinophyte）, but it also feeds on other plankton when the food supply is abundant. In this review, we document the global distribution of these two forms and include the first maps of their global distribution. Red Noctiluca occurs widely in the temperate to sub-tropical coastal regions of the world. It occurs over a wide temperature range of about 10℃ to 25℃ and at higher salinities （generally not in estuaries）. It is particularly abundant in high productivity areas such as upwelling or eutrophic areas where diatoms dominate since they are its preferred food source. Green Noctiluca is much more restricted to a temperature range of 25℃-30℃ and mainly occurs in tropical waters of Southeast Asia, Bay of Bengal （east coast of India）, in the eastern, western and northern Arabian Sea, the Red Sea, and recently it has become very abundant in the Gulf of Oman. Red and green Noctiluca do overlap in their distribution in the eastern, northern and western Arabian Sea with a seasonal shift from green Noctiluca in the cooler winter convective mixing, higher productivity season, to red Noctiluca in the more oligotrophic warmer summer season.展开更多
The Iberian Peninsula was first inhabited by Celts, Iberians, Carthaginians, Romans, Visigoths, and later Berbers. How is it possible that in a spam of only 50 years, the Berbers were able to go pass the Pyrenees and ...The Iberian Peninsula was first inhabited by Celts, Iberians, Carthaginians, Romans, Visigoths, and later Berbers. How is it possible that in a spam of only 50 years, the Berbers were able to go pass the Pyrenees and practically ruled what today is Portugal, Spain, and region of France？ This article attempts to uncover the sociological aspects that helped the Berbers and Arabs rule the Iberian Peninsula quite rapidly. It was due to the commonalities and not the differences that Spain＇s political leaders went from Arian Visigoths to Muslims for the next 800 years. Ignacio Olague＇s book La Revoluci6n Isldmica en Occidente （The Islamic Revolution in the West）, also translated as Les Arabes N＇ont Jamais Envahi l＇Espagne （The Arabs Never Invaded Spain）, serves as one instrument to shed light to how this historical event took place. The result of this fusion of cultures not only created a rich civilization that would planted the seeds of the Renaissance three centuries before it began in Italy, but also contributed to the formation of a new language （between 720-750 AD）： El castellano o espahol （Spanish language）, which today is the official language in 21 st countries.展开更多
Siberia experienced intense heat waves in 2020,and this unusual warming may have caused more wildfires and losses of permafrost than normal,both of which can be devastating to ecosystems.Based on observational data,th...Siberia experienced intense heat waves in 2020,and this unusual warming may have caused more wildfires and losses of permafrost than normal,both of which can be devastating to ecosystems.Based on observational data,this paper shows that there was an intense warming trend over Siberia(60°–75°N,70°–130°E)in June during 1979–2020.The linear trend of the June surface air temperature is 0.90℃/10 yr over Siberia,which is much larger than the area with the same latitudes(60°–75°N,0°–360°,trend of 0.46℃/10 yr).The warming over Siberia extends from the surface to about 300 h Pa.Increased geopotential height in the mid-to-upper troposphere plays an important role in shaping the Siberian warming,which favors more shortwave radiation reaching the surface and further heating the overlying atmosphere via upward turbulent heat flux and longwave radiation.The Siberian warming is closely related to Arctic sea-ice decline,especially the sea ice over northern Barents Sea and Kara Sea.Numerical experiments carried out using and atmospheric general circulation model(IAP-AGCM4.1)confirmed the contribution of the Arctic sea-ice decline to the Siberian warming and the related changes in circulations and surface fluxes.展开更多
The planetary wave response to global warm ing with single forcing of greenhouse gases （GHGs） is investigated in this study by using a total of 11 model results that anticipated CMIP3 4XCO2 experiments. It is shown ...The planetary wave response to global warm ing with single forcing of greenhouse gases （GHGs） is investigated in this study by using a total of 11 model results that anticipated CMIP3 4XCO2 experiments. It is shown that the amplitudes of the planetary wave fluxes over Siberia, the Eastern North Pacific, and the North Atlantic decrease by approximately -10% to -30% in the warming context. In particular, the vertical wave flux over the Eastern North Pacific significantly decreases by -28.6%. The weakening of the planetary waves is partly associated with the decreased land-sea thermal contrast, which may be caused by the radiation effect of CO2 and the different surface heat capacities of land and sea. The present work provides a clear understanding of the re sponses of planetary waves to GHGs forcing.展开更多
