皖北地区五河杂岩温压结构及年代学研究

蚌埠隆起位于华北克拉通南部，胶辽吉造山带的南端，主要由凤阳群和五河杂岩构成。五河杂岩的研究主要集中于年代学以及地球化学领域，其变质P—T条件和地层剖面等研究相对较弱。本文试图从变质岩石学、构造地质学和锆石年代学角度构建朱顶-石门山一线的地壳剖面。通过大量的P-T条件评价，确定了朱顶单元、庄子里单元和石门山单元之间的区别和界限，其中朱顶单元温压结果为低压麻粒岩相：T：720℃-840℃，P=0．90-1．33GPa；庄子里单元温压结果同为低压麻粒岩相，但温度和压力均低于前者：T=700℃-820℃，P=0．50—0．90GPa；石门山单元因岩性限制，仅用白云母Ti温度计拟合计算，结果为低压角闪岩相：T=610℃-700℃，P=0．30—0．50GPa。锆石u—Pb定年获得的变质年龄为2413±22Ma，与前人研究结果基本一致。此外，庄子里地区岩体和磨盘山岩体的锆石u＋Ph年龄晚于2．5—2．4Ga，因此应属于后期侵入岩，计算剖面厚度时要考虑岩体厚度的影响。研究区的岩层产状在45°-60°之间，按照两个极端值计算（不考虑岩体厚度）时获得地壳总厚度为16km，结合3条糜棱岩带的存在，其应属于中．上地壳的物质组成部分。朱顶-石门山-线的地壳剖面，自南向北，以白石山和磨盘山岩体为界，依次为上地壳、中-上地壳和下地壳，温压条件自南向北呈递增趋势。

南大别变质块体温压结构的初步探讨

根据对太湖地区大坝附近榴辉岩的峰期变质P-T条件的研究,以及前人对南大别榴辉岩的P-T条件的分析,同时结合榴辉岩的空间分布状态的研究,文章认为南大别变质块体自北向南可分为金刚石、柯石英榴辉岩、石英/柯石英榴辉岩和石英榴辉岩4个变质单元;变质P-T条件总体上显示逐渐降低的趋势,反映了南大别变质块体俯冲时的连续性,而现今榴辉岩的P-T分布型式则代表南大别多板片的折返状态。

西南天山变质俯冲杂岩带的内部结构——来自木扎尔特剖面的启示

西南天山高压-超高压变质带是世界上少有的经历深俯冲的增生杂岩带,是古天山洋向北俯冲的结果。针对该俯冲杂岩带内部结构的研究目前仍存在争论。本文以木扎尔特地区一条长约4 km的南北向剖面为例,对西南天山高压-超高压变质带的野外特征、矿物学和变质演化研究进行了综述。目前的研究表明,木扎尔特地区存在超高压和高压两类硬柱石榴辉岩,但绝大部分都经历了强烈的退变质和变形改造,被蓝片岩相或绿片岩相矿物组合取代。这些变基性岩在空间上构成北部和南部两个榴辉岩带,二者为构造接触。木扎尔特超高压硬柱石榴辉岩与其围岩经历相似的峰期压力构成西南天山超高压带的西端。与东侧阿克牙孜地区超高压榴辉岩相比,它们在变形特征、岩石组合和变质演化方面表现出一定的独特性,很可能说明深俯冲板片在折返过程中沿构造带走向存在差异变质-变形演化。这些基础研究对全面认识冷俯冲增生杂岩带的变质演化及其俯冲和折返的地球动力学机制具有重要意义。

A Warming Structure for Piezoelectric Stack Working in Cryogenic Temperature

It is widely acknowledged that the performance of a piezoelectric stack would decline with the temperature decreasing,which will exert negative influence on its application in low-temperature environment.Therefore,a convenient and efficient warming structure for the piezoelectric stack is proposed in this paper to solve this problem.Based on the theoretical analysis of heat transfer,two heating modes,namely,overall heating and local heating are analyzed and compared.Moreover,experimental tests are conducted to evaluate the effectiveness of the structure.Based on the results,it can be concluded that the theoretical results are confirmed with experimental results.Besides,the temperature and performance of the piezoelectric stack are kept stable as temperature varies from 10℃to-70℃,which manifests the feasibility of the structure.Therefore,this paper could be an available reference for those engaged in cryogenic investigation of smart materials and structures.

