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国际温室气体(碳)排放权市场的发展及其启示 被引量:39
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作者 涂毅 《江西财经大学学报》 CSSCI 2008年第2期15-19,共5页
在减缓气候变化、改善环境的全球共识下,世界各国都面临着相当大的压力,而这恰为国际温室气体(碳)排放权市场的发展提供了一个难得的机会。我国应该学习和借鉴当前国际主要温室气体(碳)排放权市场(主要指欧盟碳交易市场和芝加哥气候交易... 在减缓气候变化、改善环境的全球共识下,世界各国都面临着相当大的压力,而这恰为国际温室气体(碳)排放权市场的发展提供了一个难得的机会。我国应该学习和借鉴当前国际主要温室气体(碳)排放权市场(主要指欧盟碳交易市场和芝加哥气候交易所)的运作模式和先进经验,通过建设适应我国国情的温室气体(碳)排放权交易市场,以推动我国应对气候变化工作和节能减排事业的顺利发展,实现经济的又好又快发展。 展开更多
关键词 温室气体() 排放权市场 排放权交易 清洁发展机制(CDM) 《京都议定书》
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Positioning of Developing Low-carbon Agriculture in Local Governments
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作者 万玉山 李娜 +2 位作者 张平 李定龙 王明新 《Agricultural Science & Technology》 CAS 2012年第2期468-472,共5页
[Objective] To analyze the positioning of low-carbon agriculture development in local governments of China. [Method] The emissions of green-house gas, the connotation and characteristics of low-carbon agriculture, and... [Objective] To analyze the positioning of low-carbon agriculture development in local governments of China. [Method] The emissions of green-house gas, the connotation and characteristics of low-carbon agriculture, and the necessity of developing low-carbon agriculture were analyzed, obtaining the positioning and measures for the development of low-carbon agriculture in local government. [Result] Government plays a leading role in the development of low-carbon agriculture. The development of low-carbon agriculture can be promoted through the formulation of scientific low-carbon agricultural development plan, culturing new talents on low-carbon agriculture, promoting low-carbon agricultural technology, establishing low-carbon agricultural risk prevention mechanisms. [Conclusion] Making economy, environment and resources coordinated with each other, leading by the concept of scientific development with the concept of sustainable development, is where the future of agricultural development in China lies. 展开更多
关键词 GOVERNMENT Low-carbon agriculture Low-carbon technology Greenhouse gas
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Value Estimation of Greenhouse Gases Exchange in Wetland Ecosystem of Sanjiang Plain,China 被引量:5
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作者 LIU Xiaohui LU Xianguo +1 位作者 JIANG Ming WANG Xigang 《Chinese Geographical Science》 SCIE CSCD 2009年第1期55-61,共7页
The objective of this study is to quantify the values of greenhouse gases(GHGs) exchange in carbon equivalents of marshes and paddy fields in the Sanjiang Plain,Heilongjiang Province,China. We obtained the GHGs exchan... The objective of this study is to quantify the values of greenhouse gases(GHGs) exchange in carbon equivalents of marshes and paddy fields in the Sanjiang Plain,Heilongjiang Province,China. We obtained the GHGs exchange values based on comparable price by calculating the carbon sequestration values and the GHGs emission values of marshes and paddy fields respectively in four periods of 1982,1995,2000 and 2005. It is noted that the GHGs emission values are always negative. In this study,the marshes areas decreased from 1438977.0 to 775,132.2ha and the paddy fields areas increased from 417195.8 to 934205.0ha. The values of GHGs exchange of marshes varied from 135877.156×106 to 136882.534×106 yuan(RMB) and those of paddy fields varied from 1006.256×106 to 2767.645×106 yuan. The GHGs exchange values of marshes decreased from 1982 to 2005 on the whole,reversely,those of paddy fields increased,but those in 2005 were lower than those in 2000. In different periods,the GHGs exchange values were always higher in marshes than in paddy fields. The contribution rate of GHGs exchange values per unit area of marshes was also very high in different periods,and the maximum was up to 98.35% in 2005. As far as the whole wetland ecosystem(including marshes and paddy fields) ,assuming a linear change in GHGs exchange values,it represented a cumulative increase of 20926.757×106 yuan from 1982 to 2005. By adding GHGs exchange values increased during those four periods,we obtained a cumulative net increase values of GHGs exchange of wetland ecosystem of 18200.860×106 yuan. The results will be useful for understanding the indirect services provided by marshes and paddy fields. 展开更多
关键词 carbon equivalents GHGs exchange values contribution rate cumulative value Sanjiang Plain
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Effect of Combined Application of Organic and Inorganic Fertilizers on Methane Emission from Paddy Soil and Rice Growth 被引量:1
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作者 LIUKEXING LIAOZHONGWEN 《Pedosphere》 SCIE CAS CSCD 1997年第4期379-382,共4页
关键词 fertilizer effect methane emission organic-inorganic fertilizer RICE
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Adsorption and desorption on coals for CO_2 sequestration 被引量:3
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作者 WANG Zuo-tang FU Zhen-kun +3 位作者 ZHANG Bang-an WANG Guo-xiong RUDOLPH Victor HUO Li-wen 《Mining Science and Technology》 EI CAS 2009年第1期8-13,共6页
