辽宁省本溪城区地热类型探讨

对本溪城区地热类型进行分类,着重介绍增温型地热的特点,并对本溪市区地热资源开发远景进行展望。

Hydrogen desorption kinetics mechanism of Mg-Ni hydride under isothermal and non-isothermal conditions

The Mg-Ni hydride was prepared by hydriding combustion synthesis under a high magnetic field. The dehydriding kinetics of the hydrides was measured under the isothermal and non-isothermal conditions. A model was applied to analyzing the kinetics behavior of Mg-Ni hydride. The calculation results show that the theoretical value and the experimental data can reach a good agreement, especially in the case of non-isothermal dehydriding. The rate-controlling step is the diffusion of hydrogen atoms in the solid solution. The sample prepared under magnetic field of 6 T under the isothermal condition can reach the best performance. The similar tendency was observed under the non-isothermal condition and the reason was discussed.

Extension of analytical model of solid-state phase transformation

Departing from an analytical phase transformation model, a new analytical approach to deduce transformed fraction for non-isothermal phase transformation was developed. In the new approach, the effect of the initial transformation temperature and the accurate ＂temperature integral＂ approximations are incorporated to obtain an extended analytical model. Numerical approach demonstrated that the extended analytical model prediction for transformed fraction and transformation rate is in good agreement with the exact numerical calculation. The new model can describe more precisely the kinetic behavior than the original analytical model, especially for transformation with relatively high initial transformation temperature. The kinetic parameters obtained from the new model are more accurate and reasonable than those from the original analytical model.

Adsorptive Thermodynamic Properties and Kinetics of trans-1,2-Cyclohexandiol onto AB-8 Resin

AB-8 resin was used as an adsorbent for the removal of trans-1,2-cyclohexandiol(CHD) from aqueous solutions.Batch experiments were carried out to investigate the effect of contact time and temperature on sorption efficiency.The adsorptive thermodynamic properties and kinetics of CHD from water onto AB-8 resin were studied.The Langmuir and Freundlich isotherm models were employed to discuss the adsorption behavior.Thermodynamic parameters such as G,H and S were calculated.The results indicate that the equilibrium data are perfectly represented by Langmuir isotherm model.Thermodynamic study reveals that it is an exothermic process in nature and mainly physical adsorption enhanced by chemisorption with a decrease of entropy process.The kinetics of CHD adsorption is well described by the pseudo second-order model.The adsorbed CHD can be eluted from AB-8 resin by 5% ethanol aqueous solution with 100% elution percentage.

Changes in temperature extremes over China under 1.5 ℃ and 2 ℃ global warming targets

The long-term goal of the 2015 Paris Agreement is to limit global warming to well below 2 ℃above pre-industrial levels and to pursue efforts to limit it to 1.5 ℃. However, for climate mitigation and adaption efforts, further studies are still needed to understand the regional consequences between the two global warming limits. Here we provide an assessment of changes in temperature extremes over China （relative to 1986-2005） at 1.5 ℃ and 2 ℃ warming levels （relative to 1861-1900） by using the 5th phase of the Coupled Model Intercomparison Project （CMIP5） models under three RCP scenarios （RCP2.6, RCP4.5, RCP8.5）. Results show that the increases in mean temperature and temperature extremes over China are greater than that in global mean temperature. With respect to 1986-2005, the temperature of hottest day （TXx） and coldest night （TNn） are projected to increase about 1/1.6 ℃ and 1.1/1.8 ℃, whereas warm days （TX90p） and warm spell duration （WSDI） will increase about 7.5/13.8% and 15/30 d for the 1.5/2 ℃ global warming target, respectively. Under an additional 0.5 ℃ global warming, the projected increases of temperature in warmest day/night and coldest day/night are both more than 0.5 ℃ across almost the whole China. In Northwest China, Northeast China and the Tibetan Plateau, the projected changes are particularly sensitive to the additional 0.5 ℃ global warming, for example, multi-model mean increase in coldest day （TXn） and coldest night （TNn） will be about 2 times higher than a change of 0.5 ℃ global warming. Although the area-averaged changes in temperature extremes are very similar for different scenarios, spatial hotspot still exists, such as in Northwest China and North China, the increases in temperatures are apparently larger in RCP8.5 than that in RCP4.5.