Thermal Structure of Glass Fiber Reinforce Plastic Support Structure

The assembled form of thick-wall glass fiber reinforced plastics (GFRP) tube and 0Cr18Ni9 austenitic stainless steel pipes was designed as the radius thermal-insulating and load-supporting structure in cryogenic vessels. In order to study the thermal leakage and gap changes on the support structure, as well as radius temperature and stress distribution on GFRP tube, an experimental investigation has been taken. The results indicate that the support structure is proved to fit well as thermal-insulating and load-supporting part in cryo-genic vessels, furthermore has high security during cryogenic applications.

Molecular Dynamics Simulations of Liquid Phosphorus at High Temperature and Pressure

By performing ab initio molecular dynamics simulations, we have investigated the microstructure, dynamical and electronic properties of liquid phosphorus （P） under high temperature and pressure. In our simulations, the calculated coordination number （CN） changes discontinuously with density, and seems to increase rapidly after liquid P is compressed to 2.5 g/cm3. Under compression, liquid P shows the first-order liquid-liquid phase transition from the molecular liquid composed of the tetrahedral P4 molecules to complex polymeric form with three-dimensional network structure, accompanied by the nonmetal to metal transition of the electronic structure. The order parameters Q6 and Q4 are sensitive to the microstructural change of liquid P. By calculating diffusion coefficients, we show the dynamical anomaly of liquid P by compression. At lower temperatures, a maximum exists at the diffusion coefficients as a function of density; at higher temperatures, the anomalous behavior is weakened. The excess entropy shows the same phenomena as the diffusion coefficients. By analysis of the angle distribution functions and angular limited triplet correlation functions, we can clearly find that the Peierls distortion in polymeric form of liquid P is reduced by further compression.

Subtransus deformation mechanisms of TC11 titanium alloy with lamellar structure

Isothermal compression tests are applied to study the deformation mechanisms of TCll titanium alloy with lamellar structure under the deformation temperature range of 890-995 ℃ and strain rate range of 0.01-10 s^-1. According to the flow stress data obtained by compression tests, the deformation activations are calculated based on kinetics analysis of high temperature deformation, which are then used for deformation mechanism analysis combined with microstructure investigation. The results show that deformation mechanisms vary with deformation conditions： at low strain rate range, the deformation mechanism is mainly dislocation slip; at low temperature and high strain rate range, twinning is the main mechanism; at high temperature and high strain rate range, the deformation is mainly controlled by diffusion offl phase.

Behavior of concrete and concrete-filled circular steel tubular stub columns at constant high temperatures

Based on reanalyzing test results of uniaxial compressive behavior of concrete at constant high temperatures in China, with the compressive cube strength of concrete from 20 to 80 MPa, unified formulas for uniaxial compressive strength, elastic modulus, strain at peak uniaxial compression and mathematical expression for unaxial compressive stress-strain relations for the concrete at constant high temperatures were studied. Furthermore, the axial stress-axial strain relations between laterally confined concrete under axial compression and multiaxial stress-strain relations for steel at constant high temperatures were studied. Finally, based on continuum mechanics, the mechanics model for concentric cylinders of circular steel tube with concrete core of entire section loaded at constant high temperatures was established. Applying elasto-plastic analysis method, a FORTRAN program was developed, and the concrete-filled circular steel tubular （CFST） stub colunms at constant high temperatures were analyzed. The analysis results are in agreement with the experiment ones from references.

