Microstructure, mechanical property and oxidation resistance of MCrAlYX coatings prepared by detonation gun (D-gun) and HVOF spraying were investigated. Lamellar microstructure and uniform microstructure formed in D-g...Microstructure, mechanical property and oxidation resistance of MCrAlYX coatings prepared by detonation gun (D-gun) and HVOF spraying were investigated. Lamellar microstructure and uniform microstructure formed in D-gun sprayed MCrAlYX coating and HVOF sprayed coating, respectively. Element redistribution and formation of new phase took place during the detonation process. Besides, the porosity of D-gun sprayed coating was much lower than that of HVOF sprayed coating. On the mechanical property, the micro-hardnesses of the two coatings were in the same level (~HV 910). However, D-gun sprayed MCrAlYX coating exhibited larger standard deviation of microhardness due to its lamellar microstructure, and exhibited better bend bonding strength owing to the existence of residual compressive stress between the layers and particles. Meanwhile, due to the much more compact microstructure, D-gun sprayed MCrAlYX coating showed superior oxidation resistance to the HVOF sprayed coating. The continuous dense protective layer can form earlier in D-gun sprayed coating and thus suppress further oxidation and control the oxide thickness at a relatively low level.展开更多
Ni-Cr based nanostructured feedstock powder was prepared by mechanical milling technique involving repeated welding, fracturing, and re-welding of powder particles in a planetary ball mill. The milled nanocrystalline ...Ni-Cr based nanostructured feedstock powder was prepared by mechanical milling technique involving repeated welding, fracturing, and re-welding of powder particles in a planetary ball mill. The milled nanocrystalline powders were used to coat carbon steel tubes using high velocity oxygen fuel（HVOF） thermal spraying process. The characterization of the feedstock powder and HVOF coated substrates was performed using optical microscope, X-ray diffractometer（XRD）, scanning electron microscope（SEM）, high resolution transmission electron microscope（HR-TEM）, energy dispersive spectrometer（EDS） and microhardness tests. The coated and uncoated samples were subjected to different thermal cycles and characterized for their phase changes, metallurgical changes and microhardness variations. Ni-Cr nanostructured coated samples exhibited higher mechanical and metallurgical properties compared to their conventionally coated counter parts. The results showed that the nanostructured coating possessed a more uniform and denser microstructure than the conventional coating.展开更多
In this paper we present a performance evaluation of thermal spraying coated hot forging dies conducted in a production line. The High Velocity Oxy-Fuel process was used for the deposition of a tungsten carbide coatin...In this paper we present a performance evaluation of thermal spraying coated hot forging dies conducted in a production line. The High Velocity Oxy-Fuel process was used for the deposition of a tungsten carbide coating, which is characterized by its optimal adherence and low porosity. A metallurgical characterization of the layer was previously done, in order to obtain reference information to assist in the interpretation of the practical tests results. The coated die allowed an increase in productivity of 37.5%, besides better dimensional stability results through the process and legibility of printed numbers.展开更多
The water-cooled supersonic two-stage high-velocity oxy-fuel (HVOF) thermal spray gun was developed to make a coating of temperature-sensitive material,such as titanium,on a substrate.The gun has a combustion chamber ...The water-cooled supersonic two-stage high-velocity oxy-fuel (HVOF) thermal spray gun was developed to make a coating of temperature-sensitive material,such as titanium,on a substrate.The gun has a combustion chamber (CC) followed by a mixing chamber (MC),in which the combustion gas is mixed with the nitrogen gas at room temperature.The mixed gas is accelerated to supersonic speed through a converging-diverging (C-D) nozzle followed by a straight passage called the barrel.This paper proposes an experimental procedure to estimate the cooling rate of CC,MC and barrel separately.Then,the mathematical model is presented to predict the pressure and temperature in the MC for the specific mass flow rates of fuel,oxygen and nitrogen by assuming chemical equilibrium with water-cooling in the CC and MC,and frozen flow with constant specific heat from stagnant condition to the throat in the CC and MC.Finally,the present mathematical model was validated by comparing the calculated and measured stagnant pressures of the CC of the two-stage HVOF gun.展开更多
The leaks of pressurized hydrogen can be ignited if an ignition source is within a certain distance from the source of the leaks, and jet ftres or explosions may take place. In this paper, a high speed camera was used...The leaks of pressurized hydrogen can be ignited if an ignition source is within a certain distance from the source of the leaks, and jet ftres or explosions may take place. In this paper, a high speed camera was used to investigate the ignition kernel development, ignition probability and flame propagation along the axis of hydrogen jets, which leaked from a 3-ram-internal-diameter nozzle and were ignited by an electric spark. Experimental results indicate that for successful ignition events, the ignition delay time increases with an increase of the distance between the nozzle and the electrode. Ignitable zone of the hydrogen jets is underestimated if using the predicted hydrogen concentration along the jets centerline. The average rate of downstream flame decreases but that of the upstream flame increases with the electrode going far from the nozzle.展开更多