Adsorption and desorption of carbon dioxide, methane and other gases on coals has been investigated experimentally using representative Zhongliangshan coals. Gas adsorption is one of the major concerns for both CO2 se... Adsorption and desorption of carbon dioxide, methane and other gases on coals has been investigated experimentally using representative Zhongliangshan coals. Gas adsorption is one of the major concerns for both CO2 sequestration and methane recovery processes. The experiments were carried out using both single and multi-component mixtures at 25 ℃ and 30 ℃ with the highest pressure of 12 MPa. The coal was under moisture equilibrated conditions. This provides experimental data from which a predictive assessment of CO2 sequestration and/or methane recovery can be conducted. The results show that for pure gasses the CH4 adsorption capacity is higher than the N2 adsorption capacity but lower than the CO2 adsorption capacity. Injection of CO2 or other gases into the coal significantly affects CH4 desorption. This allows the enhancement of CH4 recovery from the coals, thus supplying more clean energy while sequestering significant amounts of CO2 thereby reducing the greenhouse effect from human beings. 展开更多
关键词 MULTI-COMPONENT CO2 sequestration greenhouse gas
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Effects of Organic Manure Applications on Methane and Nitrous Oxide Emissions in Paddy Fields 被引量:2
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作者 WU Jia-mei JI Xiong-hui +5 位作者 PENG Hua XIE Yun-he GUAN Di TIANFa-xiang ZHU Jian HUO Lian-jie 《Agricultural Science & Technology》 CAS 2018年第2期36-48,共13页
This study was carried out in paddy fields to explore how organic manure applications would affect greenhouse emissions in South China. The results showed that the seasonal emission of CH4 under the chemical fertiliz... This study was carried out in paddy fields to explore how organic manure applications would affect greenhouse emissions in South China. The results showed that the seasonal emission of CH4 under the chemical fertilizer (CF) treatment was 271.47 kg/hm^2. In comparison, the seasonal emissions of CH4 under the treatment of pig manure (PM), chicken manure (CM) and rice straw (RS) increased by 50.61,260.22 and 602.82 kg/hm^2, respectively. N2O emission under the CF treatment was 1.22 kg/hm^2, while the N20 seasonal emissions under tile PM, CM and RS treatment decreased by 23.6% (P〈0.05), 31.7% (P〈0.05) and 30.9% (P〈0.05), respectively. Meanwhile, the readily oxidized organic carbon (which was oxidized by 167 mmol/L potassium permanganate, ROC167) of manure, paddy soil Eh value and temperature could also affect the CH4 emissions. The average yield of the organic fertilizer treatments increased by 6.8% compared with that of the CF treatment. Among all the organic fertilizer treatments, the PM treatment offered the lowest global warming potential and greenhouse gas intensity, in which the PM was of no significant difference from NF (no fertilizing) and CF. Therefore, the pig manure is capable of coordinating the relationship between environment and yield, and it also has a low ROC167 content, so the PM is considered worthy of recommendation. 展开更多
关键词 Paddy field Methane emission Nitrous emission Soil Eh value Readily oxidized organic carbon Greenhouse gas intensity
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Discussion on the Construction of low-carbon electricity technology innovation system
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作者 Ge Pan 《International Journal of Technology Management》 2014年第1期29-31,共3页
With the issue of climate change increasingly restricting the sustainable development of society, people must realize that we must control atmospheric concentrations of greenhouse gases at a certain level. However, th... With the issue of climate change increasingly restricting the sustainable development of society, people must realize that we must control atmospheric concentrations of greenhouse gases at a certain level. However, the traditional model of economic development will lead to human demand for energy continuing to grow, followed by a growth in emissions of carbon dioxide. Obviously we must ensure that there is rapid economic development, but also to protect the human living environment, which is a very sharp contradiction. A good solution to this conflict is to take a new model of development --- a low-carbon economy. The so-called low-carbon economy refers to the reduction of greenhouse gas emissions, the application of new technologies, new materials and new practices, etc., through improvements, optimization or innovative production and business activities, to achieve the maximum degree of reduction of greenhouse gas emissions, and the formation of a new economic development model, the goal is to mitigate climate change and promote sustainable human development. On how to develop a low-carbon economy, domestic and foreign scholars have been studied from many angles, one of which is a consensus to reduce greenhouse gas emissions through the development and use of low-carbon technologies. 展开更多
