Nd-F species in NdF3-LiF melts were studied using cryoscopic method.Liquidus temperatures of melts of various compositions were determined by differential thermal analysis(DTA).Based on the different model calculation...Nd-F species in NdF3-LiF melts were studied using cryoscopic method.Liquidus temperatures of melts of various compositions were determined by differential thermal analysis(DTA).Based on the different model calculations,NdF4- was identified as the most likely Nd-F entity in the melts in which the mole fraction of NdF3 was lower than 20%,considering only one single Nd species in the melt,and which was formed in accordance with Temkin model or Flood model.Then,activities of different components in the melts were researched.The results show that activity of LiF decreases,and that of NdF3 increases with increasing the mole fraction of NdF3.The value of activity coefficient of NdF3 is higher than 1,and that of LiF is lower than 1.展开更多
Validated satellite-derived sea surface temperatures (SSTs) are widely used for climate monitoring and ocean data assimilation systems. In this study, the Fengyun-3A (FY-3A) SST experimental product is evaluated using...Validated satellite-derived sea surface temperatures (SSTs) are widely used for climate monitoring and ocean data assimilation systems. In this study, the Fengyun-3A (FY-3A) SST experimental product is evaluated using Advanced Very High Resolution Radiometer (AVHRR)-merged and in situ SSTs. A comparison of AVHRR-merged SSTs reveals a negative bias of more than 2K in FY-3A SSTs in most of the tropical Pacific and low-latitude Indian and Atlantic Oceans. The error variance of FY-3A SSTs is estimated using three-way error analysis. FY-3A SSTs show regional error variance in global oceans with a maximum error variance of 2.2 K in the Pacific Ocean. In addition, a significant seasonal variation of error variance is present in FY-3A SSTs, which indicates that the quality of FY-3A SST could be improved by adjusting the parameters in the SST retrieval algorithm and by applying regional and seasonal algorithms, particularly in key areas such as the tropical Pacific Ocean. An objective analysis method is used to merge FY-3A SSTs with the drifter buoy data. The errors of FY-3A SSTs are decreased to-0.45K comparing with SST observations from GTSPP.展开更多
This paper discusses the temperature field distribution of piezoelectric stack with heating and thermal insulation device in cryogenic temperature environment. Firstly,the model of the piezoelectric damper is simplifi...This paper discusses the temperature field distribution of piezoelectric stack with heating and thermal insulation device in cryogenic temperature environment. Firstly,the model of the piezoelectric damper is simplified and established by using partial-differential heat conduction equation. Secondly,the two-dimensional Du Fort-Frankel finite difference scheme is used to discretize the thermal conduction equation,and the numerical solution of the transient temperature field of piezoelectric stack driven by heating film at different positions is obtained by programming iteration. Then,the cryogenic temperature cabinet is used to simulate the low temperature environment to verify the numerical analysis results of the temperature field. Finally,the finite difference results are compared with the finite results and the experimental data in steady state and transient state,respectively. Comparison shows that the results of the finite difference method are basically consistent with the finite element and the experimental results,but the calculation time is shorter. The temperature field distribution results obtained by the finite difference method can verify the thermal insulation performance of the heating system and provide data basis for the temperature control of piezoelectric stack.展开更多
The first version of the Brazilian Oceano- graphic Modeling and Observation Network (REMO) ocean data assimilation system into the Hybrid Coordi- nate Ocean Model (HYCOM) (RODAS H) has recently been constructed ...The first version of the Brazilian Oceano- graphic Modeling and Observation Network (REMO) ocean data assimilation system into the Hybrid Coordi- nate Ocean Model (HYCOM) (RODAS H) has recently been constructed for research and operational purposes. The system is based on a multivariate Ensemble Optimal Interpolation (EnOI) scheme and considers the high fre- quency variability of the model error co-variance matrix. The EnOl can assimilate sea surface temperature (SST), satellite along-track and gridded sea level anomalies (SLA), and