In order to evaluate the electrochemical properties of aluminum alloy anode under high current densities in alkaline electrolyte, the galvanostatic discharge, potentiodynamic polarization and hydrogen evolution tests ...In order to evaluate the electrochemical properties of aluminum alloy anode under high current densities in alkaline electrolyte, the galvanostatic discharge, potentiodynamic polarization and hydrogen evolution tests of three experimental Al?Mg?Sn?In?(Ga) alloys were performed. The results show that the alloying element gallium improves the working potentials of experimental Al?Mg?Sn?In alloys under different discharge current densities. The average working potentials of the alloys containing gallium can reach?1.3 V under current density ranging from 650 to 900 mA/cm2, while those of alloy without Ga are only?1.0 V. Such phenomenon is attributed to the solid solution which can form amalgam with aluminum matrix. Such an amalgam can form the hydrolyzed species during the discharge process and lead to the corrosion infiltrating into aluminum matrix.展开更多
针对宁夏某输电线路上悬式绝缘子用锁紧销断裂失效的问题,采用宏观检查、化学成分材质分析、金相检测、扫描电镜(scanning electron microscope,SEM)以及能谱仪(energy dispersive spectrometer,EDS)分析等方法进行了分析。研究发现材质...针对宁夏某输电线路上悬式绝缘子用锁紧销断裂失效的问题,采用宏观检查、化学成分材质分析、金相检测、扫描电镜(scanning electron microscope,SEM)以及能谱仪(energy dispersive spectrometer,EDS)分析等方法进行了分析。研究发现材质为H62黄铜的锁紧销外表面覆盖一层纯铜,纯铜薄厚不均,与黄铜的界面分明,锁紧销裂纹起源于纯铜较厚位置,沿晶扩展,断口内有S元素存在。综合分析认为:锁紧销由表面溶解-再沉积机制主导发生脱锌腐蚀,脱锌后锁紧销表面力学性能下降,受力后服役过程中锁紧销脱锌表面萌生微裂纹,微裂纹以应力腐蚀机制扩展,锁紧销开裂失效。展开更多
基金Project supported by the Open Fund of the State Key Laboratory of Powder Metallurgy,China
文摘In order to evaluate the electrochemical properties of aluminum alloy anode under high current densities in alkaline electrolyte, the galvanostatic discharge, potentiodynamic polarization and hydrogen evolution tests of three experimental Al?Mg?Sn?In?(Ga) alloys were performed. The results show that the alloying element gallium improves the working potentials of experimental Al?Mg?Sn?In alloys under different discharge current densities. The average working potentials of the alloys containing gallium can reach?1.3 V under current density ranging from 650 to 900 mA/cm2, while those of alloy without Ga are only?1.0 V. Such phenomenon is attributed to the solid solution which can form amalgam with aluminum matrix. Such an amalgam can form the hydrolyzed species during the discharge process and lead to the corrosion infiltrating into aluminum matrix.
文摘针对宁夏某输电线路上悬式绝缘子用锁紧销断裂失效的问题,采用宏观检查、化学成分材质分析、金相检测、扫描电镜(scanning electron microscope,SEM)以及能谱仪(energy dispersive spectrometer,EDS)分析等方法进行了分析。研究发现材质为H62黄铜的锁紧销外表面覆盖一层纯铜,纯铜薄厚不均,与黄铜的界面分明,锁紧销裂纹起源于纯铜较厚位置,沿晶扩展,断口内有S元素存在。综合分析认为:锁紧销由表面溶解-再沉积机制主导发生脱锌腐蚀,脱锌后锁紧销表面力学性能下降,受力后服役过程中锁紧销脱锌表面萌生微裂纹,微裂纹以应力腐蚀机制扩展,锁紧销开裂失效。
