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含鏻聚多肽的合成与温敏性质研究
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作者 肖江 李敏捷 唐浩宇 《高分子学报》 SCIE CAS CSCD 北大核心 2018年第1期56-62,共7页
通过亲核取代反应合成了一系列含鏻和氯反离子的聚多肽(P1-Cl^P5-Cl).利用核磁共振氢谱和傅里叶变换红外光谱验证了聚合物的分子结构.在核磁共振氢谱图中,通过特征氢峰的积分面积计算了三丁基鏻和三苯基鏻侧基的含量和接枝度.通过离子... 通过亲核取代反应合成了一系列含鏻和氯反离子的聚多肽(P1-Cl^P5-Cl).利用核磁共振氢谱和傅里叶变换红外光谱验证了聚合物的分子结构.在核磁共振氢谱图中,通过特征氢峰的积分面积计算了三丁基鏻和三苯基鏻侧基的含量和接枝度.通过离子交换反应合成了一系列含鏻和碘或氟硼酸根反离子的聚多肽(P1-I^P5-I和P1-BF4~P5-BF4).三丁基鏻含量为x=0.89的P2-I和P2-BF4样品在水溶液中具有可逆的高临界溶解温度(UCST)类型的温敏性质.变温紫外-可见光谱的结果表明,UCST类型的相转变温度(Tpt)具有显著的聚合物浓度、盐浓度和种类的依赖性.Tpt随聚合物浓度、碘化钠或氟硼酸钠浓度的增加而升高,随氯化钠浓度的增加而降低. 展开更多
关键词 聚多肽(聚氨基酸) 离子聚合物 高临界溶解温度 温敏性质
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Investigation on the Sterility Changeover of Male Sterility Line CMS7311 in Heading Chinese Cabbage 被引量:12
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作者 张鲁刚 郝东方 《Acta Botanica Sinica》 CSCD 2001年第11期1123-1128,共6页
Sterility changeover induced by low temperature in male sterility line CMS7311 of heading Chinese cabbage ( Brassica campestris L. ssp. penkinsis) was investigated under constant temperature, day/night alternating tem... Sterility changeover induced by low temperature in male sterility line CMS7311 of heading Chinese cabbage ( Brassica campestris L. ssp. penkinsis) was investigated under constant temperature, day/night alternating temperature in light-growth-incubator and outdoor natural day/night alternating temperature respectively. It showed that the sterility of CMS7311 has significant change with temperature. The constant temperature of 6 - 12 degreesC was suitable to induce the changeover of sterility (CGS) of CMS7311 ; the shortest treatment time for CGS induction at this temperature was 3 d. The significant value of sterility changeover of CMS7311 occurred at the constant temperature of 6 - 9 degreesC after treatment for 6 - 9 d. The intensity of CGS was stronger under constant temperature than under alternate temperature, but the shortest treatment time inducing CGS has no difference between them. When treated for 9 d under the day/night alternating temperature of 11/7 degreesC, its sterility could also turn to normal fertility (near to sterile grade I or zero). In normal condition, the interval from the end of temperature treatment to the beginning of CGS induction was 10 - 16 d. In the condition of natural day/night alternating temperature, the lower limit of temperature for effective CGS induction was at the daily mean temperature ( DMT) of 3. 5 - 6. 8 degreesC, and the shortest treatment time which could induce the sterility changeover was also longer than that under constant temperature, being 11d at DMT of 1.5 - 3.1 degreesC. In addition, for the apical dominance, the flower bud on the first lateral branch showed the CGS 8 - 10 d later than the flower bud on the main stem under the same temperature with the same days of treatment. The intensity of CGS of CMS7311 on the first lateral branch was also weaker than the flower bud on the main stem. 展开更多
关键词 heading Chinese cabbage CMS7311 changeover of sterility (CGS) temperature sensitive
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Correlation of ^1H NMR Chemical Shift for Aqueous Solutions by Statistical Associating Fluid Theory Association Model 被引量:2
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作者 许波 李浩然 +2 位作者 王从敏 许映杰 韩世钧 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2005年第2期280-284,共5页
1H NMR chemical shifts of binary aqueous mixtures of acylamide, alcohol, dimethyl sulphoxide (DMSO), and acetone are correlated by statistical associating fluid theory (SAFT) association model. The comparison between ... 1H NMR chemical shifts of binary aqueous mixtures of acylamide, alcohol, dimethyl sulphoxide (DMSO), and acetone are correlated by statistical associating fluid theory (SAFT) association model. The comparison between SAPT association model and Wilson equation shows that the former is better for dealing with aqueous solutions. Finally, the specialties of both models are discussed. 展开更多
关键词 Statistical associating fluid theory (SAFT) association model NMR chemical shift aqueous solution
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