The genetic models are greatly important in the analysis of genetic epidemiologic studies and many of the studies are conducted using the trend test under the additive model. However, for many complex diseases and tra...The genetic models are greatly important in the analysis of genetic epidemiologic studies and many of the studies are conducted using the trend test under the additive model. However, for many complex diseases and traits, the underlying genetic model for a genetic locus is usually uncertain. So a robust test free of genetic model is appropriate. In this paper, the authors propose a model-embedded trend test by incorporating Hardy-Weinberg equilibrium information and obtain the explicit formula to calculate its statistical significance. Extensive simulation studies show the proposed test is more robust than the existing procedures. Finally, a real application is further analyzed to show the performance of the proposed test.展开更多
Since a frame for a Hilbert space must be a Bessel sequence, many results on(quasi-)affine bi-frame are established under the premise that the corresponding(quasi-)affine systems are Bessel sequences. However,it is ve...Since a frame for a Hilbert space must be a Bessel sequence, many results on(quasi-)affine bi-frame are established under the premise that the corresponding(quasi-)affine systems are Bessel sequences. However,it is very technical to construct a(quasi-)affine Bessel sequence. Motivated by this observation, in this paper we introduce the notion of weak(quasi-)affine bi-frame(W(Q)ABF) in a general reducing subspace for which the Bessel sequence hypothesis is not needed. We obtain a characterization of WABF, and prove the equivalence between WABF and WQABF under a mild condition. This characterization is used to recover some related known results in the literature.展开更多
The roots of hyperbolic polynomials satisfy the linear inequalities that were previously established for the eigenvalues of Hermitian matrices,after a conjecture by A.Horn.Among them are the so-called Weyl and Lidski...The roots of hyperbolic polynomials satisfy the linear inequalities that were previously established for the eigenvalues of Hermitian matrices,after a conjecture by A.Horn.Among them are the so-called Weyl and Lidskiǐ inequalities.An elementary proof of the latter for hyperbolic polynomials is given.This proof follows an idea from H.Weinberger and is free from representation theory and Schubert calculus arguments,as well as from hyperbolic partial differential equations theory.展开更多
基金supported by the National Natural Science Foundation of China(21676262,21476228,21506207)the Key Research Program of Frontier Sciences of CAS(QYZDB-SSW-JSC040)~~
文摘SAPO-34 was synthesized with n-butylamine（BA） as a template for the first time.Crystallization temperature and initial Si amount were important factors leading to successful syntheses.Lamellar AlPO-kanemite tends to form as the major phase or as an impurity of SAPO-34 at lower crystallization temperatures,though a higher initial Si amount may offer a positive effect on the crystallization of SAPO-34 that mitigates the low temperature.Higher temperature（240℃） can effectively suppress the generation of lamellar materials and allow the synthesis of pure SAPO-34 with a wider range of Si incorporation.The crystallization processes at 200 and 240℃ were investigated and compared.We used the aminothermal method to synthesize SAPO-34-BA at 240℃ and also found n-propylamine is a suitable template for the synthesis of SAPO-34.The SAPO-34-BA products were characterized by many techniques.SAPO-34-BA has good thermal stability,crystallinity and porosity.BA remained intact in the crystals with ~1.8 BA molecule per chabazite cage.The catalytic performance of SAPO-34 was tested in the methanol amination reaction,which showed high methanol conversion and selectivity for methylamine plus dimethylamine under the conditions investigated,suggesting that this material is a good candidate for the synthesis of methylamines.
基金jointly supported by the National Natural Science Foundation of China [grant number 41375064 and41675086]the National Key Technology Research and Development Program of the Ministry of Science and Technology of China [grant number 2015BAC03B03]
文摘This study investigates the major patterns of large-scale tilted ridges(LSTRS)over the Eurasian continent and their connections with large-scale surface air temperature during boreal winter.A total number of 134 LSTR events with zonal extent exceeding 90°of longitude on the peak day are identified.Using self-organizing map(SOM),the LSTRs are classified into five clusters that are characterized by different spatial distributions and orientations.The leading two clusters are closely associated with extensive and persistent cold events over different places.Considering the first cluster,LSTRs extend from the Ural Mountains to Northeast Asia and are favorable for the amplification and southeastward extension of the Siberian high.Therefore,this cluster is closely associated with the occurrence of extensive and persistent cold events in china.In comparison with the first cluster,the LSTRs of second group are situated to the west,with starting points from the Kola Peninsula,and cause extensive and persistent cold events over Eastern Europe,central Asia,and central Siberia.The results suggest that the vertical coupling between LSTRs and the corresponding anomalous sea level pressure is crucial for the persistent cold temperature events associated with the leading two SOM clusters.
