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英语定语从句的一种译法——溶合法
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作者 郑宗杜 林子安 《漳州师院学报(哲学社会科学版)》 1987年第1期70-75,共6页
英语定语从句形式繁多、语义含蓄。汉译时,可采用前置法(亦称合译法),或者后置法(亦称分译法),前者把定语从句译成带“……的”的定语词组,放在被修饰词之前,从而将复合句译成汉语简单句,后者一般用于结构较复杂的定语从句,... 英语定语从句形式繁多、语义含蓄。汉译时,可采用前置法(亦称合译法),或者后置法(亦称分译法),前者把定语从句译成带“……的”的定语词组,放在被修饰词之前,从而将复合句译成汉语简单句,后者一般用于结构较复杂的定语从句,译成后置的监列分句、或独立句。有些兼有状语职能的定语从句,还可以译成汉语的偏正复句。不少翻译专著对此有较详尽论述。张培基等四位同志合著的《英汉翻译教程》提到限制性定语从句一种比较新颖的译法——溶合法(亦称转换法),即把原句中的主语和定语从句溶合在一起,译成一个独立句子。书中指出;“Therebe”结构带有定语从的复合句往往是这样处理的。在实际应用中,溶合法也适用于其他英语句型,而且这种溶合法可以是“主句”和“定语从句”的溶合,不局限于“主语”和“定语从句”的溶合。本文仅对该种译法在英语三种基本句型的应用作初步探讨。 展开更多
关键词 英语定语从句 分译法 溶合法 《英汉翻译教程》 限制性定语从句 偏正复句 英语句型 基本句型
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英语定语从句的巧译
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作者 王归立 《甘肃农业》 2006年第9X期245-245,共1页
本文根据定语从句的构成及特点,结合实例介绍了定语从句的四种翻译方法:压缩法、溶合法、拆译法和转译法。
关键词 定语从句 压缩法 溶合法 拆译法 转译法
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定语从句的理解和汉译
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作者 郑晶 《宁德师专学报(哲学社会科学版)》 2004年第1期45-48,共4页
在英汉翻译中 ,定语从句的翻译是难点 ,也是重点。定语从句译得好不好 ,直接关系到整篇译文的质量 ,本文拟从语法角度。
关键词 定语从句 汉译 英语 汉语 英汉翻译 前置法 后置法 溶合法 语法角度 语义角度 语用角度
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Influence of pH value and chelating reagent on performance of Li_3V_2(PO_4)3/C cathode material 被引量:2
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作者 向伟 唐艳 +4 位作者 王雁英 钟本和 方为茂 刘恒 郭孝东 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第5期1395-1402,共8页
The Li3V2(PO4)3/C composite cathode material was synthesized via sol-gel method using three different chelating agents (citric acid, salicylic acid and polyacrylic acid) at pH value of 3 or 7. The crystal structur... The Li3V2(PO4)3/C composite cathode material was synthesized via sol-gel method using three different chelating agents (citric acid, salicylic acid and polyacrylic acid) at pH value of 3 or 7. The crystal structure, morphology, specific surface area and electrochemical performance of the prepared samples were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charge/discharge test. The results show that the effects of pH value on the performance of the prepared materials are greatly related to the chelating agents. With salicylic acid or polyacrylic acid as the chelating reagent, the structure, morphology and electrochemical performance of the samples are greatly influenced by the pH values. However, the structure of the materials with citric acid as the chelating agent does not change as pH value changes, and the materials own uniform particle size distribution and good electrochemical performance. It delivers an initial discharge capacity of 113.58 mA·h/g at 10C, remaining as high as 108.48 mA·h/g after 900 cycles, with a capacity retention of 95.51%. 展开更多
关键词 Li3V2(PO4)3 cathode material sol-gel method chelating agents pH value
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A Novel Approach to Synthesizing Porous ZnO Films: Inorganic Chelating Sol-Gel Method 被引量:1
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作者 杨立荣 靳正国 +1 位作者 步邵静 程志捷 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2004年第3期241-246,共6页
Porous ZnO films are synthesized by inorganic chelating sol-gel method,which is a novel sol-gel technique using zinc nitrate as starting materials and citric acid as the chelating reagent.The crystal structure,surface... Porous ZnO films are synthesized by inorganic chelating sol-gel method,which is a novel sol-gel technique using zinc nitrate as starting materials and citric acid as the chelating reagent.The crystal structure,surface morphology,porous and optical properties of the deposited films are investigated.X-ray diffraction pattern analysis shows that crystal structure of the ZnO films is hexagonal wurtzite.Scanning electron microscopy (SEM) shows that the ZnO film is porous.The curve of pore size distribution has two peak values at about 2.02nm and 4.97nm and BET surface area of the ZnO film is 27.57m2/g.In addition,the transmittance spectrum gives a high transmittance of 85% in the visible region and optical bandgap of the ZnO film (fired at 500℃) is 3.25eV. 展开更多
