NH_3·H_2O皂化P_20_4/煤油体系微乳液(反向胶束)的溶水性能及其对V(Ⅳ)的萃取研究

研究了氨水（ＮＨ３·Ｈ２Ｏ）皂化Ｐ２０４／煤油体系形成的微乳液的相区和粘度变化，溶水能力，无机盐对溶水能力的影响，以及萃取Ｖ（Ⅳ）的机理和萃取效率．

环烷酸氨皂W/O微乳液的相行为及溶水性能

绘制了环烷酸 /煤油 /氨水体系的部分拟三元相图 ,研究了几种醇 (助表面活性剂 )和几种常见的强酸强碱盐及其浓度 ,溶剂对环烷酸氨皂W/O型微乳液溶水性能的影响 .

坪湖矿长兴灰岩的溶水性分析与采煤方法

通过对长兴灰岩的岩溶水性分布及危害的调研和优化采掘方案,并试行小变形间隔长条带结合短方柱走向长壁后退式全部垮落顶板的采煤方法,成功采出煤炭117.82万t,为煤炭行业在岩溶、水体或村庄下压煤的安全开采奠定了技术基础。

水性肠溶型丙烯酸树脂乳液和薄膜包衣的研制

采用乳液聚合方法直接合成以水为分散介质的肠溶型丙烯酸树脂,研究分析了聚合过程中,乳化剂、引发剂、相对分子质量调节剂、pH值缓冲剂的种类、用量的影响,以及反应温度、搅拌速度、加料方式的影响。找到了一条合理的聚合工艺路线。同时研究了肠溶型丙烯酸树脂的薄膜包衣过程。

水性胃溶型丙烯酸树脂乳液薄膜包衣的研制

用水性胃溶型丙烯酸树脂水乳液进行薄膜包衣 ,进行了一系列的药物质量考察实验 ,结果发现制得的薄膜包衣具有更稳定的性能。分析了各种工艺因素对胃溶型丙烯酸树脂水乳液薄膜包衣的影响。

电感耦合等离子发射光谱法同时测定土壤中水溶性阳离子与硫酸根

通过建立电感耦合等离子发射光谱法,测定土壤中水溶性阳离子与硫酸根。该方法不仅缩短了操作流程,同时提高了检测的精密度和正确度,降低了方法了检出限。通过空白样品实验,各离子检出限为0.25~1.18 mg/kg,通过国家一级标准物质验证,相对标准偏差(RSD,n=7)均不大于5.19%,适合土壤样品的批量分析。

新的溶于水二氧化硅纳米材料

日本国立材料科学研究所(NIM5)开发了一种可溶于水的二氧化硅纳米材料。该种材料采用溶胶一凝胶法合成制得。它系由一个在表面上含有离子替代基的直径为1nm的二氧化硅聚合物棒组成。在水中，水分子可容易地渗透到二氧化硅棒之间的空间。通常，纳米二氧化硅在三维空间中无序生长，形成一个大分子网状结构，因此，它不溶于水及其它各种溶剂。而新开发的二氧化硅纳米材料，则在一个方向上有序生长，使其易溶于水，由此，在溶剂中的化学反应得以实现。所以，一种与有机物质结合的均匀二氧化硅(系无机材料)新型复合材料的设想产生了，要做到这一点。

水溶纤维的应用研究

利用水溶纤维的可溶水性加上其它性能优势,实现用低支毛纺高支纱的设想。

Anti-tumor Effect and Protective Effect on Chemotherapeutic Damage of Water Soluble Extracts from Hedyotis diffusa

Bai-Hua-She-She-Cao Hedyotis diffusa Willd. (Ru-biaceae) is a medicinal herbwidely distributed in northeast Asian countries. In traditional Chinese medicine, it has the effectof 'clearing away heat and toxic material, promoting blood circulation and removing blood stasis'.It is a well known Chinese folk-medicine used for the treatment of appendicitis, sore throat, mumps,acne, sebo-rheic dermatitis and various kinds of tumors, such as tumors of digestive tract,carcinoma of liver. It was reported that the MeOH extract of H. diffusa demonstrated a significantantitumor activity and ursolic acid succeeded in being isolated from the MeOH extract as an activecomponent . Shan BN, et al suggested that the direct aqueous extract of H. diffusa hadimmuno-modulating activity and antitumor activity in vitro through stimulating the immune system tokill or engulf tumor cells. But regarding anti-tumor activity in vivo of water soluble extracts fromH. diffusa, no detail was reported. Therefore, we prepared water soluble extracts (H_1 and H_2)from H. diffusa and evaluated their anti-tumor property in vivo experiments as well as protectiveeffect on chemo-therapeutic damage.