Ab initio Predictions of Structural and Thermodynamic Properties of Zr2AIC Under High Pressure and High Temperature

The structural and thermodynamic properties of Zr2A1C at high pressure and high temper- ature are investigated by first principles density functional theory method. The calculated lattice parameters of Zr2A1C are in good agreement with the available theoretical data. The pressure dependences of the elastic constants, bulk modulus, shear modulus, Young＇s mod- ulus, and Vickers hardness of Zr2A1C are successfully obtained. The elastic anisotropy is examined through the computation of the direction dependence of Young＇s modulus. By using the quasiharmonic Debye model, the thermodynamic properties including the Debye temperature, heat capacity, volume thermal expansion coefficient, and Griineisen parameter at high pressure and temperature are predicted for the first time.

Studying on the increasing temperature in IT-SOFC:Effect of heat sources

The dimensions and the materials type limit the performance of fuel cell. The increase of the temperature in electrodes and electrolyte of the cell,is due to the over potential of activation (transfer of load),the over potential Ohmic (resistance of polarization),the over potential of reaction (heat released by the chemical reaction) and the over potential of diffusion. In this paper,we studied the thermo-electrical performance of an intermediate temperature solid oxide fuel cell (IT-SOFC) with electrode supported. The aim of this work is to study this increasing temperature of a single cell of an IT-SOFC under the influence of the following parameters: heat sources,functioning temperature and voltages of the cell,geometric configuration and materials type. The equation of energy in one dimension is numerically resolved by using the method of finite volumes. A computing program (FORTRAN) is developed locally for this purpose in order to obtain fields of temperature in every element of the cell.

Design and Analysis of a Thermally Insulating and Heating Scheme for Piezoelectric Stack Actuators Used in the Cryogenic Environment

In cryogenic wind tunnel tests,piezoelectric stacks are adopted to realize the vibration control of the cantilever sting.However,the free stroke and blocking force of the piezoelectric stack would decrease dramatically as the temperature decreases.This paper proposes a convenient and effective warming structure for the piezoelectric stack,which could keep it working at operating temperatures when the ambient temperature drops.The piezoelectric stack actuator is wrapped with the heating film,and this resulting assembly is then wrapped with the aerogel material for thermal insulation.Both ends of the piezoelectric stack actuator make direct contact with the payload structure.Both one-dimensional and two-dimensional theoretical analyses of the heating conduction problem of the piezoelectric stack actuator are conducted.These analyses results are compared with those of the finite element simulation analysis.The finite element method results show a good consistency with the two-dimensional theoretical results,and a slight deviation of only 0.91 K is observed,indicating its potential for protecting piezoelectric stacks at low temperatures.

Effects of strain rate and temperature on microstructure and texture for AZ31 during uniaxial compression

In order to investigate the effects of strain rate and temperature on the microstructure and texture evolution during warm deformation of wrought Mg alloy,AZ31 extruded rods were cut into cylinder samples with the dimension of d8 mm×12 mm.The samples were compressed using a Gleeble 1500D thermo-mechanical simulation machine at various strain rates(0.001,0.01,0.1,1 and 5 s- 1)and various temperatures(300,350,400 and 450℃).The microstructure and texture of the compressed samples at the same strain under different deformation conditions were studied and compared by electron backscatter diffraction(EBSD)in scanning electron microscope(SEM).The results show that the size of recrystallized grains in the deformed samples generally increases with the decrease of strain rate and the increase of temperature.After 50%reduction,most basal planes are aligned perpendicular to the compression direction at relatively high strain rate(>0.01 s- 1)or low temperature(<350℃).The optimized strain rate is 0.1 s- 1for uniaxial compression at 300℃,which produces about 80%of small grains(<5μm).

An Overview of the Advanced Nonintrusive Measurement Techniques in Hypersonic Flow Field

Hypersonic flow-field measurement techniques have been studied for about 50 years. Despite truly remarkable progress with a probe or other device to measure the temperature, pressure or velocity, there are still serious problems for these "intrusive" techniques. The intrusive measurement techniques introduce unexpected shock waves or flow-field structures, even make the boundary layer transition earlier and show a converse result. In recent years, nonintrusive diagnostics have been in urgent demand to give a more accurate and comprehensive flow-field for hypersonic testing. In this paper, an overview of some advanced nonintrusive measurement techniques such as embedded thermocouples for heat flux measurement, Pressure Sensitive Paint(PSP), Particle Image Velocimetry(PIV), infrared thermographs, and focusing Schlieren system are introduced. All of these techniques are nonintrusive and provide measurement of various parameters such as temperature, static pressure, dynamic pressure, flow velocity and visualization of flow structure, which gives us an exact and direct understanding of the hypersonic flow.