关键词 CARBON ELECTRICITY technological innovation
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Carbon Footprint Analysis for Baby Strollers
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作者 Yu Ang Luo Yifan 《Chinese Journal of Population,Resources and Environment》 2012年第4期16-21,共6页
The increasing awareness of climate change has led organizations to demand a standard procedure to measure and communicate greenhouse gas(GHG) emissions linked to their products or services.The publicly available spec... The increasing awareness of climate change has led organizations to demand a standard procedure to measure and communicate greenhouse gas(GHG) emissions linked to their products or services.The publicly available specification PAS 2050 has been developed in response to broad community and industry desire for a consistent method-carbon footprint for assessing the life cycle GHG emissions of goods and services.Specifically,this paper illustrates the implementation of carbon footprint for a baby stroller in accordance with PAS 2050.A fial value of 321 kg per one stroller including package was calculated.Moreover,the study led to identify raw materials production of the stroller as the main source of GHS emissions where efforts need to focus for emission reduction opportunities.This case study is hoped to be a starting point for organizations to benefit from the increasing application of carbon footprint assessment. 展开更多
关键词 baby stroller carbon footprint greenhouse gas emis- sions life cycle PAS 2050
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Carbon Footprint in Meat Production and Supply Chains 被引量:1
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作者 Roberto Schroeder Luís Kluwe Aguiar Richard Baines 《Journal of Food Science and Engineering》 2012年第11期652-665,共14页
All human activities, including food production, are potentially sources of greenhouse gases (GHG) emissions. In order to provide a better understanding of how to mitigate the GHG emissions, an inventory based on di... All human activities, including food production, are potentially sources of greenhouse gases (GHG) emissions. In order to provide a better understanding of how to mitigate the GHG emissions, an inventory based on different beef supply chains in the United Kingdom and in Brazil was carried out. The carbon footprint of the beef systems was calculated based on the life cycle assessment methodology. Total emissions per kg of bone-free meat were calculated at being 33.85, 33.99 and 45.17 kg of CO2e-100/kg for UK1, UK2 and Brazil farm units, respectively. Based on an average potential for carbon sequestration rate at the proportion of 12:44 for C:CO2 conversion for well managed grasslands, there is a potential sequestration of 1,980 kg of CO2/ha/year. This would potentially reduce the total emissions value for the three distinct supply chains the cases ofUKb UK2 and Brazil, respectively. as being 29.4, 28.4 and 25.4 kg C02-e 100/kg of bone-free meat for 展开更多
关键词 Life cycle assessment GHG emissions carbon footprint supply chains beef.
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A Novel Approach to Ethanol Fuel Production using Rotary Collection of Forest Debris
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作者 Marian Nicte Zappala Rajab Abujnah +1 位作者 Cesar Luna Russell Robert Chianelli 《Journal of Environmental Science and Engineering(B)》 2013年第10期614-620,共7页
In this article, the authors propose the production of ethanol from cellulose as an alternative to oil. Cellulosic-ethanol will reduce greenhouse gas emissions, and provide a means to prevent forest fires. This liquid... In this article, the authors propose the production of ethanol from cellulose as an alternative to oil. Cellulosic-ethanol will reduce greenhouse gas emissions, and provide a means to prevent forest fires. This liquid dense fuel was selected because it: (1) easily transported and dispensed as a fuel; (2) can be handled by the existing fuel distribution infrastructure; and (3) unlike its commercial competitor, Me-OH (Methanol), Et-OH (Ethanol), is edible, thus being biodegradable and nontoxic. Forest residue ethanol is cheaper to produce and more environmentally friendly than other forms of ethanol fuel. Furthermore, forests would have less available ground fuel for fires. The potential decline of forest fires would then reduce the carbon footprint attributed directly to forest fires. In combination with ethanol fuel combustion, carbon emissions can be reduced by more than 70% compared to gasoline combustion. We used GREET (Greenhouse gases, Regulated Emissions, and Energy use in Transportation) software to assess the life cycles of different fuel pathways. In conclusion, cellulosic ethanol fuel is clearly an answer to decrease dependency on current oil imports and prevent forest fires. 展开更多
关键词 Cellulosic ethanol FUEL forest residue forest fires GREET software.