Photocatalytic Degradation of Water-Soluble Dyes by LaCoO_3

Pervoskite type oxides LaCoO 3 was prepared by citrate method with the granula of 20 nm-30 nm. With a fluorescent Hg lamp or sunlight as irradiator, the degradation experiments of various water soluble dyes were carried out in the suspension system of LaCoO 3 . The results show that the pervoskite type oxide LaCoO 3 has good photocatalytic activity.Studied by X ray photoelectron spectroscopy and photoacoustic spectra, its photocatalytic activity is found to be related with factors such as the d electron structure of ion Co 3+ ,Co—O binding energy and adsorbed oxygen on the surface etc.

Release Model of Water-soluble Chitosan Nanoparticles for Protein Delivery

[Objective] The experiment aimed to explore release rule of water-soluble chitosan (WSC) in vitro. [Method]The bovine serum albumin(BSA) was taken as a model protein drug and some existing release models such as Kinetics model, Gompertz model, Weibull model, Higuchi model and Logistic model were used to fit the BSA release profile from WSC carriers. [Result] Except Higuchi model and Logistic model, other models could fit BSA release profile better. [Conclusion] Gompertz two-order kinetics model could fit the release of WSC nano-particles better and model parameters had practical physical meaning.

Effects of Nitrogen Fertilizer Regulation with Straw-return on Wheat Yield and Different Forms of Potassium in the Soil

In order to study the effects of nitrogen fertilizer application methods and nitrogen fertilizer regulation with straw-return on wheat yield and potassium forms in the soil, field experiment was arranged in Pinyuan County, and the effects of the regulation of different ratios of basal to topdressed nitrogen on the yield of wheat and the contents of different forms of potassium in the soil were studied. The re- sults indicated that in the condition of straw-return, the yield of wheat was the high- est after the treatments of the ratios of basal to topdressed nitrogen of 7：3 and 6：4. As to the contents of different forms of potassium, the contents of water-soluble potassium, exchangeable potassium and total potassium treated by the ratios of basal to topdressed nitrogen of 7：3 and 6：4 were the highest, and the differences of non-exchangeable potassium among all treatments were not significant. Under the experiment condition, the ratios of basal to topdressed nitrogen of 7：3 and 6：4 were the best treatments, they can increase the wheat yield and the contents of available potassium and total potassium in the soil.

Hydrophilic and photocatalytic activities of Nd-doped titanium dioxide thin films

The Nd-doped TiO2 thin films with higher hydrophilic and photocatalytic activities were prepared on glass slides by an acid-catalyzed sol？gel method. The effects of Nd doping on crystalline phase, surface composition and optical property were investigated by means of techniques such as X-ray diffraction （XRD）, scanning electron microscopy （SEM）, transmission electron microscopy （TEM）, Fourier transform infrared spectroscopy （FT-IR）, optical contact angle tester and UV-Vis spectroscopy. The results show that Nd doping obviously influences the hydrophilic and photocatalytic activities of TiO2thin films. Nd doping could cause the TiO2 lattice distortion, inhibit phase transition from anatase to rutile, cause red shift of the absorption spectrum edge, produce hydroxyl radicals （·OH）, and accelerate surface hydroxylation, which result in a significant improvement in the hydrophilicity and photoreactivity of Nd-doped TiO2 thin films. When the content of Nd is 0.1% （mass fraction）, TiO2 thin films achieve the smallest grain size （about 15 nm）, and the hydrophilic and photocatalytic activities of TiO2 thin film reach the maximum, the contact angle is only 8.1°, and 92% of methylene blue is finally degraded. Moreover, the modification mechanism of Nd doping was also discussed.

Stability of Baicalin Aqueous Solution by Validated RP-HPLC

Aim In the present study a RP-HPLC method was developed and validated toinvestigate the stability of baicalin aqueous solution. Methods The influences of temperature and pHon the stability of baicalin aqueous solution were investigated by classic homoiothermicacceleration test, and the pH for the most stable solution was determined. Results The time whenbaicalin suffered 10% loss was found to be 18.1 h, and the degradation activation energy of baicalinwas 79.1 kJ·moL^(-1) . The pH at which baicalin is most stable is 4.28. Conclusion The temperatureshould be kept at a lower level and the pH should be adjusted to near that for the most stablesolution in the production of baicalin preparations.

Surface modification of NiTi alloy by sol-gel derived porous TiO_(2)film

Titania films with nano-sized pores were prepared on the NaOH？HCl pretreated NiTi alloy substrate by sol？gel method.A crack-free film is obtained for the sample with a dense inner layer and a porous outside layer（sample TC1＋1）.The X-ray diffraction shows that the titania films are composed of anatase,and a little Ni4Ti3 phase in the heat treated substrate is also detected.The X-ray photoelectron spectroscopy results indicate that the titania film completely covered the NiTi substrate for sample TC1＋1.The sample TC1＋1 is hydrophilic with a contact angle about 20°,and UV illumination treatment for 15 min further decreases the contact angle to（9.2±3.2）°.The potentiodynamic polarization test in 0.9% NaCl solution reveals a better corrosion resistance of sample TC1＋1 than the polished NiTi sample.