关键词 porous ZnO film inorganic chelating sol-gel method pore size distribution PROPERTIES
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医学英语中定语从句译法探讨
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作者 吴臻 《山西职工医学院学报》 CAS 2005年第4期61-62,共2页
关键词 前置法 后置法 溶合法 医学英语 定语从句
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Surface modification of NiTi alloy by sol-gel derived porous TiO_(2)film 被引量:3
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作者 付涛 吴晓明 +3 位作者 吴锋 罗孟 董兵辉 纪元 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第7期1661-1666,共6页
Titania films with nano-sized pores were prepared on the NaOH?HCl pretreated NiTi alloy substrate by sol?gel method.A crack-free film is obtained for the sample with a dense inner layer and a porous outside layer(s... Titania films with nano-sized pores were prepared on the NaOH?HCl pretreated NiTi alloy substrate by sol?gel method.A crack-free film is obtained for the sample with a dense inner layer and a porous outside layer(sample TC1+1).The X-ray diffraction shows that the titania films are composed of anatase,and a little Ni4Ti3 phase in the heat treated substrate is also detected.The X-ray photoelectron spectroscopy results indicate that the titania film completely covered the NiTi substrate for sample TC1+1.The sample TC1+1 is hydrophilic with a contact angle about 20°,and UV illumination treatment for 15 min further decreases the contact angle to(9.2±3.2)°.The potentiodynamic polarization test in 0.9% NaCl solution reveals a better corrosion resistance of sample TC1+1 than the polished NiTi sample. 展开更多
关键词 NiTi alloy TITANIA sol-gel method HYDROPHILICITY corrosion resistance
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螺旋藻的破碎及藻蓝色素的提取 被引量:8
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作者 叶海辉 何秀芬 王秀兰 《华南热带农业大学学报》 2001年第3期24-30,共7页
研究螺旋藻细胞的三种破碎方法及其对提取藻蓝色素的的影响。实验结果表明 ,最佳破碎方法为酶溶—高压均质结合法。其破碎条件为 :均质压力 2 0Kpa、酶用量 10 0mg/10 0 g干粉、而循环次数应为 3次 ,酶解温度为 4 5℃。
关键词 螺旋藻 破碎 藻蓝素 提取 -高压均质结合法 天然食用色素
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我对《英汉翻译教程》的一些浅见
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作者 邹必成 《外国语文》 1986年第3期99-106,共8页
由教育部委托中国人民解放军洛阳外国语学院编写的我国高等院校通用教材——《英汉翻译教程》,系统地介绍了一些基本翻译理论知识和基本规律,其最大的特点是全部运用对比法来叙述翻译的理论、方法和技巧;它通过英汉两种语言的全面对比... 由教育部委托中国人民解放军洛阳外国语学院编写的我国高等院校通用教材——《英汉翻译教程》,系统地介绍了一些基本翻译理论知识和基本规律,其最大的特点是全部运用对比法来叙述翻译的理论、方法和技巧;它通过英汉两种语言的全面对比来掌握两者的异同和特点,从而解决了如何用不同的语言形式来表达同一思想内容的问题。同时,译例丰富而且深浅兼有,照顾了程度参差不齐的学生。 展开更多
关键词 《英汉翻译教程》 原文 译例 词序 翻译理论 重复法 句子结构 句法结构 译文 编者 溶合法 浅见
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也谈外贸英语中定语从句的理解与汉译
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作者 章石如 《南昌高专学报》 1999年第1期37-42,共6页
《中国翻译》1997年第6期发表了许国新同志的《英文商贸契约中定语从句的理解与汉译》一文,它以详实的译例分门别类地介绍了用前置法和转换法翻译商贸契约中定请从句的问题,读后使人受益匪浅,但有两点美中不足。现就“前置法与后置... 《中国翻译》1997年第6期发表了许国新同志的《英文商贸契约中定语从句的理解与汉译》一文,它以详实的译例分门别类地介绍了用前置法和转换法翻译商贸契约中定请从句的问题,读后使人受益匪浅,但有两点美中不足。现就“前置法与后置法”、“溶合法与分句法”等几个问题与许国新同志商榷,并与广大同仁共同探讨。 展开更多
关键词 外贸英语 定语从句 英汉翻译 前置法 后置法 溶合法 分句法 中国
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Microwave-assisted Synthesis of Modified Polyaspartic Acid in Solvent 被引量:6
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作者 张玉玲 黄君礼 +1 位作者 程志辉 杨士林 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2007年第3期458-462,共5页
Polyaspartic acid(PASP)is suitable for the inhibition of scale deposition from water.To enhance its in- hibition efficiency,PASP was modified by reacting aspartic acid(Asp)with glutamic acid(Glu)to provide Asp-Glu cop... Polyaspartic acid(PASP)is suitable for the inhibition of scale deposition from water.To enhance its in- hibition efficiency,PASP was modified by reacting aspartic acid(Asp)with glutamic acid(Glu)to provide Asp-Glu copolymer under microwave irradiation.The influence of reaction parameters on conversion,molecular weight and inhibition of CaCO3 precipitation was investigated Infra-red.(IR), 1H nuclear magnetic resonance( 1H NMR)and 13C nuclear magnetic resonance( 13C NMR)spectroscopies were used to characterize the copolymer.The results show that copolymerization of aspartic acid and glutamic acid is catalyzed by a small amount of phosphorous acid (H3PO4)in solvent,the product conversion is 98.05%under the following conditions:the molar ratio of glutamic acid to reactant[Glu/(Asp+Glu)]is 0.3 and that of catalyst(Cat)to reactant[Cat/(Glu+Asp)]is 0.05(0.65ml H3PO4),the volume of solvent dimethylformamide is 16ml,the microwave power used is 720W and the reaction for 3 min.The weight average molecular weight of copolymer synthesized under these conditions is 2709 and the inhi- bition rate for CaCO3 is 97.75%. 展开更多