Simplification and Experimental Verification for Temperature and Humidity Field Coupling Model of Conservatory Soil

Based on the surface energy balance model which is widely used abroad, a temperature and humidity field coupling model of conservatory soil without crop vegetation in full illumination was established. Considering the relatively closed environment in conservatory, weak solar radiation and little surface evaporation of soil, the daily variation of water content in different soil layers may be neglected, then the temperature and humidity field coupling model was simplified to a one-dimensional thermal diffusion model. The simplified model and the temperature and humidity field coupling model adopted the same computational method of soil physical parameters and discrete format of heat diffusion differential equations, and were applied to the continuous simulation of temperature field in conservatory soil without crop vegetation in full illumination. Through the comparison between simulation results and experimental data, the precision of the simplified model was verified. The typical rule of soil heat flux variation in a 24 h cycle was also obtained.

Removal of Bi(Ⅲ) with Adsorption Technique Using Coconut Shell Activated Carbon

In present study,we report the preparation of coconut shell activated carbon as adsorbent and its appli-cation for Bi(Ⅲ) removal from aqueous solutions.The developed adsorbent was characterized with scanning elec-tron microscope(SEM),Fourier Transform Infrared(FTIR),C,H,N,S analyzer,and BET surface area analyzer.The parameters examined include agitation time,initial concentration of Bi(Ⅲ),adsorbent dose and temperature.The maximum adsorption of Bi(Ⅲ)(98.72%) was observed at 250 mg·L-1 of Bi(Ⅲ) and adsorbent dose of 0.7 g when agitation was at 160 r·min-1 for 240 min at(299±2) K.The thermodynamic parameters such as Gibb's free energy(△Gθ),enthalpy(△Hθ) and entropy(△Sθ) were evaluated.For the isotherm models applied to adsorption study,the Langmuir isotherm model fits better than the Freundlich isotherm.The maximum adsorption capacity from the Langmuir isotherm was 54.35 mg?g?1 of Bi(Ⅲ).The kinetic study of the adsorption shows that the pseudo second order model is more appropriate than the pseudo first order model.The result shows that,coconut shell ac-tivated carbon is an effective adsorbent to remove Bi(Ⅲ) from aqueous solutions with good adsorption capacity.

Fracture behavior of high strength Mg-Gd-Y-Zr magnesium alloy

The fracture behavior of a permanent mould casting Mg-8.57Gd-3.72Y-0.54Zr(mass fraction,%)(GW94) alloy was investigated under different thermal conditions,including as-cast,solution-treated,peak-aged,and over-aged states.Scanning electron microscopy(SEM) and optical microscopy(OM) were employed to examine the crack nucleation and fracture model.The results indicate that the GW94 alloy shows different behaviors of crack initiation and fracture under different thermal conditions. During tensile test at room temperature,the fracture model of the as-cast GW94 alloy is quasi-cleavage,while that of the solution-treated alloy is transgranular cleavage.It is a mixed pattern of transgranular and intergranular fracture for both the aged conditions.Large cavities formed at grain boundaries are observed in the peak-aged sample tested at 300℃,corresponding to the intergranular fracture.Localized plastic deformation at grain boundaries is also observed and corresponds to the high elongation at 300℃.

Temperature modeling and control of Direct Methanol Fuel Cell based on adaptive neural fuzzy technology

Aiming at on-line controlling of Direct Methanol Fuel Cell （DMFC） stack, an adaptive neural fuzzy inference technology is adopted in the modeling and control of DMFC temperature system. In the modeling process, an Adaptive Neural Fuzzy Inference System （ANFIS） identification model of DMFC stack temperature is developed based on the input-output sampled data, which can avoid the internal complexity of DMFC stack. In the controlling process, with the network model trained well as the reference model of the DMFC control system, a novel fuzzy genetic algorithm is used to regulate the parameters and fuzzy rules of a neural fuzzy controller. In the simulation, compared with the nonlinear Proportional Integral Derivative （PID） and traditional fuzzy algorithm, the improved neural fuzzy controller designed in this paper gets better performance, as demonstrated by the simulation results.

