Gypsum-salt rocks and coccolith calcareous shale are widely deposited in the lower part of the Paleogene Shahejie Formation in the Dongying Sag, Sbandong Province. The gypsum-salt rock is believed to be formed during ...Gypsum-salt rocks and coccolith calcareous shale are widely deposited in the lower part of the Paleogene Shahejie Formation in the Dongying Sag, Sbandong Province. The gypsum-salt rock is believed to be formed during the earlier deposition in salt lake, while the overlying coccolith shale in saline lake with relatively low salinity. By comparing the lake environment and la- custrine microbial communities between ancient and recent lakes, cyanobacteria are regarded as the main representative of productivity during the formation of gypsum-salt strata series, with the annual productivity of 1500-2000 gC m-2 yr1. Based on the research of ultramicrofossils in the calcareous shale, coccolith is considered as the main contributor to the productivity during the formation of calcareous shale. On the basis of statistic data of sedimentary rates, shale laminations, and coccolith fossils in each lamination, the quantitative value of productivity is calculated, with the annual productivity of 2250 3810 gC m 2 yr-1 （averagely 3120 gC m-2 yr-1）. Statistic data of large amount of pyrite framboids indicate that the lower water col- umn was persistently in sulfidic or anoxic conditions during the deposition of gypsum-salt strata series, but it changed to be dysoxic when the coccolith calcareous shale was deposited. Both of these water conditions are favorable for the preservation of organic matter. It is estimated that the organic carbon burial efficiency of the Lower Paleogene salt lakes and saline lakes of Dongying Depression is about 10%-15%, which is calculated and analyzed using the multi-parameter geobiological model.展开更多
Based on comprehensive studies in petrography, petrofabric analysis and geochemistry, this paper describes a unique and rare laminated micritic ferruginous primary dolostone crystallized and precipitated from the alka...Based on comprehensive studies in petrography, petrofabric analysis and geochemistry, this paper describes a unique and rare laminated micritic ferruginous primary dolostone crystallized and precipitated from the alkaline hot brine under the conditions of the Mesozoic faulted lake basin. The main rock-forming mineral of this dolostone is ferruginous dolomite with a micritic structure. This dolomite mostly exhibits laminae of 0.1-1 mm thick and is often discovered with other minerals, such as albite, analcite, barite and dickite, which have at least two types of interbedded laminae. Petrogeochemistry reveals that this dolostone contains a large number of typomorphic elements of hydrothermal sedimentation, including Sb, Ba, Sr, Mn, and V. In addition, the LREE is in relatively high concentrations and possesses the typical REE distribution pattern with negative Eu anomaly. Oxygen isotope values （C^ISOpDB） range from 5.89%~ to 14.15%o with an average of 9.69%0. The ratio of 87Sr/86Sr is between 0.711648 and 0.719546, with an average of 0.714718. These data indicate that the depositional environment is a stable, blocked, anoxic low-lying hot brine pool in the bottom of deep lake controlled by basement faults. The hydrothermal fluid is the alkaline hot brine formed by the combination of the infiltration lake water and mantle-derived magmatic water, consisting of many ions, including Ca2＋, Mg2＋ and Fe2＋. Under the driving flow power of magmatic heat, gravity and compaction, the hy- drothermal fluid overcame the overburden pressure and hydrostatic pressure of the lake water body, and boiled to explosion, and then the explosion shattered the original laminated micritic ferruginous primary dolostone near the vent and then formed a new type of dolostone called shattered ＂hydroexplosion breccias＂. In the low-lying, unperturbed hot brine pool, far from the vent, the laminated micritic ferruginous primary dolostone was quickly crystallized and chemicals precipitated from the hy- drotherm. This study of special rocks contributes to research into the causes of the formation of lacustrine carbonate rocks and dolostone. In particular, it provides new examples and research insights for future studies of the lacustrine dolomite from the similar Mesozoic and Cenozoic basins in China.展开更多
