The decomposition kinetics of glucose was studied in high-temperature liquid water （HTLW） from 180 to 220℃ under a pressure of 10 MPa. It was found the main products from glucose decomposition were 5-hydroxymethylf...The decomposition kinetics of glucose was studied in high-temperature liquid water （HTLW） from 180 to 220℃ under a pressure of 10 MPa. It was found the main products from glucose decomposition were 5-hydroxymethylfurfural （5-HMF） and levulinic acid （LA）. The decomposition kinetics of 5-HMF and stability of LA in HTLW were further investigated. A kinetic model for glucose decomposition was proposed accordingly. In the model, a series of first-order reactions with the consideration of parallel by-reactions were used to illustrate the decomposition of glucose. The decomposition activation energies of glucose, 5-HMF, and LA were evaluated as 118.85, 95.40, and 31.29 kJ·mol^-1, respectively.展开更多
Ultrafine grain pure aluminum was produced by equal channel angular pressing and cold rolling, the deformed aluminum was annealed at 200 ℃ for 1 h. The tensile curves of deformed and annealed aluminum show that yield...Ultrafine grain pure aluminum was produced by equal channel angular pressing and cold rolling, the deformed aluminum was annealed at 200 ℃ for 1 h. The tensile curves of deformed and annealed aluminum show that yield strength of deformed aluminum increases by 100%-300% and its elongation decreases by about 20%. After low temperature annealing, strength of annealed aluminum increases by 20% and elongation decreases by over 50%, the recovery of dislocations may be the main cause of annealing strengthening. In addition, there is an abrupt stress drop in the tensile curves of annealed aluminum and the formation of shear band is responsible for it.展开更多
基金Supported by the National Natural Science Foundation of China （20674068） and the Natural Science Foundation of Zhejiang Province （Y405157）.
文摘The decomposition kinetics of glucose was studied in high-temperature liquid water （HTLW） from 180 to 220℃ under a pressure of 10 MPa. It was found the main products from glucose decomposition were 5-hydroxymethylfurfural （5-HMF） and levulinic acid （LA）. The decomposition kinetics of 5-HMF and stability of LA in HTLW were further investigated. A kinetic model for glucose decomposition was proposed accordingly. In the model, a series of first-order reactions with the consideration of parallel by-reactions were used to illustrate the decomposition of glucose. The decomposition activation energies of glucose, 5-HMF, and LA were evaluated as 118.85, 95.40, and 31.29 kJ·mol^-1, respectively.
基金Project(gjd08011) supported by Shanghai Municipal Education Commission,ChinaProject (J51402) supported by Shanghai Leading Academic Discipline,China
文摘Ultrafine grain pure aluminum was produced by equal channel angular pressing and cold rolling, the deformed aluminum was annealed at 200 ℃ for 1 h. The tensile curves of deformed and annealed aluminum show that yield strength of deformed aluminum increases by 100%-300% and its elongation decreases by about 20%. After low temperature annealing, strength of annealed aluminum increases by 20% and elongation decreases by over 50%, the recovery of dislocations may be the main cause of annealing strengthening. In addition, there is an abrupt stress drop in the tensile curves of annealed aluminum and the formation of shear band is responsible for it.