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Tire Manufacturer Fighting Climate Changes
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作者 A. Grec 《Journal of Environmental Science and Engineering》 2010年第7期24-29,共6页
This paper presents methods and strategy promoted by an operator of tire rubber manufacturer in order to reduce CO2 emissions. This paper presents calculation methods of GHG emissions and data on production activities... This paper presents methods and strategy promoted by an operator of tire rubber manufacturer in order to reduce CO2 emissions. This paper presents calculation methods of GHG emissions and data on production activities, as well as fuel consumption, energy, etc. This example shows that environmental investments are effective primarily in the environmental aspect, but they can become profitable (the carbon trading market of GHG allowances and by providing alternative energy in national energy system, resulting in "green certificates"). 展开更多
关键词 Greenhouse gas-(GHG) European emissions trading scheme -(EU ETS) alternative energy carbon intensity
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Carbon Budget Proposal:An Institutional Framework for an Equitable and Sustainable World Climate Regime
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作者 Pan Jiahua Chen Ying 《Chinese Journal of Population,Resources and Environment》 2011年第3期3-20,共18页
Consensus on reducing greenhouse gas emissions has been reached at the technical and political level.However,as the issue involves economic costs and the right to develop,the international institutional framework for ... Consensus on reducing greenhouse gas emissions has been reached at the technical and political level.However,as the issue involves economic costs and the right to develop,the international institutional framework for addressing greenhouse gas emissions has consistently failed to balance the demands of impartiality and sustainability.However,a sustainable carbon budget proposal is undoubtedly achievable if the global carbon budget (the total amount of carbon permitted by climate security) is made an absolute constraint.If a preliminary distribution was made among the world's population on a per capita basis,the total limited global carbon budget could not only meet basic needs but also ensure the proposal's equitable.Taking into account historical emission levels and future needs,we should carry out carbon budget transfer payments and devise a corresponding funding mechanism to ensure efficient allocation under the proposal.Unlike the phase-by-phase progress and provisional goals of the Kyoto Protocol,the carbon budget proposal outlined above is a comprehensive and holistic package.Due to the politicization of the climate change issue,however,many technical issues can only be worked out through international political and diplomatic negotiations. 展开更多
关键词 carbon budget EQUITY sustainability international climate regime
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Brief Talk on China's Carbon Tax System-Based on Lowcarbon Thermal Power Project
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作者 Ling-wen-ying LI 《International Journal of Technology Management》 2015年第5期109-110,共2页
China has surpassed America and became the biggest greenhouse gases emission country in the world in 2008.1t is an urgent need for China to actively respond to climate change and promote energy conservation.This paper... China has surpassed America and became the biggest greenhouse gases emission country in the world in 2008.1t is an urgent need for China to actively respond to climate change and promote energy conservation.This paper bases on the above facts, studies the carbon tax, which is an effective policy, designs an carbon tax system for China and analyzes the advantages of carbon tax, thus providing some reference for promoting the development of low-carbon thermal power project. 展开更多
关键词 Carbon tax Carbon emissions Energy conservation
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Study on carbon emission in prefecture-level cities of china
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作者 Feng Ying Cai Bofeng 《High Technology Letters》 EI CAS 2012年第1期101-106,共6页
The study on greenhouse gas inventory in urban China lags far behind the global level. The important factor that curbs the carbon inventory of cities of China is inventory methodology and scope. Given the insufficienc... The study on greenhouse gas inventory in urban China lags far behind the global level. The important factor that curbs the carbon inventory of cities of China is inventory methodology and scope. Given the insufficiency of Chinese cities carbon inventory, a system and accounting model (scopel+ scope2) as well as principles and boundaries were proposed for China. The carbon emissions in scopel and scopel+ scope2 were calculated in Chinese prefecture-level cities. The EDGAR dataset was used for the calculation of scopel carbon emissions in cities in China and the level of uncertainty was analyzed as well. The results showed that the direct carbon emission of cities in China was about 31.65% of China total emissions. The scopel+ scope2 carbon emissions in cities of China were calculated based on the GIS and RS model. The results showed that the sum of direct (scopel) and indirect (scope2) carbon emissions of cities in China accounted for 38.80% of total China carbon emissions. 展开更多
