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水解聚丙烯酰胺盐水溶液表观粘度的数学模拟(Ⅲ)——表观粘度与剪切速率的通用关系式 被引量:5
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作者 方道斌 郭睿威 +2 位作者 周少刚 聂贵权 程杰成 《化工学报》 EI CAS CSCD 北大核心 1997年第1期80-84,共5页
通过对水解聚丙烯酰胺盐水溶液的流动曲线的分析,提出了两点假设.据此分别建立了Meter-Bird式常数γ_(1/2)和P_α与零剪切粘度η_0间的经验式,及表观粘度η_α和剪切速率γ间的通用 Meter-Bird式.用此方程式与本文(Ⅰ)报通用 MHS方程式... 通过对水解聚丙烯酰胺盐水溶液的流动曲线的分析,提出了两点假设.据此分别建立了Meter-Bird式常数γ_(1/2)和P_α与零剪切粘度η_0间的经验式,及表观粘度η_α和剪切速率γ间的通用 Meter-Bird式.用此方程式与本文(Ⅰ)报通用 MHS方程式和(Ⅱ)报式(4) 联用,模拟水解聚丙烯酰胺盐水溶液的表观粘度,取得了较好的结果. 展开更多
关键词 水解 聚丙烯酰胺 聚电解质 溶液流变学 粘度
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Numerical Study on Interaction Between Two Bubbles Rising Side by Side in CMC Solution 被引量:5
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作者 范文元 尹晓红 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第7期705-713,共9页
A numerical simulation was performed to investigate the interaction of two bubbles rising side by side in shear-thinning fluid using volume of fluid (VOF) method coupled with continuous surface force (CSF) method.... A numerical simulation was performed to investigate the interaction of two bubbles rising side by side in shear-thinning fluid using volume of fluid (VOF) method coupled with continuous surface force (CSF) method. By considering rheological characteristics of fluid, this approach was able to accurately capture the deformation of bubble interface, and validated by comparing with the experimental results. The rising of bubble pairs with different configurations, including horizontal alignment and oblique alignment, was simulated by the method. The influences of the bubble initial distance and the bubble alignment were studied by analyzing the bubble deformation, rising paths and flow fields surrounding bubbles. The results indicate that within certam mltlal bubble spacing of S = 3.3 (S* = SI/D, SI initial distance between bubbles, and D bubble diameter), the dynamic interaction between two bub- bles aligned horizontally shows repulsive effect that decreases with the increase of initial bubble spacing, but weakens to certain degree by the shear-thinning properties of fluid. However, the interaction between two bubbles aligned obliquely presents a repulsive effect for the small angle involved but an attractive impact for the large one, which is vet strengthened by the rheological characteristics of fluid. 展开更多
关键词 bubble pairs INTERACTION SHEAR-THINNING volume of fluid method rheological characteristics
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Miscibility, Crystallization, and Rheological Behavior of Solution Casting Poly(3-hydroxybutyrate)/poly(ethylene succinate) Blends Probed by Differential Scanning Calorimetry, Rheology, and Optical Microscope Techniques
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作者 孙伟华 乔晓平 +1 位作者 曹启坤 刘结平 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第1期107-112,I0002,共7页
The miscibility and crystallization of solution casting biodegradable poly(3-hydroxybuty- rate)/poly(ethylene succinate) (PHB/PES) blends was investigated by differential scanning calorimetry, rheology, and opti... The miscibility and crystallization of solution casting biodegradable poly(3-hydroxybuty- rate)/poly(ethylene succinate) (PHB/PES) blends was investigated by differential scanning calorimetry, rheology, and optical microscopy. The blends showed two glass transition temperatures and a depression of melting temperature of PHB with compositions in phase diagram, which indicated that the blend was partially miscible. The morphology observation supported this result. It was found that the PHB and PES can crystallize simultaneously or upon stepwise depending on the crystallization temperatures and compositions. The spherulite growth rate of PHB increased with increasing of PES content. The influence of compositions on the spherulitic growth rate for the partially miscible polymer blends was discussed. 展开更多
关键词 MISCIBILITY Poly(3-hydroxybutyrate)/poly(ethylene succinate) blend Phase behavior CRYSTALLIZATION
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