Influence of extrusion ratio on microstructure and texture developments of high-temperature extruded AZ31 Mg alloy

Experiments were conducted to evaluate the effects of extrusion ratio on the microstructure and texture developments of AZ31 Mg alloy during forward extrusion. The forward extrusion was undertaken at 400℃ with extrusion ratios of 10, 18, and 25 after the alloy was homogenized at 410℃ for 12 h. Partially recrystallized microstructures were observed in all the extruded rods examined. The texture of the large elongated deformed grains appeared strongly centered at （1010） dominating the extrusion texture, while the recrystallized grains exhibited much more randomized texture. For the alloy with the largest ER （25）, coarse secondary recrystallized grains were found which presented a different texture component with （11 2 0） parallel to the ED. The occurrence of the coarse secondary recrystallized grains in the alloy with the largest ER might be attributed to that the large ER raised the die exit temperature during extrusion and thus promoted significantly grain growth after the extruded rod exited from extrusion die. The intensities of different texture components varied with ER because ER affected the contents of the deformed grains, DRX grains and coarse secondary recrystallized grains. In particular, the maximum intensity of fiber texture was decreased as ER increased due to the decrease of the large elongated deformed grains.

Large thermal biasing of individual gated nanostructures

We demonstrate very large and uniform temperature gradients up to about 1 K every 100 nm, in an architecture which is compatible with the field-effect control of the nanostructure under test. The temperature gradients demonstrated greatly exceed those typically obtainable with standard resistive heaters fabricated on top of the oxide layer. The nanoheating platform is demonstrated in the specific case of a short-nanowire device.

Small onion-like BN leads to ultrafine-twinned cubic BN

Nanotwinned cubic boron nitride(nt-cBN) with remarkable hardness, toughness, and stability has attracted widespread attention due to its distinct scientific and industrial importance. The key for nt-cBN synthesis is to adopt an onion-like BN(oBN) nano-precursor and induce phase transition under high pressure. Here, we found that the size change of oBN used greatly affected the mechanical performance of products. With the precursor size decreasing from^320 to 90 nm, the Vickers hardness of nanostructured products improved from 61 to 108 GPa, due to the fact that large oBN nanoparticles possessed more flattened, orderly and graphite-like shell layers, in sharp contrast to the highly wrinkled and imperfect layers in small-diameter nanoparticles, thus resulting in the apparent reduction of ultrafinetwin substructure in the synthetic products. This study reveals that only small oBN precursor could produce complete ultrafine nt-cBN with outstanding performance. A practical route was proposed to further improve the performance of this important material.

Structural and electrical properties of high Curie temperature Aurivillius phase composite ceramics with largely enhanced piezoelectricity

High performance piezoelectric ceramics with high Curie temperatures(TC) are the bottle necks of relevant high temperature devices. In this study, the electrical performance and microstructure of Li and Mn codoped Aurivillius-type composite ceramics with a composition Ca_(0.99-x_Bi_(6.99+x)(Li Mn)_(0.01) Nb Ti_5O_(24)(x = 0–0.8) were systematically investigated. The results indicated that uniform intergrowth structure with a lattice similar to that of the end member CBT could be formed at a low x value(x < 0.4). Phase separation occurred when more A-site Ca^(2+) ions were replaced by Bi^(3+) ions. Nevertheless, all composite samples showed d_(33) values about 2 to 3 times of that of the constituent phase Ca Bi_4Ti_4O_(15) and Bi_3 Ti NbO_9 with still a high depolarization temperature. The performance of the samples was found to be related to the density and larger lattice distortion along the polarization a axis. The results also demonstrated that formation of the compound system was an effective way in improving the performance of Aurivillius-type high TC piezoelectric ceramics.