In this study, we investigated the nucleation mechanism of perovskite films by employing isopropanol(IPA), a weakly coordinating solvent, to anneal both PbI2 and CH3 NH3 PbI3 in the sequential deposition and CsPbI3 in...In this study, we investigated the nucleation mechanism of perovskite films by employing isopropanol(IPA), a weakly coordinating solvent, to anneal both PbI2 and CH3 NH3 PbI3 in the sequential deposition and CsPbI3 in the one-step deposition. IPA solvent annealing(IPA SA) of PbI2 films was carried out at different temperatures. The grain size,compactness, roughness and morphology of PbI2 and CH3 NH3 PbI3 films were seriously affected by annealing methods. Similarly, weakly coordinating solvent annealing process was also employed to anneal all inorganic CsPbI3 perovskite in a one-step method. A continuous and dense CsPbI3 film with uniform grain size was obtained. We recognized that weakly coordinating solvent annealing for perovskite could regulate the dissolution-recrystallization process via controlling the volume of residual solvent in perovskite intermediate films. The power conversion efficiency(PCE) of conventional CH3 NH3 PbI3 perovskite solar cells(PSCs)reached 17.4% and that of CsPbI3 PSCs reached 2.5% based on this sequential IPA SA process.展开更多
Three new iron（Ⅲ） phosphonate cage-like complexes with [Fe4], [Feg] and [Fe14] cores have been synthesized by solvothermal reaction with various starting materials. Magnetic studies show overall antiferromagnetic i...Three new iron（Ⅲ） phosphonate cage-like complexes with [Fe4], [Feg] and [Fe14] cores have been synthesized by solvothermal reaction with various starting materials. Magnetic studies show overall antiferromagnetic interaction presented in these cages.展开更多
基金supported by the National Natural Science Foundation of China(61574029,61421002 and 61574029)supported by University of Kentucky
文摘In this study, we investigated the nucleation mechanism of perovskite films by employing isopropanol(IPA), a weakly coordinating solvent, to anneal both PbI2 and CH3 NH3 PbI3 in the sequential deposition and CsPbI3 in the one-step deposition. IPA solvent annealing(IPA SA) of PbI2 films was carried out at different temperatures. The grain size,compactness, roughness and morphology of PbI2 and CH3 NH3 PbI3 films were seriously affected by annealing methods. Similarly, weakly coordinating solvent annealing process was also employed to anneal all inorganic CsPbI3 perovskite in a one-step method. A continuous and dense CsPbI3 film with uniform grain size was obtained. We recognized that weakly coordinating solvent annealing for perovskite could regulate the dissolution-recrystallization process via controlling the volume of residual solvent in perovskite intermediate films. The power conversion efficiency(PCE) of conventional CH3 NH3 PbI3 perovskite solar cells(PSCs)reached 17.4% and that of CsPbI3 PSCs reached 2.5% based on this sequential IPA SA process.
基金financially supported by Marie Curie International Incoming Fellowship (E.C. Contract No: PIIF-GA-2008-219588)the starting fund of Xi’an Jiaotong University (to YZZ)+1 种基金the Engineering and Physical Science Research Council (UK)the Royal Society for a Wolfson Merit Award (to REPW)
文摘Three new iron（Ⅲ） phosphonate cage-like complexes with [Fe4], [Feg] and [Fe14] cores have been synthesized by solvothermal reaction with various starting materials. Magnetic studies show overall antiferromagnetic interaction presented in these cages.