vertical profiles of temperature (T) and salinity (S) from Argo. The first observing system experiment was carried out over the Atlantic Ocean (78°S-50°N, 100°W-20°E) with HYCOM forced with atmospheric reanalysis from 1 January to 30 June 2010. Five integra- tions were performed, including the control run without assimilation. In the other four, different observations were assimilated: SST only (A SST); Argo T-S profiles only (AArgo); along-track SLA only (A_SLA); and all data employed in the previous runs (A_All). The A_SST, A_Argo, and A_SLA runs were very effective in improv- ing the representation of the assimilated variables, but they had relatively little impact on the variables that were not assimilated. In particular, only the assimilation of S was able to reduce the deviation of S with respect to ob- servations. Overall, the A_All run produced a good analy- sis by reducing the deviation of SST, T, and S with respect to the control run by 39%, 18%, and 30%, respectively, and by increasing the correlation of SLA by 81%.展开更多
Freezing is the most common method used to preserve and minimize loss in quality of catfish during storage. Since freezing is a heat transfer process, the design and selection of freezing equipment require knowledge o...Freezing is the most common method used to preserve and minimize loss in quality of catfish during storage. Since freezing is a heat transfer process, the design and selection of freezing equipment require knowledge of thermophysical properties such as freezing temperature, enthalpy of freezing, unfreezable water and specific heat. Channel catfish thermophysical properties at freezing temperature were determined using differential scanning calorimetry. Using the combination of Raoult's law and Classius-Clapeyron equations, the amount of unfreezable (bound water) was estimated to be 0.129 g H20 g^-1 During freezing (or melting), the specific heat increased from about 1.5 J g^-1 ℃^-1 to about 30.6 J g^-1 ℃^-1 It was found that freezing of catfish occur over a wide temperature range with the peak and incident freezing temperatures occurring at temperatures of-1.88 ℃ and -6.10 ℃, respectively. About 250 J g^-1 of heat have to be removed from catfish when it is to be frozen to -40 ℃. The implication is that any system that will be designed to freeze catfish must be able to remove 250 J g^-1 of heat.展开更多
To test the hypothesis that the variance of incubation temperature may have constituted a significant selective force for reptilian viviparity, we incubated eggs of the slender forest skink Scincella modesta in five t...To test the hypothesis that the variance of incubation temperature may have constituted a significant selective force for reptilian viviparity, we incubated eggs of the slender forest skink Scincella modesta in five thermally different natural nests and at two constant temperatures (18℃ and 21 ℃). Our manipulation of incubation temperature had significant effects on incubation length and several hatchling traits (snout-vent length, tail length, fore-limb length, and sprint speed), but not on hatching success and other hatchling traits examined (body mass, head size, and hind-limb length). Incubation length was nonlinearly sensitive to temperature, but it was not correlated with the thermal variance when holding the thermal mean constant. The 18 ℃ treatment not only produced smaller sized hatchlings but also resulted in decreased sprint speed. Eggs in the nest with the greatest proportion of temperatures higher than 28 ℃ also produced smaller sized hatchlings. None of the hatchling traits examined was affected by the thermal variance. Thermal fluctuations did result in longer incubation times, but females would benefit little from maintaining stable body temperatures or selecting thermally stable nests in terms of the reduced incubation length. Our data show that the mean rather than the variance of temperatures has a key role in influencing incubation length and hatchling phenotypes, and thus do not support the hypothesis tested .展开更多
