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四正丁基溴化铵的合成改进 被引量:3
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作者 王国喜 李淑君 《辽宁化工》 CAS 1999年第4期211-212,共2页
通过对四正丁基溴化铵合成的有关文献分析,提出了一种改良措施,在不使用溶剂的情况下,使溴代正丁烷与部分三正丁胺回流反应3h后,剩余量的三正丁胺在4h内滴入,接近反应终点时加入乙酸丁酯,冷却析出粗品,从苯中重结晶得四正丁... 通过对四正丁基溴化铵合成的有关文献分析,提出了一种改良措施,在不使用溶剂的情况下,使溴代正丁烷与部分三正丁胺回流反应3h后,剩余量的三正丁胺在4h内滴入,接近反应终点时加入乙酸丁酯,冷却析出粗品,从苯中重结晶得四正丁基溴化铵精品,产品纯度大于99%,收率90.2% 展开更多
关键词 四正丁基 合成 溴化安
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Using prechloramination to control trihalomethanes formation in River Huang water with high bromide
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作者 陶辉 陈卫 +3 位作者 林涛 刘成 陈杰 李圭白 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2008年第5期722-727,共6页
An effective technology in controlling trihalomethanes (THMs) formation in the case of large amounts of bromide presenting was proposed, and the water of River Huang seriously polluted by bromide in winter in Tianji... An effective technology in controlling trihalomethanes (THMs) formation in the case of large amounts of bromide presenting was proposed, and the water of River Huang seriously polluted by bromide in winter in Tianjin City was studied. The THMs formation characteristics during prechloramination using preformed chloramines and converted chloramines were studied through jar tests. Results show that, in prechloramination process, the formation of THMs by preformed chloramines is very few, while that by converted ehloramines is a little higher. And the formation of THMs, especially Br^- substituted THMs, increases with the increase of time and Cl2:N ratio as well as the decrease of pH. The result obtained in a pilot plant shows that compared with prechlorination, the prechloramination process can efficiently control the formation of THMs, especially the Br^- substituted species. With equal chlorine dosage, the prechloramination can maintain a larger chlorine residue which offece, a larger CT value than prechlorination. 展开更多
关键词 prechloramination TRIHALOMETHANES BROMIDE pilot plant chemical security
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