In present study,we report the preparation of coconut shell activated carbon as adsorbent and its appli-cation for Bi(Ⅲ) removal from aqueous solutions.The developed adsorbent was characterized with scanning elec-tro...In present study,we report the preparation of coconut shell activated carbon as adsorbent and its appli-cation for Bi(Ⅲ) removal from aqueous solutions.The developed adsorbent was characterized with scanning elec-tron microscope(SEM),Fourier Transform Infrared(FTIR),C,H,N,S analyzer,and BET surface area analyzer.The parameters examined include agitation time,initial concentration of Bi(Ⅲ),adsorbent dose and temperature.The maximum adsorption of Bi(Ⅲ)(98.72%) was observed at 250 mg·L-1 of Bi(Ⅲ) and adsorbent dose of 0.7 g when agitation was at 160 r·min-1 for 240 min at(299±2) K.The thermodynamic parameters such as Gibb's free energy(△Gθ),enthalpy(△Hθ) and entropy(△Sθ) were evaluated.For the isotherm models applied to adsorption study,the Langmuir isotherm model fits better than the Freundlich isotherm.The maximum adsorption capacity from the Langmuir isotherm was 54.35 mg?g?1 of Bi(Ⅲ).The kinetic study of the adsorption shows that the pseudo second order model is more appropriate than the pseudo first order model.The result shows that,coconut shell ac-tivated carbon is an effective adsorbent to remove Bi(Ⅲ) from aqueous solutions with good adsorption capacity.展开更多
In order to explore the law of photosynthetic active radiation in winter sunlight greenhouse in Panjin and serve the local facility agriculture better,based on the observed data of sunlight greenhouse microclimate and...In order to explore the law of photosynthetic active radiation in winter sunlight greenhouse in Panjin and serve the local facility agriculture better,based on the observed data of sunlight greenhouse microclimate and of the nearby weather station during winter in 2012,the methods of correlation analysis and stepwise regression analysis were adopted to study characteristics of photosynthetic active radiation in sunlight greenhouse and the ratio of photosynthetic active radiation to global radiation under different weather types during winter,and to set up forecast models of photosynthetic active radiation in sunlight greenhouse under different weather types during winter.The results showed that:(1) the daily variation of photosynthetic active radiation in sunlight greenhouse on sunny and cloudy days were both obvious,and photosynthetic active radiation in sunlight greenhouse was 1-38 W/m^2 when it's cloudy.(2) ηPARon typical cloudy day was the highest,on cloudy day was secondary and on sunny day was the minimum during winter;(3) the methods of stepwise regression analysis were respectively adopted to set up models of the highest daily maximum photosynthetic active radiation,the total daily photosynthetic active radiation,daily maximum global radiation,and the total daily global radiation in sunlight greenhouse associated with climate outside,the models passed the 0.01 level of significance,and fitting test had been carried out:4 factors were fitted well on sunny and cloudy day,but fitted poor on overcast day.展开更多
Femtosecond pulsed lasers have been widely used over the past decades due to their capability to fabricate precise patterns at the micro-and nano-lengths scales. A key issue for efficient material processing is the de...Femtosecond pulsed lasers have been widely used over the past decades due to their capability to fabricate precise patterns at the micro-and nano-lengths scales. A key issue for efficient material processing is the determination of the laser parameters used in the experimental set ups. Despite a systematic investigation that has been performed to highlight the impact of every parameter independently, little attention has been drawn on the role of the substrate material on which the irradiated solid is placed. In this work, the influence of the substrate is emphasised for films of various thicknesses, which demonstrates that both the optical and thermophysical properties of the substrate affect the thermal fingerprint on the irradiated film while the impact is manifested to be higher at smaller film sizes. Two representative materials, silicon and fused silica, have been selected as typical substrates for thin films(gold and nickel) of different optical and thermophysical behaviour and the thermal response and damage thresholds are evaluated for the irradiated solids. The pronounced influence of the substrate is aimed to pave the way for new and more optimised designs of laserbased fabrication set ups and processing schemes.展开更多
The aim of this study was to investigate the mechanism of cadmium (Cd) adsorbed by microalgae Chlamydomonas reinhardtii (C.reinhardtii). The kinetic and adsorption isotherm of the process could be well described by ma...The aim of this study was to investigate the mechanism of cadmium (Cd) adsorbed by microalgae Chlamydomonas reinhardtii (C.reinhardtii). The kinetic and adsorption isotherm of the process could be well described by mathematical models. Chemical modification experiments and Fourier transform infrared spectra indicated that carboxyl and amine groups were the important functional groups for adsorption of Cd. The maximum contribution of physical adsorption in the overall adsorption process was evaluated as 5.5%. These results indicated that chemisorption was the dominating mechanism of Cd biosorption by C.reinhardtii.展开更多
A novel miniature Fabry-Perot interferometric(FPI) temperature sensor is proposed and demonstrated experimentally. The modal interferometer is fabricated by just splicing a section of photonic crystal fiber(PCF) with ...A novel miniature Fabry-Perot interferometric(FPI) temperature sensor is proposed and demonstrated experimentally. The modal interferometer is fabricated by just splicing a section of photonic crystal fiber(PCF) with a single-mode fiber(SMF). The air holes of the PCF are fully collapsed by the discharge arc during the splicing procedure to enhance the reflection coefficient of the splicing point. The transmission spectra with different temperatures are measured, and the experimental results show that the linear response of 11.12 pm/°C in the range of 30–80 °C is obtained. This sensor has potential applications in temperature measurement field.展开更多
文摘In present study,we report the preparation of coconut shell activated carbon as adsorbent and its appli-cation for Bi(Ⅲ) removal from aqueous solutions.The developed adsorbent was characterized with scanning elec-tron microscope(SEM),Fourier Transform Infrared(FTIR),C,H,N,S analyzer,and BET surface area analyzer.The parameters examined include agitation time,initial concentration of Bi(Ⅲ),adsorbent dose and temperature.The maximum adsorption of Bi(Ⅲ)(98.72%) was observed at 250 mg·L-1 of Bi(Ⅲ) and adsorbent dose of 0.7 g when agitation was at 160 r·min-1 for 240 min at(299±2) K.The thermodynamic parameters such as Gibb's free energy(△Gθ),enthalpy(△Hθ) and entropy(△Sθ) were evaluated.For the isotherm models applied to adsorption study,the Langmuir isotherm model fits better than the Freundlich isotherm.The maximum adsorption capacity from the Langmuir isotherm was 54.35 mg?g?1 of Bi(Ⅲ).The kinetic study of the adsorption shows that the pseudo second order model is more appropriate than the pseudo first order model.The result shows that,coconut shell ac-tivated carbon is an effective adsorbent to remove Bi(Ⅲ) from aqueous solutions with good adsorption capacity.