基金supported by National Science and Technology Major Project (Grant No. 2009ZX05009)National Basic Research Program of China (Grant No. 2011CB808800)+1 种基金National Natural Science Foundation of China (Grant Nos. 41172036, 40730209)the "111" Project (Grant No. B08030)
文摘Gypsum-salt rocks and coccolith calcareous shale are widely deposited in the lower part of the Paleogene Shahejie Formation in the Dongying Sag, Sbandong Province. The gypsum-salt rock is believed to be formed during the earlier deposition in salt lake, while the overlying coccolith shale in saline lake with relatively low salinity. By comparing the lake environment and la- custrine microbial communities between ancient and recent lakes, cyanobacteria are regarded as the main representative of productivity during the formation of gypsum-salt strata series, with the annual productivity of 1500-2000 gC m-2 yr1. Based on the research of ultramicrofossils in the calcareous shale, coccolith is considered as the main contributor to the productivity during the formation of calcareous shale. On the basis of statistic data of sedimentary rates, shale laminations, and coccolith fossils in each lamination, the quantitative value of productivity is calculated, with the annual productivity of 2250 3810 gC m 2 yr-1 （averagely 3120 gC m-2 yr-1）. Statistic data of large amount of pyrite framboids indicate that the lower water col- umn was persistently in sulfidic or anoxic conditions during the deposition of gypsum-salt strata series, but it changed to be dysoxic when the coccolith calcareous shale was deposited. Both of these water conditions are favorable for the preservation of organic matter. It is estimated that the organic carbon burial efficiency of the Lower Paleogene salt lakes and saline lakes of Dongying Depression is about 10%-15%, which is calculated and analyzed using the multi-parameter geobiological model.
基金supported by National Natural Science Foundation of China(Grant No.41002033)National Science and Technology Major Project(Grant No.2011ZX05030-003-02)Foundation for Fostering Middleaged and Young Key Teachers of Chengdu University of Technology
文摘Based on comprehensive studies in petrography, petrofabric analysis and geochemistry, this paper describes a unique and rare laminated micritic ferruginous primary dolostone crystallized and precipitated from the alkaline hot brine under the conditions of the Mesozoic faulted lake basin. The main rock-forming mineral of this dolostone is ferruginous dolomite with a micritic structure. This dolomite mostly exhibits laminae of 0.1-1 mm thick and is often discovered with other minerals, such as albite, analcite, barite and dickite, which have at least two types of interbedded laminae. Petrogeochemistry reveals that this dolostone contains a large number of typomorphic elements of hydrothermal sedimentation, including Sb, Ba, Sr, Mn, and V. In addition, the LREE is in relatively high concentrations and possesses the typical REE distribution pattern with negative Eu anomaly. Oxygen isotope values （C^ISOpDB） range from 5.89%~ to 14.15%o with an average of 9.69%0. The ratio of 87Sr/86Sr is between 0.711648 and 0.719546, with an average of 0.714718. These data indicate that the depositional environment is a stable, blocked, anoxic low-lying hot brine pool in the bottom of deep lake controlled by basement faults. The hydrothermal fluid is the alkaline hot brine formed by the combination of the infiltration lake water and mantle-derived magmatic water, consisting of many ions, including Ca2＋, Mg2＋ and Fe2＋. Under the driving flow power of magmatic heat, gravity and compaction, the hy- drothermal fluid overcame the overburden pressure and hydrostatic pressure of the lake water body, and boiled to explosion, and then the explosion shattered the original laminated micritic ferruginous primary dolostone near the vent and then formed a new type of dolostone called shattered ＂hydroexplosion breccias＂. In the low-lying, unperturbed hot brine pool, far from the vent, the laminated micritic ferruginous primary dolostone was quickly crystallized and chemicals precipitated from the hy- drotherm. This study of special rocks contributes to research into the causes of the formation of lacustrine carbonate rocks and dolostone. In particular, it provides new examples and research insights for future studies of the lacustrine dolomite from the similar Mesozoic and Cenozoic basins in China.
