Q63 2003021595漫射近似理论的有效使用范围分析=Analysis of the effectiveapplication range of diffusion approximation theory[刊,中]/万春明(长春光学精密机械学院.吉林,长春(130022))//光学技术.—2002,28(2).—137-138利用蒙特...Q63 2003021595漫射近似理论的有效使用范围分析=Analysis of the effectiveapplication range of diffusion approximation theory[刊,中]/万春明(长春光学精密机械学院.吉林,长春(130022))//光学技术.—2002,28(2).—137-138利用蒙特卡罗方法模拟了半无限大生物组织内部深度分辨的光能流率的分布情况。分析了漫射近似理论的有效使用范围。当组织厚度大于3/2个光子的平均自由程时,应用漫射近似理论能得到很好的结果,反之,漫射理论不能使用。也就是说,当组织厚度x】0.1875cm时,应用漫射理论能得到很好的结果;当组织厚度z【展开更多
Q63 2005032397 漫射近似在测量生物组织光学性质中的适用范围=Valid- ity of the diffusion approximation in determining the optical properties of biological tissus[刊,中]／李剑平(山东大学信 息科学与工程学院．山东,济南(2501...Q63 2005032397 漫射近似在测量生物组织光学性质中的适用范围=Valid- ity of the diffusion approximation in determining the optical properties of biological tissus[刊,中]／李剑平(山东大学信 息科学与工程学院．山东,济南(250100)),陈冰泉∥应用 光学．-2005,26(1).-20-24 采用Monte Carlo模拟校验的方法,对漫射近似理论 和Monte Carlo模拟计算的结果进行了比较。展开更多
Light illumination has been widely used to promote activity and selectivity of traditional thermal catalysts. Nevertheless, the role of light irradiation during catalytic reactions is not well understood. In this work...Light illumination has been widely used to promote activity and selectivity of traditional thermal catalysts. Nevertheless, the role of light irradiation during catalytic reactions is not well understood. In this work, Pt/Al2 O3 prepared by wet impregnation was used for photothermal CO2 hydrogenation, and it showed a photothermal effect. Hence, operando diffuse reflectance infrared Fourier-transform spectroscopy and density functional theory calculations were conducted on Pt/Al2 O3 to gain insights into the reaction mechanism. The results indicated that CO desorption from Pt sites including step sites(Ptstep) or/and terrace site(Ptterrace) is an important step during CO2 hydrogenation to free the active Pt sites. Notably, visible light illumination and temperature affected the CO desorption in different ways. The calculated adsorption energy of CO on Ptstep and Ptterrace sites was-1.24 and-1.43 e V, respectively. Hence, CO is more strongly bound to the Ptstep sites. During heating in the dark, CO preferentially desorbs from the Ptterrace site. However, the additional light irradiation facilitates transfer of CO from the Ptstep to Ptterrace sites and its subsequent desorption from the Ptterrace sites, thus promoting the CO2 hydrogenation.展开更多
文摘Q63 2003021595漫射近似理论的有效使用范围分析=Analysis of the effectiveapplication range of diffusion approximation theory[刊,中]/万春明(长春光学精密机械学院.吉林,长春(130022))//光学技术.—2002,28(2).—137-138利用蒙特卡罗方法模拟了半无限大生物组织内部深度分辨的光能流率的分布情况。分析了漫射近似理论的有效使用范围。当组织厚度大于3/2个光子的平均自由程时,应用漫射近似理论能得到很好的结果,反之,漫射理论不能使用。也就是说,当组织厚度x】0.1875cm时,应用漫射理论能得到很好的结果;当组织厚度z【
文摘Q63 2005032397 漫射近似在测量生物组织光学性质中的适用范围=Valid- ity of the diffusion approximation in determining the optical properties of biological tissus[刊,中]／李剑平(山东大学信 息科学与工程学院．山东,济南(250100)),陈冰泉∥应用 光学．-2005,26(1).-20-24 采用Monte Carlo模拟校验的方法,对漫射近似理论 和Monte Carlo模拟计算的结果进行了比较。
基金supported by the National Natural Science Foundation of China(U1862111,U1232119)Sichuan Provincial International Cooperation Project(2017HH0030)the Innovative Research Team of Sichuan Province(2016TD0011)~~
文摘Light illumination has been widely used to promote activity and selectivity of traditional thermal catalysts. Nevertheless, the role of light irradiation during catalytic reactions is not well understood. In this work, Pt/Al2 O3 prepared by wet impregnation was used for photothermal CO2 hydrogenation, and it showed a photothermal effect. Hence, operando diffuse reflectance infrared Fourier-transform spectroscopy and density functional theory calculations were conducted on Pt/Al2 O3 to gain insights into the reaction mechanism. The results indicated that CO desorption from Pt sites including step sites(Ptstep) or/and terrace site(Ptterrace) is an important step during CO2 hydrogenation to free the active Pt sites. Notably, visible light illumination and temperature affected the CO desorption in different ways. The calculated adsorption energy of CO on Ptstep and Ptterrace sites was-1.24 and-1.43 e V, respectively. Hence, CO is more strongly bound to the Ptstep sites. During heating in the dark, CO preferentially desorbs from the Ptterrace site. However, the additional light irradiation facilitates transfer of CO from the Ptstep to Ptterrace sites and its subsequent desorption from the Ptterrace sites, thus promoting the CO2 hydrogenation.