文摘In this work we show that homogeneous Neumann boundary conditions inhibit the Coleman-Weinberg mechanism for spontaneous symmetry breaking in the scalar electrodynamics if the length of the finite region is small enough （a = e2Mφ-1, where M, is the mass of the scalar field generated by the Coleman-Weinberg mechanism）.
基金the University Grants Council of Hong Kong and its Area of Excellence Program to PJH. KF was supported by a JSPS grant on the ecophysiology of green Noctiluca in the Gulf of Thailand. PMG received funding from NSF （No. OCE-1015980）This is contribution number 4502 from the University of Maryland Center for Environmental Studies. KY Acknowledges Support from the CAS/SAFEA International Partnership Program for Creative Research Teams （No. KZCXZYW-T001）. DMA received partial funding through the NSF/NIEHS Centers for Oceans and Human Health （No. NIEHS P50 ES012742, NSF OCE- 043072 and OCE-0911031）, and through NSF Grant （No. OCE-0850421）+1 种基金 This paper is based on work partially supported by SCOR/LOICZ Working Group 132, supported by the Scientific Committee on Oceanographic Research （SCOR） through grants from the U.S. National Science Foundation （No OCE-0938349 and OCE-0813697） from the Land-Ocean Interactions in the Coastal Zone （LOICZ） Project and the Chinese Academy of Sciences. We thank A. KANA for assistance with the GIS produced maps and LIU Hao for his assistance with the tables and references.
文摘The dinoflagellate Noctiluca scintillans is one of the most important and abundant red tide organisms and it is distributed world-wide. It occurs in two forms. Red Noctiluca is heterotrophic and fills the role of one of the microzooplankton grazers in the foodweb. In contrast, green Noctiluca contains a photosynthetic symbiont Pedinomonas noctilucae （a prasinophyte）, but it also feeds on other plankton when the food supply is abundant. In this review, we document the global distribution of these two forms and include the first maps of their global distribution. Red Noctiluca occurs widely in the temperate to sub-tropical coastal regions of the world. It occurs over a wide temperature range of about 10℃ to 25℃ and at higher salinities （generally not in estuaries）. It is particularly abundant in high productivity areas such as upwelling or eutrophic areas where diatoms dominate since they are its preferred food source. Green Noctiluca is much more restricted to a temperature range of 25℃-30℃ and mainly occurs in tropical waters of Southeast Asia, Bay of Bengal （east coast of India）, in the eastern, western and northern Arabian Sea, the Red Sea, and recently it has become very abundant in the Gulf of Oman. Red and green Noctiluca do overlap in their distribution in the eastern, northern and western Arabian Sea with a seasonal shift from green Noctiluca in the cooler winter convective mixing, higher productivity season, to red Noctiluca in the more oligotrophic warmer summer season.
文摘The Iberian Peninsula was first inhabited by Celts, Iberians, Carthaginians, Romans, Visigoths, and later Berbers. How is it possible that in a spam of only 50 years, the Berbers were able to go pass the Pyrenees and practically ruled what today is Portugal, Spain, and region of France？ This article attempts to uncover the sociological aspects that helped the Berbers and Arabs rule the Iberian Peninsula quite rapidly. It was due to the commonalities and not the differences that Spain＇s political leaders went from Arian Visigoths to Muslims for the next 800 years. Ignacio Olague＇s book La Revoluci6n Isldmica en Occidente （The Islamic Revolution in the West）, also translated as Les Arabes N＇ont Jamais Envahi l＇Espagne （The Arabs Never Invaded Spain）, serves as one instrument to shed light to how this historical event took place. The result of this fusion of cultures not only created a rich civilization that would planted the seeds of the Renaissance three centuries before it began in Italy, but also contributed to the formation of a new language （between 720-750 AD）： El castellano o espahol （Spanish language）, which today is the official language in 21 st countries.
