The positron lifetime spectra and electrical conductivities have been measured for polyaniline as a function of protonation level ([H+] from 10-7-1000.8 mol/L). Weobserved that (1) the short lifetime τ1, which was re...The positron lifetime spectra and electrical conductivities have been measured for polyaniline as a function of protonation level ([H+] from 10-7-1000.8 mol/L). Weobserved that (1) the short lifetime τ1, which was related to electron density in bulk,decreased with the protonation level; (2) the intermediate lifetime τ2≈360ps, almost remaining constant, whereas its intensity I2 increased with increasing protonation level which was related to the conductivity of material. These results are discussed in terms of conducting island model.展开更多
文摘The positron lifetime spectra and electrical conductivities have been measured for polyaniline as a function of protonation level ([H+] from 10-7-1000.8 mol/L). Weobserved that (1) the short lifetime τ1, which was related to electron density in bulk,decreased with the protonation level; (2) the intermediate lifetime τ2≈360ps, almost remaining constant, whereas its intensity I2 increased with increasing protonation level which was related to the conductivity of material. These results are discussed in terms of conducting island model.