关键词 CITIES carbon emission inventory SCOPE
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Global Research Trends Related to CO_2 Emissions and Their Enlightenment to China
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作者 Liu Hongguang Liu Weidong +1 位作者 Fan Xiaomei Tang Zhipeng 《Chinese Journal of Population,Resources and Environment》 2012年第1期3-12,共10页
Given the growing awareness of the likely catastrophic impacts of climate change and close association of climate change with global emissions of greenhouse gases (of which carbon dioxide is more prominent) , consid... Given the growing awareness of the likely catastrophic impacts of climate change and close association of climate change with global emissions of greenhouse gases (of which carbon dioxide is more prominent) , considerable research efforts have been devoted to the analysis of carbon dioxide (CO2) emissions and its relationship to sustainable development. Now GHG reduction programs have been coming into effect in many developed coun- tries that have more responsibility for historical CO2 emissions, and the studies have become mature. First, the GHG emissions accounting system is more all-inclusive and the methods are more rational with the effort of IPCC from 1995 and all other research- ers related. Second, the responsibility allocation is more rational and fair. Along with the clarity of "carbon transfer" and "carbon leakage", the perspective and methodology for allocating regional COz emissions responsibility is turning from production base to consumption base. Third, the decomposition method has become more mature and more complex. For example, the decomposition formulas are including KAYA expression and input-output expres- sion and the decomposition techniques are developed from index analysis to simple average divisia and then adaptive-weighting divisia. Fourth, projection models have become more integrated and long-term. The top-down model and bottom-up model are both inter-embedded and synergetic. Trends above give some advice for the research on CO2 in China, such as emissions factors database construction, deeper-going research on emissions responsibility and structure analysis, promotion of modeling technology and technology-environment database. 展开更多
关键词 CO2 emissions research trends ENLIGHTENMENT
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Influence of Soil Organic Carbon on Greenhouse Gas Emission Potential After Application of Biogas Residues or Cattle Slurry:Results from a Pot Experiment 被引量:2
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作者 gawan heintze tim eickenscheidt +1 位作者 urs schmidhalter matthias drsler 《Pedosphere》 SCIE CAS CSCD 2017年第5期807-821,共15页
A change in the European Union energy policy has markedly promoted the expansion of biogas production. Consequently, large amounts of nutrient-rich residues are being used as organic fertilizers. In this study, a pot ... A change in the European Union energy policy has markedly promoted the expansion of biogas production. Consequently, large amounts of nutrient-rich residues are being used as organic fertilizers. In this study, a pot experiment was conducted to simulate the high-risk situation of enhanced greenhouse gas (GHG) emissions following organic fertilizer application in energy maize cultivation. We hypothesized that cattle slurry application enhanced CO2 and N20 fluxes compared to biogas digestate because of the overall higher carbon (C) and nitrogen (N) input, and that higher levels of CO2 and N20 emissions could be expected by increasing soil organic C (SOC) and N contents. Biogas digestate and cattle slurry, at a rate of 150 kg NH+-N ha-1, were incorporated into 3 soil types with low, medium, and high SOC contents (Cambisol, Mollic Gleysol, and Sapric Histosol, termed Clow, Cmedium, and Chigh, respectively). The GHG exchange (CO2, CH4, and N20) was measured on 5 replicates over a period of 22 d using the closed chamber technique. The application of cattle slurry resulted in significantly higher CO2 and N20 fluxes compared to the application of biogas digestate. No differences were observed in CH4 exchange, which was close to zero for all treatments. Significantly higher CO2 emissions were observed in Chigh compared to the other two soil types, whereas the highest N20 emissions were observed in Cmedium. Thus, the results demonstrate the importance of soil type-adapted fertilization with respect to changing soil physical and environmental conditions. 展开更多
关键词 C mineralization energy maize mineral soil N mineralization organic fertilization PEATLAND
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Carbon budget proposal: a framework for an equitable and sustainable international climate regime 被引量:4
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作者 Pan Jiahua Chen Ying 《Social Sciences in China》 2010年第1期5-34,共30页