基金supported by the National Key R&D Pro-gram of China[grant number 2017YFE0111800]the National Natural Science Foundation of China[grant numbers 41790472 and 41822502]。
文摘Siberia experienced intense heat waves in 2020,and this unusual warming may have caused more wildfires and losses of permafrost than normal,both of which can be devastating to ecosystems.Based on observational data,this paper shows that there was an intense warming trend over Siberia(60°–75°N,70°–130°E)in June during 1979–2020.The linear trend of the June surface air temperature is 0.90℃/10 yr over Siberia,which is much larger than the area with the same latitudes(60°–75°N,0°–360°,trend of 0.46℃/10 yr).The warming over Siberia extends from the surface to about 300 h Pa.Increased geopotential height in the mid-to-upper troposphere plays an important role in shaping the Siberian warming,which favors more shortwave radiation reaching the surface and further heating the overlying atmosphere via upward turbulent heat flux and longwave radiation.The Siberian warming is closely related to Arctic sea-ice decline,especially the sea ice over northern Barents Sea and Kara Sea.Numerical experiments carried out using and atmospheric general circulation model(IAP-AGCM4.1)confirmed the contribution of the Arctic sea-ice decline to the Siberian warming and the related changes in circulations and surface fluxes.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41130962 and 41005035)the National Basic Research Project Program of China (973 Program, Grant No.2010CB428606)
文摘The planetary wave response to global warm ing with single forcing of greenhouse gases （GHGs） is investigated in this study by using a total of 11 model results that anticipated CMIP3 4XCO2 experiments. It is shown that the amplitudes of the planetary wave fluxes over Siberia, the Eastern North Pacific, and the North Atlantic decrease by approximately -10% to -30% in the warming context. In particular, the vertical wave flux over the Eastern North Pacific significantly decreases by -28.6%. The weakening of the planetary waves is partly associated with the decreased land-sea thermal contrast, which may be caused by the radiation effect of CO2 and the different surface heat capacities of land and sea. The present work provides a clear understanding of the re sponses of planetary waves to GHGs forcing.
基金partial supported by Special National Key Research and Development Plan under Grant No.2016YFD0400206the Breakthrough Project of Strategic Priority Program of Chinese Academy of Sciences under Grant No.XDB13040600+2 种基金Youth Innovation Promotion Association of Chinese Academy of Sciencethe National Science Foundation of China under Grant Nos.11371353,11661080,61134013Special Fund of the University of Chinese Academy of Sciences for Scientific Research Cooperation
文摘The genetic models are greatly important in the analysis of genetic epidemiologic studies and many of the studies are conducted using the trend test under the additive model. However, for many complex diseases and traits, the underlying genetic model for a genetic locus is usually uncertain. So a robust test free of genetic model is appropriate. In this paper, the authors propose a model-embedded trend test by incorporating Hardy-Weinberg equilibrium information and obtain the explicit formula to calculate its statistical significance. Extensive simulation studies show the proposed test is more robust than the existing procedures. Finally, a real application is further analyzed to show the performance of the proposed test.
基金supported by National Natural Science Foundation of China(Grant No.11271037)Beijing Natural Science Foundation(Grant No.1122008)
文摘Since a frame for a Hilbert space must be a Bessel sequence, many results on(quasi-)affine bi-frame are established under the premise that the corresponding(quasi-)affine systems are Bessel sequences. However,it is very technical to construct a(quasi-)affine Bessel sequence. Motivated by this observation, in this paper we introduce the notion of weak(quasi-)affine bi-frame(W(Q)ABF) in a general reducing subspace for which the Bessel sequence hypothesis is not needed. We obtain a characterization of WABF, and prove the equivalence between WABF and WQABF under a mild condition. This characterization is used to recover some related known results in the literature.
文摘The roots of hyperbolic polynomials satisfy the linear inequalities that were previously established for the eigenvalues of Hermitian matrices,after a conjecture by A.Horn.Among them are the so-called Weyl and Lidskiǐ inequalities.An elementary proof of the latter for hyperbolic polynomials is given.This proof follows an idea from H.Weinberger and is free from representation theory and Schubert calculus arguments,as well as from hyperbolic partial differential equations theory.