基金Supported by Special Program for Scientific Research in Public Service Industry"Studies on Professional Weather Report for Agricultural Production in Northeast China"(GYHY201206024)~~
文摘In order to explore the law of photosynthetic active radiation in winter sunlight greenhouse in Panjin and serve the local facility agriculture better,based on the observed data of sunlight greenhouse microclimate and of the nearby weather station during winter in 2012,the methods of correlation analysis and stepwise regression analysis were adopted to study characteristics of photosynthetic active radiation in sunlight greenhouse and the ratio of photosynthetic active radiation to global radiation under different weather types during winter,and to set up forecast models of photosynthetic active radiation in sunlight greenhouse under different weather types during winter.The results showed that:(1) the daily variation of photosynthetic active radiation in sunlight greenhouse on sunny and cloudy days were both obvious,and photosynthetic active radiation in sunlight greenhouse was 1-38 W/m^2 when it's cloudy.(2) ηPARon typical cloudy day was the highest,on cloudy day was secondary and on sunny day was the minimum during winter;(3) the methods of stepwise regression analysis were respectively adopted to set up models of the highest daily maximum photosynthetic active radiation,the total daily photosynthetic active radiation,daily maximum global radiation,and the total daily global radiation in sunlight greenhouse associated with climate outside,the models passed the 0.01 level of significance,and fitting test had been carried out:4 factors were fitted well on sunny and cloudy day,but fitted poor on overcast day.
基金Projects(862016(Bio Combs4Nanofibres)HELLAS-CH+1 种基金MIS 5002735) funded by the Operational Programme “Competitiveness, Entrepreneurship and Innovation” and co-financed by Greece and the EU (European Regional Development Fund)Project (COST Action TUMIEE) supported by COST-European Cooperation in Science and Technology。
文摘Femtosecond pulsed lasers have been widely used over the past decades due to their capability to fabricate precise patterns at the micro-and nano-lengths scales. A key issue for efficient material processing is the determination of the laser parameters used in the experimental set ups. Despite a systematic investigation that has been performed to highlight the impact of every parameter independently, little attention has been drawn on the role of the substrate material on which the irradiated solid is placed. In this work, the influence of the substrate is emphasised for films of various thicknesses, which demonstrates that both the optical and thermophysical properties of the substrate affect the thermal fingerprint on the irradiated film while the impact is manifested to be higher at smaller film sizes. Two representative materials, silicon and fused silica, have been selected as typical substrates for thin films(gold and nickel) of different optical and thermophysical behaviour and the thermal response and damage thresholds are evaluated for the irradiated solids. The pronounced influence of the substrate is aimed to pave the way for new and more optimised designs of laserbased fabrication set ups and processing schemes.
基金supported by Beijing Elitist Foundation (Grant no. 2005IA05016012) Beijing New Century Talent Foundation (Grant no. 011 005400601)
文摘The aim of this study was to investigate the mechanism of cadmium (Cd) adsorbed by microalgae Chlamydomonas reinhardtii (C.reinhardtii). The kinetic and adsorption isotherm of the process could be well described by mathematical models. Chemical modification experiments and Fourier transform infrared spectra indicated that carboxyl and amine groups were the important functional groups for adsorption of Cd. The maximum contribution of physical adsorption in the overall adsorption process was evaluated as 5.5%. These results indicated that chemisorption was the dominating mechanism of Cd biosorption by C.reinhardtii.
基金supported by the National Natural Science Foundation of China(Nos.61205068 and 61475133)the College Youth Talent Project of Hebei Province(No.BJ2014057)"Xin Rui Gong Cheng"Talent Project and the Excellent Youth Funds for School of Information Science and Engineering in Yanshan University(No.2014201)
文摘A novel miniature Fabry-Perot interferometric(FPI) temperature sensor is proposed and demonstrated experimentally. The modal interferometer is fabricated by just splicing a section of photonic crystal fiber(PCF) with a single-mode fiber(SMF). The air holes of the PCF are fully collapsed by the discharge arc during the splicing procedure to enhance the reflection coefficient of the splicing point. The transmission spectra with different temperatures are measured, and the experimental results show that the linear response of 11.12 pm/°C in the range of 30–80 °C is obtained. This sensor has potential applications in temperature measurement field.