Identification of an Algae-lysing Bacterium of Anabaena flosaquae and Primary Research on Their Relationship

[Objective] The aim was to explore the relationship between alage-lysing bacterium and Anabaena flosaquae so as to provide reference for the control of bloom. [Method] An algae-lysing bacterium strain named S7 was isolated from eu- trophic river. The lyric efficiency and performing mode of S7 strain to Anabaena flos- aquae was studied. Influence of different environmental factors and the relationship between S7 strain and Anabaena flosaquae was also studied, and then the bacteri- um strain was physiologically identified. [Result] More than 90% of Anabaena flos- aquae had been removed by 7 d when the volume ratio of medium to algae solu- tion was 30%, the pH was 9 and the temperature was 35 ℃. These results also showed that a mutual inhibit relationship existed between S7 strain and Anabaena flos-aquae. The S7 strain killed the algae by indirectly through certain lyric agents in absence of direct contact with the target but by secreting metabolites. Moreover, these lyric agents also had the thermostability. 16SrDNA sequence analysis showed that S7 strain belonged to Chryseobacterium sp. [Conclusion] The examined Poly-p proved that S7 strain is polyphosphate accumulating bacteria （PAOs） and has better lyric efficiency.

Estimation of Digestible Energy Values of Plant Protein Supplement in Pig

[Objective] The aim of the study was to establish the effective and accurate formulas for estimating the digestible energy （DE） values of plant protein supplement in pig. [Method] By difference method with different amount of alternative feeds （20% -50%）, two4 x4 Latin- square-designed trials were taken on eight castrated male pigs [ Yorkshire x Landrace x Neijiang pig, initial body-weight： （46 ±2） kg ] to deter- mine the apparent digestible energy （ADE） of the eight kinds of plant protein supplement commonly used in China, that is, corn gluten meal （sol.）, soybean meal （ sol. ）, fababean, pea, rapeseed meal （ sol. ）, sesame meal （ sol. ）, rapeseed meal （ exp. ） and cotton seed meal （sol.）. [Resultl （1） Fiber was the most important factor to estimate the ADE of plant protein supplement in pigs, and ADF was the best one. （2） The most effective equations were as below： （ 1 ） OE （kJ/kg DM） = 14 741.86 - 185.01ADF＋54.01SCHO＋22.45CP （ R =0.988,RSD= 67.9,P〈0.01 ） ; （2） DE （kJ/kg DM） =22 223.26 -209.58ADF＋26.79SCHO-1.09GE （ Ff =0.989,RSD=66.9, P〈0.01 ） . [Conclusion] The accurate, practical and specific regression equations were established for DE prediction of plant protein supplement in pig.

Sol-gel preparation, corrosion resistance and hydrophilicity of Ta-containing TiO_2 films on Ti6Al4V alloy

Ta-containing TiO2 films with Ta contents of 5%, 20%, 33% （mole fraction） were sol-gel coated on the surface roughened Ti6AI4V alloy by dip coating method for biomedical applications. The Ta-TiO2 films on 1.5 mol/L NaOH-HCI pretreated substrate are adherent, but there are cracks for the sample with 33% Ta. X-ray photoelectron spectroscopy results show that Ti and Ta exist as TiP2 and Ta205 in the film, and A1 element is not detectable. X-ray diffraction and Raman scattering analyses reveal that the addition of Ta decreases crystallization of the films. Potentiodynamic polarization test in a Ca-free Hank＇s balanced solution demonstrates that the coating samples markedly improve the corrosion resistance compared with the polished sample. The addition of Ta impedes UV light-induced hydrophilic conversion of the coating samples. The sample with 20% Ta has enough film integrity and hydrophilic conversion rate, and is expected to possess good biological properties.

Effect of thatch on water-soluble phosphorus of pasture soil fertilized with broiler litter

The presence of a thatch layer in established pastures could reduce the contact between broiler litter and soil, thus increasing the potential for surface runoff contamination with litter P. We conducted a laboratory study to evaluate the effect of a thatch layer on the dynamics of water-soluble P in undisturbed cores taken from a pasture. Cores with and without a thatch layer received a surface application of broiler litter (5 thm-2) and were incubated at 25 oC for 56 d. The result showed that on the soil surface the contents of water soluble-P (39 kghm-2) of the cores with the thatch layer was higher than that (20 kghm-2) of the cores without the thatch layer. Therefore on well-established pastures fertilized with broiler litter, the presence of a thatch layer might lead to high concentrations of water-soluble P on the soil surface.