Locating method of fire source for spontaneous combustion of sulfide ores

in order to achieve a more efficient way to accurately detect the position of the fire source of spontaneous combustion underground mine, a simple fire source locating method, based on infrared scanning system which can determine the point where the highest temperature on the surface of igniting ores occurs, was proposed. First, the differential equations that describe heat flow in ore body were presented and the relationship between the surface temperature distribution and the depth and intensity of inner fire source was established with a relatively simple heat transfer model. With the solution of equation, the expression of the relationship between the surface temperature distribution and the inner fire source was deduced and the mathematical-physical model of heat transfer process was set up. Then, with the model, visualization of fire source on the basis of MATLAB simulation platform was realized. The results show that： 1） within 10 m, when the detecting depth is less than 2 m, the temperature perturbation on ores surface can change rapidly, and then slowly; after 4 m, in contrast, it changes very little, and is even close to zero at 10 m; 2） When it is close to self-ignition duration and the detective depths are 2, 5 and 10 m, respectively, the maximum temperature differences are correspondingly 0.5, 0.04 and 0.005 ℃ in the scope of 1 m×1 m; under the same condition, the maximum temperature differences are 1.391, 0.136 and 0.018 ℃, respectively, in the scope of 2 m×2 m. Therefore, this system can be used to measure the temperature differences on the surface of ore body and determine the highest temperature point directly. Also, it is possible to determine the depth of fire source and its intensity by locating method of fire source indirectly.

An Experimental Study on the Drag Property of High-Temperature Particles Falling into Cold Liquid Pool

This experiment is to study the special resistant induced by the high-speed evaporation surrounding themoving high-temperature particles. An observable equipment was designed, in which the first 11 experiments wereperformed by pouring one or several Zirconia spheres with various high-temperature and a diameter of 3～ 10 mminto a water pool. The particles falling-down speeds were recorded by high-speed photographic instrumentation,and pressures and water temperatures were measured. A comparison between the experiments with cold and hotspheres respectively, employing three different sphere types each, was presented. The experimental data, com-pared with the theory of the evaporation drag model, are nearly identical.

Effect of cooling structure on thermal behavior of copper plates of slab continuous casting mold

A three-dimensional finite-element model of slab continuous casting mold was conducted to clarify the effect of cooling structure on thermal behavior of copper plates. The results show that temperature distribution of hot surface is mainly governed by cooling structure and heat-transfer conditions. For hot surface centricity, maximum surface temperature promotions are 30 ℃and 15 ℃ with thickness increments of copper plates of 5 mm and nickel layers of 1 ram, respectively. The surface temperature without nickel layers is depressed by 10 ℃ when the depth increment of water slots is 2 mm and that with nickel layers adjacent to and away from mold outlet is depressed by 7℃ and 5 ℃, respectively. The specific trend of temperature distribution of transverse sections of copper plates is nearly free of cooling structure, but temperature is changed and its law is similar to the corresponding surface temperature.

Investigation of non-isothermal and isothermal gasification process of coal char using different kinetic model

Isothermal and non-isothermal gasification kinetics of coal char were investigated by using thermogravimetric analysis(TGA) in CO2 atmosphere, and the experimental data were interpreted with the aids of random pore model(RPM), unreacted shrinking core model(URCM) and volume model(VM). With the increase of heating rate, gasification curve moves into high temperature zone and peak rate of gasification increases; with the increase of gasification temperature, gasification rate increases and the total time of gasification is shortened. The increase of both heating rate and gasification temperature could improve gasification process of coal char. Kinetics analysis indicates that experimental data agree better with the RPM than with the other two models. The apparent activation energy of non-isothermal and isothermal gasification of coal char using RPM is 193.9 k J/mol and 212.6 k J/mol respectively, which are in accordance with reported data. Gasification process of coal char under different heating rates and different temperatures are predicted by the RPM derived in this study, and it is found that the RPM predicts the reaction process satisfactorily.