A worldwide consensus on reducing greenhouse gas emissions has been reached at the technical and political level. However, as the issue involves economic costs and developmental interests, the international institutio... A worldwide consensus on reducing greenhouse gas emissions has been reached at the technical and political level. However, as the issue involves economic costs and developmental interests, the international institutional framework for addressing global greenhouse gas emissions has consistently failed to balance the demands of equity and sustainability. But the sustainability of carbon budget proposal is undoubtedly achievable if the total global carbon budget (the total amount of carbon permitted by climate security) is made an absolute constraint. If an initial allocation is made among all members of the global village on a per capita basis, a limited total budget could not only meet basic needs but also ensure equity. Taking into account historical emission levels and future needs, we should implement carbon budget transfer payments and devise a corresponding financial mechanism to ensure efficient allocation. Unlike the phase-by-phase progress and provisional goals of the Kyoto Protocol, the carbon budget proposal presented here is a comprehensive and holistic package. Due to the politicization of the climate change question, however, many technical issues can only be worked out through international political and diplomatic negotiations. 展开更多
关键词 Carbon budget proposal EQUITY SUSTAINABILITY international climate regime
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Cross-shelf carbon transport under different greenhouse gas emission scenarios in the East China Sea during winter 被引量:3
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作者 Dongliang YUAN Jiajia HAO +1 位作者 Jianle LI Lei HE 《Science China Earth Sciences》 SCIE EI CAS CSCD 2018年第6期659-667,共9页
Based on Marx-Planck coupled model simulations and in situ hydrography measurements, the volume transport of ocean currents and associated carbon fluxes across the continental margin from the continental shelf to the ... Based on Marx-Planck coupled model simulations and in situ hydrography measurements, the volume transport of ocean currents and associated carbon fluxes across the continental margin from the continental shelf to the deep ocean in the East China Sea during winter are estimated. Because cross-shelf currents in the Yellow and East China seas are much stronger in winter than in other seasons and are subducted into the subsurface Kuroshio, the cross-shelf burial of carbon takes place mainly in winter. The analyses show prominent cross-shelf transports during winter in the Yellow and East China seas, with annual mean offshore transport across a section from Taiwan to Cheju at 3.92 Sv(1 Sv=10~6 m^3 s^(-1)). Net transport across the section was0.82 Sv off the shelf, determined by the difference between Taiwan and Cheju strait transports. Net cross-shelf transports of dissolving inorganic carbon(DIC), dissolved organic carbon(DOC), and particulate organic carbon(POC) in winter were 98, 12,and 0.1 million tons, respectively. Under global greenhouse gas emission reduction(RCP4.5) and continuous increase(RCP8.5)scenarios, this cross-shelf transport has an increasing trend. The transports across the Taiwan-Cheju section in winter are predicted to increase by 0.54 and 0.65 Sv from 2006 to 2099, with rates of increase 15.3% and 19.6%, respectively. Associated with the transport increase, the cross-shelf fluxes of DIC, DOC and POC increase by as much as 15.4–25.2%. Cross-shelf carbon fluxes in the East China Sea during winter are evaluated for the first time under the global warming scenarios, showing the importance of cross-shelf transport in the carbon cycle of the China marginal seas. 展开更多
关键词 Cross-shelf transport Carbon fluxes Global warming RCP8.5 RCP4.5
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A DFT study of CO_2 electrochemical reduction on Pb(211) and Sn(112)
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作者 Chaonan Cui Hua Wang +2 位作者 Xinli Zhu Jinyu Han Qingfeng Ge 《Science China Chemistry》 SCIE EI CAS CSCD 2015年第4期607-613,共7页
Electrochemical reduction of CO2 has the benefit of turning greenhouse gas emissions into useful resources. We performed a comparative study of the electrochemical reduction of CO2 on stepped Pb(211) and Sn(112) surfa... Electrochemical reduction of CO2 has the benefit of turning greenhouse gas emissions into useful resources. We performed a comparative study of the electrochemical reduction of CO2 on stepped Pb(211) and Sn(112) surfaces based on the results of density functional theory slab calculations. We mapped out the potential energy profiles for electrochemical reduction of CO2 to formate and other possible products on both surfaces. Our results show that the first step is the formation of the adsorbed formate(HCOO*) species through an Eley-Rideal mechanism. The formate species can be reduced to HCOO- through a oneelectron reduction in basic solution, which produces formic acid as the predominant product. The respective potentials of forming HCOO* are predicted to be -0.72 and -0.58 V on Pb and Sn. Higher overpotentials make other reaction pathways accessible, leading to different products. On Sn(112), CO and CH4 can be generated at -0.65 V following formate formation. In contrast, the limiting potential to access alternative reaction channels on Pb(211) is -1.33 V, significantly higher than that of Sn. 展开更多
关键词 electrochemical reduction reaction mechanism carbon dioxide FORMATE DFT
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