Influence of supersaturation on the structure of a series of freshly prepared supersaturated sodium aluminate solutions with medium concentration was investigated by solution X-ray diffraction. Experimental results sh...Influence of supersaturation on the structure of a series of freshly prepared supersaturated sodium aluminate solutions with medium concentration was investigated by solution X-ray diffraction. Experimental results show that the basic Al-containing species in all kinds of supersaturated solution is four-coordinated ions. Opposite to Al-O distance contracted in highly concentrated solution, a little expand of the Al-O distance from 1.75 *@ to 1.85 *@ occurs with increasing supersaturation, which is consistent with the occurrence of oligomeric aluminate species. Meanwhile, O-O distance in the first shell of H 2O-H 2O(OH) in supersaturated sodium aluminate solution is obviously longer than in hydroxide sodium solution and becomes longer and longer with increasing supersaturation. Na-O bond length is about 2.4 *@ and changes little with supersaturation. The reason for Al-O bond expanding with supersaturation and its influence on the stability of solution was discussed.展开更多
AimTo study effects of PVP K30 on the aque ou s solubility and dissolution properties of daidzein. Methods To measure the aqueous solubility and dissolution rates of daidzein in three diffe rent states (within solid d...AimTo study effects of PVP K30 on the aque ou s solubility and dissolution properties of daidzein. Methods To measure the aqueous solubility and dissolution rates of daidzein in three diffe rent states (within solid dispersions, physical mixtures and as a pure drug) and investigate drug-polymer interactions in the solid state using X-ray powder d iffraction and fourier-transform infrared spectroscopy. Results The negative values of the Gibbs free energy and enthalpy of transfer explaine d the spontaneous transfer of daidzein from phosphate buffer solution (PBS) to a solution of PVP in PBS. X-ray powder diffraction patterns showed that the drug was in the amorphous state (ratio of the drug ∶ PVP<1∶5) when dispers ed i n PVP K30. The infrared spectra indicated there exist interactions between the O H of daidzein and the C=O of PVP K30. Conclusionthe dispersion of daidzein in PVP K30 considerably enhances the solubility and dissolution rat e.展开更多
The erosion failure mechanism of concrete is studied systematically based on field investigation and laboratory experiments of concrete samples from more than 30 km concrete lining and 10 hydraulic structures of Shand...The erosion failure mechanism of concrete is studied systematically based on field investigation and laboratory experiments of concrete samples from more than 30 km concrete lining and 10 hydraulic structures of Shandong Jiaodong water diversion project, in which the concrete failed only 3-6 months after conslruction was completed. With electron microscopy scanning, energy dispersive analysis, XKD （X-ray diffraction） analysis and Raman spectrum analysis of the mineral composition of the failure concrete and precipitates, chemical and physical reactions that occurred in the concrete under engineering environment were investigated. The analysis indicated that the rapid corrosion and dissolution reaction of the concrete in weak sulfate environment is due to sulfate and carbonate corrosion with the catalytic magnesium salt at low temperature. Also, corrosion damage facilitates the sulfate ions and carbonate ions into the concrete, and the expansion of ettringite and TSA （thaumasite sulfate attack） reaction also accelerates the corrosion damage of the concrete.展开更多
文摘Influence of supersaturation on the structure of a series of freshly prepared supersaturated sodium aluminate solutions with medium concentration was investigated by solution X-ray diffraction. Experimental results show that the basic Al-containing species in all kinds of supersaturated solution is four-coordinated ions. Opposite to Al-O distance contracted in highly concentrated solution, a little expand of the Al-O distance from 1.75 *@ to 1.85 *@ occurs with increasing supersaturation, which is consistent with the occurrence of oligomeric aluminate species. Meanwhile, O-O distance in the first shell of H 2O-H 2O(OH) in supersaturated sodium aluminate solution is obviously longer than in hydroxide sodium solution and becomes longer and longer with increasing supersaturation. Na-O bond length is about 2.4 *@ and changes little with supersaturation. The reason for Al-O bond expanding with supersaturation and its influence on the stability of solution was discussed.
文摘AimTo study effects of PVP K30 on the aque ou s solubility and dissolution properties of daidzein. Methods To measure the aqueous solubility and dissolution rates of daidzein in three diffe rent states (within solid dispersions, physical mixtures and as a pure drug) and investigate drug-polymer interactions in the solid state using X-ray powder d iffraction and fourier-transform infrared spectroscopy. Results The negative values of the Gibbs free energy and enthalpy of transfer explaine d the spontaneous transfer of daidzein from phosphate buffer solution (PBS) to a solution of PVP in PBS. X-ray powder diffraction patterns showed that the drug was in the amorphous state (ratio of the drug ∶ PVP<1∶5) when dispers ed i n PVP K30. The infrared spectra indicated there exist interactions between the O H of daidzein and the C=O of PVP K30. Conclusionthe dispersion of daidzein in PVP K30 considerably enhances the solubility and dissolution rat e.
文摘The erosion failure mechanism of concrete is studied systematically based on field investigation and laboratory experiments of concrete samples from more than 30 km concrete lining and 10 hydraulic structures of Shandong Jiaodong water diversion project, in which the concrete failed only 3-6 months after conslruction was completed. With electron microscopy scanning, energy dispersive analysis, XKD （X-ray diffraction） analysis and Raman spectrum analysis of the mineral composition of the failure concrete and precipitates, chemical and physical reactions that occurred in the concrete under engineering environment were investigated. The analysis indicated that the rapid corrosion and dissolution reaction of the concrete in weak sulfate environment is due to sulfate and carbonate corrosion with the catalytic magnesium salt at low temperature. Also, corrosion damage facilitates the sulfate ions and carbonate ions into the concrete, and the expansion of ettringite and TSA （thaumasite sulfate attack） reaction also accelerates the corrosion damage of the concrete.