Influence of Weather and Climate on Malaria Occurrence Based on Human-Biometeorological Methods in Ondo State, Nigeria

This study focuses on the influence of weather and climate on malaria occurrence based on human-biometeorological methods was carried out in Ondo State, Nigeria using meteorological and malaria dataset in the state for the period from 1998 to 2008. In addition, sea surface temperatures （SSTs） over equatorial Pacific Ocean were integrated in the analysis. The association between each of the meteorological-biometeorological parameters and clinical-reported malaria cases was examined by using Poisson distribution and log as link function between the two categories of dataset. The next step was the building of a model by using Poisson multiple regression models （GLMs） in order to know the weather variables that lead to statistically changes in clinical-reported malaria cases. The study revealed that an increase of I m.s1 of wind speed can lead to an increase of about 164% and 171% in the monthly occurrence of malaria at 95% confidence interval in derived savanna and humid forest zone respectively. Also, an increase of I ℃ in air temperature and sea surface temperature is associated with 53.4% and 29% increase in monthly malaria occurrence （CI： 95%） in derived savanna while an increase of 1 ℃ in air temperature and sea surface temperature is associated with 56.4% and 15.4% increase in monthly malaria occurrence at 95% confidence interval in humid forest zone of Ondo State

Research on software development of air temperature prediction in coal face

With ever-increasing depth of coal mine and the continuous improvement of mechanization, heat damage has become one of the major disasters in coal mine exploitation. Established the temperature prediction models suitable for different kinds of tunnels through analysis of the heat of shafts, roadways and working faces. The average annual air temperature prediction equation from the inlets of shafts to the working faces was derived. The formula was deduced using combine method of iteration and direct calculation. The method can improve the precision of air temperature prediction, so we could establish the whole pathway air temperature prediction model with high precision. Emphasizing on the effects of leakage air to air temperature of working face and using the ideology of the finite difference method and considering the differential equation of inlet and outlet at different stages, this method can significantly improve the accuracy of temperature prediction. Program development uses Visual Basic 6.0 Language, and the Origin software was used to fit the relevant data. The predicted results shows that the air temperature generally tends to rapidly increase in the air inlet, then changes slowly on working face, and finally increases sharply in air outlet in the condition of goaf air leakage. The condition is in general consistent with the air temperature change tendency of working face with U-type ventilation system. The software can provide reliable scientific basis for reasonable ventilation, cooling measures and management of coal mine thermal hazards.

Last Glacial Maximum Sea Surface Temperatures: A Model-Data Comparison

In this study,the authors investigated changes in Last Glacial Maximum （LGM） sea surface temperature （SST） simulated by the Paleoclimate Modelling Intercomparison Project （PMIP） multimodels and reconstructed by the Multiproxy Approach for the Reconstruction of the Glacial Ocean Surface （MARGO） project,focusing on model-data comparison.The results showed that the PMIP models produced greater ocean cooling in the North Pacific and Tropical Ocean than the MARGO,particularly in the northwestem Pacific,where the modeldata mismatch was larger.All the models failed to capture the anomalous east-west SST gradient in the North Atlantic.In addition,large discrepancies among the models were observed in the mid-latitude ocean,particularly with models in the second phase of the PMIP.Although these models showed better agreement with the MARGO,the latest models in the third phase of the PMIP did not show substantial progresses in simulating LGM ocean surface conditions.That is,improvements in the modeling community are still needed to describe SST for a better understanding of climate during the LGM.