In the new century, energy and environmental problems are becoming more critical, and the development of natural energy is desired. Low-grade Thermal Energy Conversion(LTEC) is refocused as one of the renewable energy...In the new century, energy and environmental problems are becoming more critical, and the development of natural energy is desired. Low-grade Thermal Energy Conversion(LTEC) is refocused as one of the renewable energy methods. The usefulness of LTEC is expected using hot springs and waste heat. In the case of the Rankine cycle using ammonia as the working fluid, the thermal properties of the working fluid changes in the evaporator. The traditional evaluation method of heat exchanger performance is the LMTD(Logarithmic Mean Temperature Difference) method. On the other hand, the GMTD(Generalized Mean Temperature Difference) method allows the variation of thermal properties in the heat exchanger. The aim of this study is to compare the two methods for the calculation of temperature differences and the corresponding influence on the total performance of the Rankine cycle that is operated using ammonia as a working fluid. As a result, the thermal efficiency of the Rankine cycle is greater than that of the LMTD method. Moreover, the computable range of the GMTD calculation method is less than that of the LMTD calculation method.展开更多
The accuracy of daily mean 2 meter air temperatures from five reanalyses are assessed against in-situ observations from Automatic Weather Stations in East Antarctica for 2005 to 2008. The five reanalyses all explain m...The accuracy of daily mean 2 meter air temperatures from five reanalyses are assessed against in-situ observations from Automatic Weather Stations in East Antarctica for 2005 to 2008. The five reanalyses all explain more than 70% of the average variance, and have annual root mean square errors (RMSE) between 3.4 and 6.9℃. The NOAA reanalyses, NCEP-1, NCEP-2 and 20CRv2, have cool biases of 2.5, 1.4 and 1.5℃, respectively. The ERA Interim and JCDAS reanalyses have warm biases of 1.7 and 2.0℃. All reanalyses generally perform better in the austral spring and worse in winter and autumn. They also show the best performance at an inland plateau site at 2800 m elevation, but are worst at Dome A, the summit of the East Antarctic ice sheet. In general, ERA Interim is superior to the other reanalyses, probably because of its 4D assimilation scheme. The three NOAA reanalyses perform worst; Their assimilation scheme is more constrained by limited observations and 20CRy2 has less input data, assimilating only surface pressure observations. Despite deficiencies and limitations, the reanalyses are still powerful tools for climate studies in the Antarctic region. However, more in-situ observations are required, especially from the vast interior of Antarctica.展开更多
基金Project(51004034)supported by the National Natural Science Foundation of ChinaProject(N090302009)supported by the Fundamental Research Funds for the Central Universities,China
文摘Nd-F species in NdF3-LiF melts were studied using cryoscopic method.Liquidus temperatures of melts of various compositions were determined by differential thermal analysis(DTA).Based on the different model calculations,NdF4- was identified as the most likely Nd-F entity in the melts in which the mole fraction of NdF3 was lower than 20%,considering only one single Nd species in the melt,and which was formed in accordance with Temkin model or Flood model.Then,activities of different components in the melts were researched.The results show that activity of LiF decreases,and that of NdF3 increases with increasing the mole fraction of NdF3.The value of activity coefficient of NdF3 is higher than 1,and that of LiF is lower than 1.
基金supported by the National Basic Research Program of China(973 Program,Grant Nos.2010CB951902 and 2011CB403505)the National Key Technologies R&D Program of China(Grant No.2009BAC51B03)the National Natural Science Foundation of China(Grant No.41106003)
文摘Validated satellite-derived sea surface temperatures (SSTs) are widely used for climate monitoring and ocean data assimilation systems. In this study, the Fengyun-3A (FY-3A) SST experimental product is evaluated using Advanced Very High Resolution Radiometer (AVHRR)-merged and in situ SSTs. A comparison of AVHRR-merged SSTs reveals a negative bias of more than 2K in FY-3A SSTs in most of the tropical Pacific and low-latitude Indian and Atlantic Oceans. The error variance of FY-3A SSTs is estimated using three-way error analysis. FY-3A SSTs show regional error variance in global oceans with a maximum error variance of 2.2 K in the Pacific Ocean. In addition, a significant seasonal variation of error variance is present in FY-3A SSTs, which indicates that the quality of FY-3A SST could be improved by adjusting the parameters in the SST retrieval algorithm and by applying regional and seasonal algorithms, particularly in key areas such as the tropical Pacific Ocean. An objective analysis method is used to merge FY-3A SSTs with the drifter buoy data. The errors of FY-3A SSTs are decreased to-0.45K comparing with SST observations from GTSPP.
