开孔泡沫钛力学性质的温度相依性

用粉末烧结法制备了相对密度为0．2的开孔泡沫纯钛材料，并在室温20～600℃温度范围内，对其压缩性能进行了测试，并从理论上分析了其杨氏模量、弹性极限和屈服强度对温度的相依性。结果表明：该开孔泡沫材料在室温下表现出脆性泡沫材料变形断裂特征；在200℃以及更高温度下，该材料表现出塑性开孔泡沫材料变形特征，其应力-应变曲线分为3个阶段，即弹性阶段，平台阶段和压实阶段。开孔泡沫钛的杨氏模量、弹性极限和屈服强度随着温度的升高而减小，其对温度的相依性可分别表示为：E^＊=1．5217×10^9-5．988×10^5 T，σel^＊=85．7-0．095T，σys^＊=99．1-0．16T＋7．02×10^-5T^2。

Gas Phase Thermodynamic Properties of Polychlorinated Xanthones Predicted with DFT Method and Cl Substituted Position

The gas phase thermodynamic properties of 135 polychlorinated xanthones(PCXTs)are calculated using a combination of quantum mechanical computations performed with the Gaussian 03 program at the B3LYP/6-311G**level.It is found that the chlorine substitution pattern strongly influences the thermodynamic properties of the compounds.The thermodynamic properties of congeners with the same number of chlorines also depend on the chlorine substitution pattern,especially for ortho-substituted congeners.PCXT congeners with one phenyl ring fully chlorinated are found to be the least stable among the analogues.The effect of the chlorine substitution pattern is quantitatively studied by considering the number and position of Cl atom substitution(NPCS).The results show that the NPCS model may be used to predict the thermodynamic properties for all 135 PCXT congeners. In addition,the values of molar heat capacities at constant pressure(cp,m)from 200 to 1000 K for PCXT congeners are calculated,and the temperature dependence relation of this parameter is obtained using the least-squares method.

Te^(4+)-doped Cs_(2)InCl_(5)·H_(2)O single crystals for remote optical thermometry

Zero-dimensional metal halide perovskites have captured intense research interest owing to their unique optoelectronic properties.Particularly,metal halides with the ns^(2) electronic configuration are of great interest owing to the high-temperature sensitivity of their photoluminescence,which could be applied to remote optical thermometry(ROT).Herein,all-inorganic and lead-free halide perovskite Te^(4+)-doped Cs_(2)InCl_(5)·H_(2)O single crystals(SCs)were prepared through the hydrothermal method and showed a strong temperature dependence of photoluminescence lifetime.Upon Te^(4+) doping,the nonemissive Cs_(2)InCl_(5)·H_(2)O SC exhibits a bright orange emission at 660 nm with a wide full width at half maximum of 180 nm.The strong phonon-exciton coupling promotes the formation of self-trapped excitons in the soft lattice of the zero-dimensional Te^(4+)-doped Cs_(2)InCl_(5)·H_(2)O SC.The Te^(4+) ions with the 5 s^(2) electronic configuration endow the Te^(4+)-doped Cs_(2)InCl_(5)·H_(2)O SC with a strong temperaturedependent photoluminescence lifetime.This SC reaches a maximum specific sensitivity of 0.062 K^(-1) at 320 K,thereby showing the potential advantages of indium-based metal halide perovskites in ROT applications.

ON STABILITY AND REGULARIZATION FOR BACKWARD HEAT EQUATION

Consider a backward heat equation in a bounded domain Ω (?) R2 with the noisy data in the initial time geometry. The aim is to find the temperature for 0 < ε < t < T. For this ill-posed problem, the authors give a continuous dependence estimate of the solution. Moreover, the convergence rate of the approximate solution is also given.

Relative humidity and temperature dependence of mechanical degradation of natural fiber composites^(?)

In this paper,the mechanical degradation of natural fiber composites is studied with the consideration of the relative humidity and the temperature.A nonlinear constitutive model is established,which employs an internal variable to describe the mechanical degradation related to the energy dissipation during moisture absorption.The existing experimental researches demonstrated that the mechanical degradation is an irreversible thermodynamic process induced by the degradation of fibers and the damages of interfaces between fiber and matrix,both of which depend on the variation of the relative humidity or the temperature.The evolution of the mechanical degradation is obtained through the determination of dissipation rates as a function of the relative humidity and the temperature.The theoretically predicted mechanical degradations are compared with experimental results of sisal fiber reinforced composites subject to different relative humidity and temperatures,and a good agreement is found.

A novel technique for probing phase transitions in ferroelectric functional materials: Condensed matter spectroscopy

As relaxor ferroelectric functional materials, their crystal structures depend on temperature, component, electric filed, pressure, and so on, which are important for the applications of sensors, transducers, and actuators. For the case of PbTiO3-based ferroelectrics Pb（Zn2/3Nb2/3）O3-PbTiO3, Pb（Mg1/3Nb2/3）O3-PbTiO3, Pb（In1/2Nb1/2）O3-Pb（Mgu3Nb2/3）O3-PbTiO3 and some other crystals, they have been extensively investigated due to the excellent electromechanical and piezoelectric properties. Generally, ferroelectric crystal structure and corresponding phase diagram are detected by temperature-dependent high resolution X-ray diffraction, low frequency dielectric permittivity, and domain structures. In this review, we focus on the novel condensed matter spectroscopy （i.e., spectroscopic ellipsometry, transmittance, photoluminescence spectra as well as Raman spectra）, which is nondestructive, noncontact, and sensitive optical techniques for probing symmetries, phase transitions and phase diagrams of ferroelectric crystals. Besides, it can supply some other physical and chemical information for ferroelectric and semiconductor functional materials such as optical band gap, electronic transitions, dielectric functions, optical conductivity, absorption, pho- non modes, lattice dynamics as functions of temperature and PT composition.

Stimulated Holographic P-wave Superconductors

Using classical time-average approximation, critical temperature and condensed solution in holographic pwave superconductors with a time-dependent source is investigated in probe limit. By choosing suitable gauge field ansatz, the equation of motion for a vector field is presented. With the help of the Sturm-Liouville equation, concrete values of phase transition temperature and criticaJ frequency are obtained. It is shown that the phase transition temperature enhances as the frequency of the time-dependent source raises in high frequency regime, which means that the operators on the boundary field theory will be easier to condense.