关键词 microwave irradiation aspartic acid glutamic acid COPOLYMER conversion ratio scale inhibition
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Structure, synthesis, and catalytic properties of nanosize cerium-zirconium-based solid solutions in environmental catalysis 被引量:20
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作者 Jixing Liu Zhen Zhao +1 位作者 Chunming Xu Jian Liu 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2019年第10期1438-1487,共50页
Nanosize cerium-zirconium solid solution(CZO)with a special fluorite structure has received an increasing research interest due to their remarkable advantages such as excellent oxygen storage capacity and great flexib... Nanosize cerium-zirconium solid solution(CZO)with a special fluorite structure has received an increasing research interest due to their remarkable advantages such as excellent oxygen storage capacity and great flexibility in their composition and structure.By partial metal(including rare earth,transition,alkaline earth or other metal)doping into CZO,the physicochemical properties of these catalytic materials can be controllable adjusted for the study of specific reactions.To date,nanosize CZO has been prepared by co-precipitation,sol-gel,surfactant-assisted approach,solution combustion,micro-emulsion,high energy mechanical milling,etc.The advent of these methodologies has prompted researchers to construct well-defined networks with customized micromorphology and functionalities.In this review,we describe not only the basic structure and synthetic strategies of CZO,but also their relevant applications in environmental catalysis,such as the purification for CO,nitrogen oxides(NOx),volatile organic compounds(VOC),soot,hydrocarbon(HC),CO2 and solid particulate matters(PM),and some reaction mechanisms are also summarized. 展开更多
关键词 Cerium-zirconium solid solution SYNTHESIS Method STRUCTURE Environmental catalysis
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Effects of doping route on microstructure and mechanical properties of W−1.0wt.%La2O3 alloys 被引量:5
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作者 Jun-jun YANG Gang CHEN +6 位作者 Zheng CHEN Xiao-dong MU Ying YU Lin ZHANG Xing-yu LI Xuan-hui QU Ming-li QIN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第12期3296-3306,共11页
A comparative study was conducted by using solution combustion synthesis with three different doping routes(liquid-liquid(WL10), liquid-solid(WLNO) and solid-solid(WLO)) to produce nanoscale powders and further fabric... A comparative study was conducted by using solution combustion synthesis with three different doping routes(liquid-liquid(WL10), liquid-solid(WLNO) and solid-solid(WLO)) to produce nanoscale powders and further fabricate the ultrafine-grained W-1.0 wt.%La2O3 alloys by pressureless sintering. Compared with pure tungsten, W-1.0 wt.%La2O3 alloys exhibit ultrafine grains and excellent mechanical properties. After sintering, the average grain size of the WLO sample is larger than that of WL10 and WLNO samples;the microhardness values of WL10 and WLNO samples are similar but larger than the value of WLO sample. The optimized La2O3 particles are obtained in the WL10 sample after sintering at 1500 ℃ with the minimum mean size by comparing with WLNO and WLO samples, which are uniformly distributed either at grain boundaries or in the grain interior with the sizes of(57±29.7) and(27±13.1) nm, respectively. This study exhibits ultrafine microstructure and outperforming mechanical properties of the W-1.0 wt.%La2O3 alloy via the liquid-liquid doping route, as compared with conventionally-manufactured tungsten materials. 展开更多
关键词 tungsten alloy solution combustion synthesis doping route ultrafine grain MICROHARDNESS
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Er^(3+)-activated silica inverse opals synthesized by the solgel method 被引量:2