文摘This paper discusses the temperature field distribution of piezoelectric stack with heating and thermal insulation device in cryogenic temperature environment. Firstly,the model of the piezoelectric damper is simplified and established by using partial-differential heat conduction equation. Secondly,the two-dimensional Du Fort-Frankel finite difference scheme is used to discretize the thermal conduction equation,and the numerical solution of the transient temperature field of piezoelectric stack driven by heating film at different positions is obtained by programming iteration. Then,the cryogenic temperature cabinet is used to simulate the low temperature environment to verify the numerical analysis results of the temperature field. Finally,the finite difference results are compared with the finite results and the experimental data in steady state and transient state,respectively. Comparison shows that the results of the finite difference method are basically consistent with the finite element and the experimental results,but the calculation time is shorter. The temperature field distribution results obtained by the finite difference method can verify the thermal insulation performance of the heating system and provide data basis for the temperature control of piezoelectric stack.
基金financially supported by the Brazilian State oil company Petróleo Brasileiro S. A. (Petrobras) and Agência Nacional de Petróleo (ANP), Gás Natural e Biocombustíveis, Brazil, via the Oceanographic Modeling and Observation Network (REMO)support of the Coordenao de Aperfeioamento de Pessoal de Nível Superior (CAPES), Ministry of Education of Brazil (Proc. BEX 3957/13-6)
文摘The first version of the Brazilian Oceano- graphic Modeling and Observation Network (REMO) ocean data assimilation system into the Hybrid Coordi- nate Ocean Model (HYCOM) (RODAS H) has recently been constructed for research and operational purposes. The system is based on a multivariate Ensemble Optimal Interpolation (EnOI) scheme and considers the high fre- quency variability of the model error co-variance matrix. The EnOl can assimilate sea surface temperature (SST), satellite along-track and gridded sea level anomalies (SLA), and vertical profiles of temperature (T) and salinity (S) from Argo. The first observing system experiment was carried out over the Atlantic Ocean (78°S-50°N, 100°W-20°E) with HYCOM forced with atmospheric reanalysis from 1 January to 30 June 2010. Five integra- tions were performed, including the control run without assimilation. In the other four, different observations were assimilated: SST only (A SST); Argo T-S profiles only (AArgo); along-track SLA only (A_SLA); and all data employed in the previous runs (A_All). The A_SST, A_Argo, and A_SLA runs were very effective in improv- ing the representation of the assimilated variables, but they had relatively little impact on the variables that were not assimilated. In particular, only the assimilation of S was able to reduce the deviation of S with respect to ob- servations. Overall, the A_All run produced a good analy- sis by reducing the deviation of SST, T, and S with respect to the control run by 39%, 18%, and 30%, respectively, and by increasing the correlation of SLA by 81%.
文摘Freezing is the most common method used to preserve and minimize loss in quality of catfish during storage. Since freezing is a heat transfer process, the design and selection of freezing equipment require knowledge of thermophysical properties such as freezing temperature, enthalpy of freezing, unfreezable water and specific heat. Channel catfish thermophysical properties at freezing temperature were determined using differential scanning calorimetry. Using the combination of Raoult's law and Classius-Clapeyron equations, the amount of unfreezable (bound water) was estimated to be 0.129 g H20 g^-1 During freezing (or melting), the specific heat increased from about 1.5 J g^-1 ℃^-1 to about 30.6 J g^-1 ℃^-1 It was found that freezing of catfish occur over a wide temperature range with the peak and incident freezing temperatures occurring at temperatures of-1.88 ℃ and -6.10 ℃, respectively. About 250 J g^-1 of heat have to be removed from catfish when it is to be frozen to -40 ℃. The implication is that any system that will be designed to freeze catfish must be able to remove 250 J g^-1 of heat.