Adsorption of Naphthol Green B on unburned carbon：2-and3-parameter linear and non-linear equilibrium modelling

The study deals with adsorption of Naphthol Green B on two unburned carbons and the parent coal,from which the UCs have been created in a fluidised-bed power station.Particular attention has been paid to the adsorption equilibrium modelling:experimental data has been analysed using 2-parameter(Langmuir,Freundlich) and3-parameter(Redlich-Peterson) isotherms — both linear and non-linear regressions have been used for the estimation of the isotherm parameters.In the case of both UCs,the Langmuir isotherm model provides the worst fit,whereas 2-parameter Freundlich and 3-parameter Redlich-Peterson models are both good,from which 3-parameter Redlich-Peterson isotherm provides slightly better results(despite the penalty used for the higher number of parameters).In the case of both UCs,the linear regression of Freundlich and Redlich-Peterson models provides good results(comparable with non-linear regressions).Unlike both UCs,the best fit of the experimental data from the adsorption on the coal has been achieved by the Langmuir isotherm model.The results based on the Freundlich or Redlich-Peterson model were(in this case) somewhat worse.

Preliminary Studies on Predicting the Tropical Indian Ocean Sea Surface Temperature through Combined Statistical Methods and Dynamic ENSO Prediction

The sea surface temperature （SST） in the In- dian Ocean affects the regional climate over the Asian continent mostly through a modulation of the monsoon system. It is still difficult to provide an a priori indication of the seasonal variability over the Indian Ocean. It is widely recognized that the warm and cold events of SST over the tropical Indian Ocean are strongly linked to those of the equatorial eastern Pacific. In this study, a statistical prediction model has been developed to predict the monthly SST over the tropical Indian Ocean. This model is a linear regression model based on the lag relationship between the SST over the tropical Indian Ocean and the Nino3.4 （5°S-5°N, 170°W-120°W） SST Index. The pre- dictor （i.e., Nino3.4 SST Index） has been operationally predicted by a large size ensemble E1 Nifio and the Southern Oscillation （ENSO） forecast system with cou- pled data assimilation （Leefs_CDA）, which achieves a high predictive skill of up to a 24-month lead time for the equatorial eastern Pacific SST. As a result, the prediction skill of the present statistical model over the tropical In- dian Ocean is better than that of persistence prediction for January 1982 through December 2009.

Optimal Precursor Perturbations of El Ni?o in the Zebiak-Cane Model for Different Cost Functions

Optimal precursor perturbations of El Nino in the Zebiak-Cane model were explored for three different cost functions. For the different characteristics of the eastern-Pacific （EP） El Nino and the central-Pacific （CP） El Nino, three cost functions were defined as the sea surface temperature anomaly （SSTA） evolutions at prediction time in the whole tropical Pacific, the Nino3 area, and the Nino4 area. For all three cost functions, there were two optimal precursors that developed into El Nino events, called Precursor Ⅰ and Precursor Ⅱ. For Precursor Ⅰ, the SSTA component consisted of an east-west （positive-negative） dipole spanning the entire tropical Pacific basin and the thermocline depth anomaly pattern exhibited a tendency of deepening for the whole of the equatorial Pacific. Precursor Ⅰ can develop into an EP-El Nino event, with the warmest SSTA occurring in the eastern tropical Pacific or into a mixed El Nino event that has features between EP-El Nino and CP-El Nino events. For Precursor Ⅱ, the thermocline deepened anomalously in the eastern equatorial Pacific and the amplitude of deepening was obviously larger than that of shoaling in the central and western equatorial Pacific. Precursor Ⅱ developed into a mixed El Nino event. Both the thermocline depth and wind anomaly played important roles in the development of Precursor Ⅰ and Precursor Ⅱ.

The definition analyses of radiation temperature measurement area

In the research of primary spectrum pyrometry, this paper discussed the definition problem of radiation temperature measurement area based on the measurement coordinates. For the linear spectrum emissivity model and improved monotonic spectrum emissivity model, the characteristics of radiation temperature measurement area restricted by the measurement coordinates were theoretically analyzed, through the investigations of the temperature and emissivity coordinate axes. Choosing the specific primary spectrum pyrometer as an example in applications, the theoretical area of radiation temperature measurement of this pyrometer was given and it was verified through blackbody experiments. The discussions of this paper will provide the necessary foundation for the theory research development of primary spectrum pyrometry and the realization of technical applications.