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作者 A. Chiappini C.Armellini +11 位作者 A. Chiasera Y. Jestin M. Ferrari M. Mattarelli M. Montagna E. Moser C. Tosello L. Zampedri G. Nunzi Conti S. Pelli R. M. Almeida G. C. Righini 《Optoelectronics Letters》 EI 2007年第3期184-187,共4页
We present the details of the sol-gel processing used to realize inverse silica opal,where the silica was activated with 0.3 mol% of Er3+ ions. The template(direct opal) was obtained assembling polystyrene spheres of ... We present the details of the sol-gel processing used to realize inverse silica opal,where the silica was activated with 0.3 mol% of Er3+ ions. The template(direct opal) was obtained assembling polystyrene spheres of the dimensions of 260 nm by means of a vertical deposition technique. The Er3+-activated silica inverse opal was obtained infiltrating,into the void of the template,the silica sol doped with Er3+ ions and subsequently removing the polystyrene spheres by means of calcinations. Scanning electron microscope showed that the inverse opals possess a fcc structure with a air hollows of about 210 nm and a photonic band gap,in the visible range,was observed from reflectance measurements. Spectroscopic properties of Er3+-activated silica inverse opal were investigated by luminescence spectroscopy,where,upon excitation at 514.5 nm,an emission of 4I13/2 → 4I15/2 of Er3+ ions transition with a 21 nm bandwidth was observed. Moreover the 4I13/2 level decay curve presents a single-exponential profile,with a measured lifetime of 18 ms,corresponding a high quantum efficiency of the system. 展开更多
关键词 铒掺杂 活性硅 反opal结构 胶-凝胶法 合成
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Selection of Chelated Fe(Ⅲ)/Fe(Ⅱ) Catalytic Oxidation Agents for Desulfurization Based on Iron Complexation Method 被引量:5
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作者 Luo Ying Liu Youzhi +2 位作者 Qi Guisheng Guo Huidong Zhu Zhengfeng 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2014年第2期50-58,共9页
Optimization of factors influencing the experiments on reactions involving 8 different chelating agents and soluble Fe(III)/Fe(II) salts was carried out to yield chelated iron complexes. A combination of optimized inf... Optimization of factors influencing the experiments on reactions involving 8 different chelating agents and soluble Fe(III)/Fe(II) salts was carried out to yield chelated iron complexes. A combination of optimized influencing factors has resulted in a Fe chelating capacity of the iron-based desulfurization solution to be equal to 6.83—13.56 g/L at a redox potential of 0.185—0.3. The desulfurization performance of Fe(III)/Fe(II) chelating agents was investigated on a simulated sulfur-containing industrial gas composed of H2 S and N2 in a cross-flow rotating packed bed. Test results have revealed that the proposed iron-based desulfurization solution showed a sulfur removal efficiency of over 99% along with a Fe chelating capacity exceeding 1.35 g/L. This desulfurization technology which has practical application prospect is currently in the phase of commercial scale-up study. 展开更多
关键词 hydrogen sulfide chelated iron catalytic oxidation factor analysis redox
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Structure,morphology and opto-magnetic properties of Bi_2MoO_6 nano-photocatalyst synthesized by sol-gel method 被引量:3
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作者 V.UMAPATHY A.MANIKANDAN +2 位作者 S.ARUL ANTONY P.RAMU P.NEERAJA 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第10期3271-3278,共8页
