Long-chain alkenones (LCAs) can potentially be used as indicators to understand past variations in lacustrine environments.Previous research has suggested that the relationship between the temperature and the unsatura...Long-chain alkenones (LCAs) can potentially be used as indicators to understand past variations in lacustrine environments.Previous research has suggested that the relationship between the temperature and the unsaturation index of LCAs should be calibrated individually,because of the possible variations in the alkenone-producing algal species in the lacustrine environment.In this work,we have calibrated U37K' of water filter samples against the in-situ water temperature in Lake Qinghai,Tibetan Plateau.There are significant relationships between U37K' and the water temperature,a non-linear relationship was derived.Because the U37K' values did not respond sensitively at lower temperatures,we suggested that a quadratic regression (U37K' =0.0011×T2-0.0201×T+0.1959,n=15,r2=0.74) was appropriate than linear regression to represent the relationship between the in-situ temperatures and U37K'.Meanwhile,the U37K correlation relationship was not more significant than U37K' index in our study.Because of the C37:4 effects by salinity change,we suggest U37K is not as robust as the U37K' index as a temperature proxy,at least for the salt lake in the Tibetan Plateau.The calibration of the U37K' index in this work has provided a new understanding of historic climatic changes in the Tibetan Plateau.展开更多
The hydrogen isotopic composition(δD) of leaf wax long-chain n-alkanes(C27, C29, and C31) from lacustrine sediments has been widely applied to reconstruct terrestrial paleoclimatic and paleohydrological changes. Howe...The hydrogen isotopic composition(δD) of leaf wax long-chain n-alkanes(C27, C29, and C31) from lacustrine sediments has been widely applied to reconstruct terrestrial paleoclimatic and paleohydrological changes. However, few studies have addressed whether the aquatic-derived n-alkanes can affect the δD values of lake sedimentary long-chain n-alkanes, which are usually regarded as a recorder of the terrestrial hydrological signals. Here we systematically investigated δD values of long-chain n-alkanes from modern aquatic plants, both near-shore and off-shore surface sediments, surrounding terrestrial plant litters, as well as river water and lake water in Lake Qinghai and its satellite lakes on the northeastern Qinghai-Tibet Plateau. Our data showed that(i) δD values of long-chain n-alkanes from aquatic plants varied from-184‰ to-132‰ for n-C27, from-183‰ to-138‰ for n-C29, and from-189‰ to-130‰ for n-C31, respectively, with no significant differences among the three n-alkanes homologues;(ii) δD values of long-chain n-alkanes from aquatic plants were generally more positive than those from surrounding terrestrial plants, possibly because that they recorded the D-enrichment of lake water in this semi-arid region;(iii) δD values of long-chain n-alkanes from surface sediments showed significant differences among the three n-alkanes homologues, due to the larger aquatic input of n-C27 to the sedimentary lipid pool than that of n-C31, and(iv) n-C27 δD values of near-shore aquatic plants and near-shore sediments are more negative than those from off-shore as a result of lower δD values of near-shore lake water. Our findings indicate that in this region(i) the offset between sedimentary n-C27 and n-C31 δD values(ΔδDC27-C31) could potentially be used to evaluate if sedimentary long-chain n-alkanes are derived from a single source;(ii) while δD values of n-C27 may be influenced by lake water hydrological changes, sedimentary n-C31 is derived predominantly from terrestrial plants and thus its δD can serve as a relatively reliable indicator for terrestrial paleoclimatic and paleohydrological reconstructions.展开更多
基金supported by the National Natural Science Foundation of China(41002059)the West Light Foundation of the Chinese Academy of Sciences
文摘Long-chain alkenones (LCAs) can potentially be used as indicators to understand past variations in lacustrine environments.Previous research has suggested that the relationship between the temperature and the unsaturation index of LCAs should be calibrated individually,because of the possible variations in the alkenone-producing algal species in the lacustrine environment.In this work,we have calibrated U37K' of water filter samples against the in-situ water temperature in Lake Qinghai,Tibetan Plateau.There are significant relationships between U37K' and the water temperature,a non-linear relationship was derived.Because the U37K' values did not respond sensitively at lower temperatures,we suggested that a quadratic regression (U37K' =0.0011×T2-0.0201×T+0.1959,n=15,r2=0.74) was appropriate than linear regression to represent the relationship between the in-situ temperatures and U37K'.Meanwhile,the U37K correlation relationship was not more significant than U37K' index in our study.Because of the C37:4 effects by salinity change,we suggest U37K is not as robust as the U37K' index as a temperature proxy,at least for the salt lake in the Tibetan Plateau.The calibration of the U37K' index in this work has provided a new understanding of historic climatic changes in the Tibetan Plateau.
基金supported by the National Natural Science Foundation of China (Grant No. 41573005)the National Basic Research Program of China (Grant No. 2013CB955901)
文摘The hydrogen isotopic composition(δD) of leaf wax long-chain n-alkanes(C27, C29, and C31) from lacustrine sediments has been widely applied to reconstruct terrestrial paleoclimatic and paleohydrological changes. However, few studies have addressed whether the aquatic-derived n-alkanes can affect the δD values of lake sedimentary long-chain n-alkanes, which are usually regarded as a recorder of the terrestrial hydrological signals. Here we systematically investigated δD values of long-chain n-alkanes from modern aquatic plants, both near-shore and off-shore surface sediments, surrounding terrestrial plant litters, as well as river water and lake water in Lake Qinghai and its satellite lakes on the northeastern Qinghai-Tibet Plateau. Our data showed that(i) δD values of long-chain n-alkanes from aquatic plants varied from-184‰ to-132‰ for n-C27, from-183‰ to-138‰ for n-C29, and from-189‰ to-130‰ for n-C31, respectively, with no significant differences among the three n-alkanes homologues;(ii) δD values of long-chain n-alkanes from aquatic plants were generally more positive than those from surrounding terrestrial plants, possibly because that they recorded the D-enrichment of lake water in this semi-arid region;(iii) δD values of long-chain n-alkanes from surface sediments showed significant differences among the three n-alkanes homologues, due to the larger aquatic input of n-C27 to the sedimentary lipid pool than that of n-C31, and(iv) n-C27 δD values of near-shore aquatic plants and near-shore sediments are more negative than those from off-shore as a result of lower δD values of near-shore lake water. Our findings indicate that in this region(i) the offset between sedimentary n-C27 and n-C31 δD values(ΔδDC27-C31) could potentially be used to evaluate if sedimentary long-chain n-alkanes are derived from a single source;(ii) while δD values of n-C27 may be influenced by lake water hydrological changes, sedimentary n-C31 is derived predominantly from terrestrial plants and thus its δD can serve as a relatively reliable indicator for terrestrial paleoclimatic and paleohydrological reconstructions.