基金The work was carried out in compliance with the current laws of China, and was supported by grant from Priority Academic Program Development of Jiangsu Higher Education Institutions to Ji's group, the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Project No. llKJB180004), Jiangsu Provincial Foundation of Natural Science (No. BK2012849) and the Natural Science Foundation of China (No. 31070339). We would like to thank Long-Hui Lin, Jian-Fang Gao, Lai-Gao Luo andYan-Fu Qu for their assistance both in the field and in the laboratory.
文摘To test the hypothesis that the variance of incubation temperature may have constituted a significant selective force for reptilian viviparity, we incubated eggs of the slender forest skink Scincella modesta in five thermally different natural nests and at two constant temperatures (18℃ and 21 ℃). Our manipulation of incubation temperature had significant effects on incubation length and several hatchling traits (snout-vent length, tail length, fore-limb length, and sprint speed), but not on hatching success and other hatchling traits examined (body mass, head size, and hind-limb length). Incubation length was nonlinearly sensitive to temperature, but it was not correlated with the thermal variance when holding the thermal mean constant. The 18 ℃ treatment not only produced smaller sized hatchlings but also resulted in decreased sprint speed. Eggs in the nest with the greatest proportion of temperatures higher than 28 ℃ also produced smaller sized hatchlings. None of the hatchling traits examined was affected by the thermal variance. Thermal fluctuations did result in longer incubation times, but females would benefit little from maintaining stable body temperatures or selecting thermally stable nests in terms of the reduced incubation length. Our data show that the mean rather than the variance of temperatures has a key role in influencing incubation length and hatchling phenotypes, and thus do not support the hypothesis tested .
文摘In the new century, energy and environmental problems are becoming more critical, and the development of natural energy is desired. Low-grade Thermal Energy Conversion(LTEC) is refocused as one of the renewable energy methods. The usefulness of LTEC is expected using hot springs and waste heat. In the case of the Rankine cycle using ammonia as the working fluid, the thermal properties of the working fluid changes in the evaporator. The traditional evaluation method of heat exchanger performance is the LMTD(Logarithmic Mean Temperature Difference) method. On the other hand, the GMTD(Generalized Mean Temperature Difference) method allows the variation of thermal properties in the heat exchanger. The aim of this study is to compare the two methods for the calculation of temperature differences and the corresponding influence on the total performance of the Rankine cycle that is operated using ammonia as a working fluid. As a result, the thermal efficiency of the Rankine cycle is greater than that of the LMTD method. Moreover, the computable range of the GMTD calculation method is less than that of the LMTD calculation method.
基金funded by the Major State Basic Research Development Program of China (Grant No. 2013CBA01804)the National Natural Science Foundation of China (Grant Nos. 41121001, 40801027)the State Key Laboratory of Cryospheric Sciences (Grant No. SKLCS-ZZ- 2012-01-07)
文摘The accuracy of daily mean 2 meter air temperatures from five reanalyses are assessed against in-situ observations from Automatic Weather Stations in East Antarctica for 2005 to 2008. The five reanalyses all explain more than 70% of the average variance, and have annual root mean square errors (RMSE) between 3.4 and 6.9℃. The NOAA reanalyses, NCEP-1, NCEP-2 and 20CRv2, have cool biases of 2.5, 1.4 and 1.5℃, respectively. The ERA Interim and JCDAS reanalyses have warm biases of 1.7 and 2.0℃. All reanalyses generally perform better in the austral spring and worse in winter and autumn. They also show the best performance at an inland plateau site at 2800 m elevation, but are worst at Dome A, the summit of the East Antarctic ice sheet. In general, ERA Interim is superior to the other reanalyses, probably because of its 4D assimilation scheme. The three NOAA reanalyses perform worst; Their assimilation scheme is more constrained by limited observations and 20CRy2 has less input data, assimilating only surface pressure observations. Despite deficiencies and limitations, the reanalyses are still powerful tools for climate studies in the Antarctic region. However, more in-situ observations are required, especially from the vast interior of Antarctica.