Bismuth molybdate (Bi2MoO6) nano-particles (NPs) were synthesized using bismuth nitrate, ammonium molybdate, citric acid and ethyl cellulose by a simple sol-gel method. The structure, morphology, opto-magnetic and... Bismuth molybdate (Bi2MoO6) nano-particles (NPs) were synthesized using bismuth nitrate, ammonium molybdate, citric acid and ethyl cellulose by a simple sol-gel method. The structure, morphology, opto-magnetic and photocatalytic properties of the obtained powder were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectra, high resolution scanning electron microscopy (HRSEM), energy dispersive X-ray (EDX), ultraviolet-visible diffuse reflectance spectra (DRS), photoluminescence (PL) spectra and vibrating sample magnetometer (VSM) techniques. The XRD, FT-IR and EDX results indicate that the resultant powder is pure and single phase crystalline Bi2MoO6 with orthorhombic structure. The HRSEM image shows that the morphology of obtained powder consists with well defined nano-particles structure. The VSM results show superparamagnetic behavior of the obtained nano-particles. The photocatalytic activity of Bi2MoO6 nano-particles was performed. The addition of TiO2 catalyst enhances the photocatalytic activity of Bi2MoO6 nano-particles. The catalysts Bi2MoO6, TiO2 and mixed oxide catalyst Bi2MoO6-TiO2 nano-composites (NCs) were tested for the photocatalytic degradation (PCD) of 4-chlorophenol (4-CP). It is found that the PCD efficiency of Bi2MoO6-TiO2 NCs is higher than that of pure Bi2MoO6 and TiO2 catalysts. 展开更多
关键词 Bi2MoO6 NANOSTRUCTURE sol-gel synthesis optical properties magnetic properties PHOTOCATALYST
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Sol-gel synthesis and photoluminescence of LaPO_4:Eu^(3+) nanorods 被引量:6
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作者 高锐 钱东 李卫 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第3期432-436,共5页
Monoclinic LaPO4 nanostructures with uniform rod shape have been successfully synthesized by a simple sol-gel method.The procedure involves formation of homogeneous,transparent,metal-citrate-EDTA gel precursors,follow... Monoclinic LaPO4 nanostructures with uniform rod shape have been successfully synthesized by a simple sol-gel method.The procedure involves formation of homogeneous,transparent,metal-citrate-EDTA gel precursors,followed by calcination to promote thermal decomposition of the gel precursors to yield the LaPO4 nanoparticles.Their morphologies and structures were characterized by XRD,TEM,TG-DSC and HRTEM.The results indicate that single monoclinic phase LaPO4 nanorods are readily obtained at 800 ℃ within 3 h.Furthermore,photoluminescence(PL) characterization of the Eu3+-doped LaPO4 nanocrystals was carried out.The effects of calcination temperatures and Eu3+ doping content on the PL properties were elaborated in detail.Room-temperature photoluminescence(PL) characterization reveals that the optical brightness as well as the intensity ratio of 5D0-7F1 to 5D0-7F2 is highly dependent on the calcination temperature,and the Eu0.05La0.95PO4 nanophosphor shows the relatively promising PL performance with the most intense emission. 展开更多
关键词 LAPO4 Eu doping SOL-GEL NANORODS PHOTOLUMINESCENCE
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Effect of Preparation Conditions on Visible Photocatalytic Activity of Titania Synthesized by Solution Combustion Method 被引量:3
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作者 程友萍 孙红旗 +1 位作者 金万勤 徐南平 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2007年第2期178-183,共6页
Titania catalysts were synthesized by a solution combustion method (SCM). Photodegradation of 4-chlorophenol (4-CP) using the synthesized catalysts was studied under both visible light (λ≥420nm) and sunlight i... Titania catalysts were synthesized by a solution combustion method (SCM). Photodegradation of 4-chlorophenol (4-CP) using the synthesized catalysts was studied under both visible light (λ≥420nm) and sunlight irradiation. The effect of preparation conditions on photocatalytic activities of the synthesized catalysts was investigated. The optimal photocatalytic activity of the catalyst (denoted as A1 ) was obtained under the following synthesis conditions: ignition temperature of 350~C, fuel ratio ( φ) of 1 and calcination time of lh. The degradation and mineralization ratio of 4-CP were 78.2% and 53.7% respectively under visible light irradiation for 3h using catalyst A1. And the catalyst A1 also showed high photocatalytic activity under sunlight irradiation. 展开更多
关键词 TiO2 solution combustion method PHOTODEGRADATION visible light
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Preparation and Application of the Sol–Gel Combustion Synthesis-Made CaO/CaZrO_3 Sorbent for Cyclic CO_2 Capture Through the Severe Calcination Condition 被引量:5
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作者 王保文 宋小勇 +1 位作者 王宗华 郑楚光 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2014年第9期991-999,共9页
Calcium looping method has been considered as one of the efficient options to capture C02 in the combustion Ilue gas. CaO-based sorbent is the basis for application of calcium looping and should be subjected to the se... Calcium looping method has been considered as one of the efficient options to capture C02 in the combustion Ilue gas. CaO-based sorbent is the basis for application of calcium looping and should be subjected to the severe calcination condition so as to obtain the concentrated C02 stream. In this research, CaO/CaZrO3 sorbents were synthesized using the sol-gel combustion synthesis (SGCS) method with urea as fuel. The cyclic reaction performance of the synthesized sorbents was evaluated on a lab-scaled reactor system through calcination at 950 ℃ in a pure C02 atmosphere and carbonation at 650 ℃ in the 15% (by volume) C02. The mass ratio of CaO to CaZr03 as 8:2 (designated as CasZr2) was screened as the best option among all the synthesized CaO sorbents for its high CO2 capture capacity and carbonation conversion at the initial cycle. And then a gradual decay in the C02 capture capacity was observed at the following 10 successive cycles, but hereafter stabilized throughout the later cycles. Furthermore, structural evolution of the carbonated CasZr2 over the looping cycles was investigated. With increasing looping cycles, the pore peak and mean grain size of the carbonated CasZr2 sorbent shifted to the bigger direction but both the surface area (SA) ratio and surface fractal dimension Ds decreased. Finally, morphological transformation of the carbonated CasZr2 was observed. Agglomeration and edge rounding of the newly formed CaC03 grains were found as aggravated at the cyclic carbonation stage. As a result, carbonation of CasZr2 with C02 was observed only confined to the external active CaO by the fast formation of the CaC03 shell outside, which occluded the further carbonation of the unreacted CaO inside. Therefore, enough attention should be paid to the carbonation stage and more effective activation measures should be explored to ensure the unreacted active CaO fully carbonatPd river the extended Ioonin cycles. 展开更多
关键词 C02 captureCalcium looping cyclesCaO/CaZr03 sorbentSol-gel combustion synthesis method
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Preparation and properties of PEO/LiClO_4/KH560-SiO_2 composite polymer electrolyte by sol-gel composite-in-situ method 被引量:4
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作者 潘春跃 高金环 +2 位作者 张倩 冯庆 巢猛 《Journal of Central South University of Technology》 2008年第3期295-300,共6页
Composite polymer electrolytes based on polyethylene oxide(PEO) were prepared by using LiClO4 as doping salt and silane-modified SiO2 as filler. SiO2 was formed in-situ in (PEO)8LiClO4 matrix by the hydrolysis and con... Composite polymer electrolytes based on polyethylene oxide(PEO) were prepared by using LiClO4 as doping salt and silane-modified SiO2 as filler. SiO2 was formed in-situ in (PEO)8LiClO4 matrix by the hydrolysis and condensation reaction of Si(OC4H9)4. The crystallinity,morphology and ionic conductivity of composite polymer electrolyte films were examined by differential scanning calorimetry,scanning electron microscopy,atom force microscopy and alternating current impedance spectroscopy,respectively. Compared with the crystallinity of the unmodified SiO2 as inert filler,that of composite polymer electrolytes is decreased. The results show that silane-modified SiO2 particles are uniformly dispersed in (PEO)8LiClO4 composite polymer electrolyte film and the addition of silane-modified SiO2 increases the ionic conductivity of the (PEO)8LiClO4 more noticeably. When the mass fraction of SiO2 is about 10%,the conductivity of (PEO)8LiClO4-modified SiO2 attains a maximum value of 4.8×10-5 S·cm-1. 展开更多
关键词 polyethylene oxide(PEO) SOL-GEL composite-in-situ polymer electrolyte ionic conductivity
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