The self-extinguishing behavior of kerosene spray fire was investigated in a completely enclosed compartment with the size of 3 m× 3 m × 3.4 m. The spray was generated by locating one BETE nozzle at the cent...The self-extinguishing behavior of kerosene spray fire was investigated in a completely enclosed compartment with the size of 3 m× 3 m × 3.4 m. The spray was generated by locating one BETE nozzle at the center of the bottom wall. A series of spray fire videos were obtained by changing BETE nozzle type and injecting pressure. The results show that spray ftre undergoes four stages： the growth stage, the quasi-steady stage, the stretch stage and the self-extinguishing stage. Consumption of large quantities of oxygen causes spray fire to first be stretched and then quench. In this process, fire base migrates away from spray region and leads to the emergence of ghost- hag fire. Ghosting fire promotes the instability of spray fire and large fluctuation of its height, which provides help to its self-extinguishing. With increasing the injecting pressure or the nozzle diameter, the self-extinguishing time decreases. It is found that the self-extinguishing time is approximately in inverse relation with injecting flow rate. Additionally, we also observed the occurrence of two-phase de flagration just after ignition, and it accelerates the spray fire growth and induces a larger fire height than the following quasi-steady spray fire. The deflagration turns stronger with increasing the injecting pressure.展开更多
We consider the backreaction of the fundamental flavor degrees of freedom on the A dSs-Schwarz background, and calculate their contributions to the shear viscosity and jet-quenching parameter of the thermal quark-gluo...We consider the backreaction of the fundamental flavor degrees of freedom on the A dSs-Schwarz background, and calculate their contributions to the shear viscosity and jet-quenching parameter of the thermal quark-gluon plasma.展开更多
基金Project(51201156)supported by the National Natural Science Foundation of China
文摘Microstructure, mechanical property and oxidation resistance of MCrAlYX coatings prepared by detonation gun (D-gun) and HVOF spraying were investigated. Lamellar microstructure and uniform microstructure formed in D-gun sprayed MCrAlYX coating and HVOF sprayed coating, respectively. Element redistribution and formation of new phase took place during the detonation process. Besides, the porosity of D-gun sprayed coating was much lower than that of HVOF sprayed coating. On the mechanical property, the micro-hardnesses of the two coatings were in the same level (~HV 910). However, D-gun sprayed MCrAlYX coating exhibited larger standard deviation of microhardness due to its lamellar microstructure, and exhibited better bend bonding strength owing to the existence of residual compressive stress between the layers and particles. Meanwhile, due to the much more compact microstructure, D-gun sprayed MCrAlYX coating showed superior oxidation resistance to the HVOF sprayed coating. The continuous dense protective layer can form earlier in D-gun sprayed coating and thus suppress further oxidation and control the oxide thickness at a relatively low level.
基金supported and funded from consultancy project of Bharath Heavy Electricals Limited, Tiruchirappalli,India
文摘Ni-Cr based nanostructured feedstock powder was prepared by mechanical milling technique involving repeated welding, fracturing, and re-welding of powder particles in a planetary ball mill. The milled nanocrystalline powders were used to coat carbon steel tubes using high velocity oxygen fuel（HVOF） thermal spraying process. The characterization of the feedstock powder and HVOF coated substrates was performed using optical microscope, X-ray diffractometer（XRD）, scanning electron microscope（SEM）, high resolution transmission electron microscope（HR-TEM）, energy dispersive spectrometer（EDS） and microhardness tests. The coated and uncoated samples were subjected to different thermal cycles and characterized for their phase changes, metallurgical changes and microhardness variations. Ni-Cr nanostructured coated samples exhibited higher mechanical and metallurgical properties compared to their conventionally coated counter parts. The results showed that the nanostructured coating possessed a more uniform and denser microstructure than the conventional coating.
文摘In this paper we present a performance evaluation of thermal spraying coated hot forging dies conducted in a production line. The High Velocity Oxy-Fuel process was used for the deposition of a tungsten carbide coating, which is characterized by its optimal adherence and low porosity. A metallurgical characterization of the layer was previously done, in order to obtain reference information to assist in the interpretation of the practical tests results. The coated die allowed an increase in productivity of 37.5%, besides better dimensional stability results through the process and legibility of printed numbers.
文摘The water-cooled supersonic two-stage high-velocity oxy-fuel (HVOF) thermal spray gun was developed to make a coating of temperature-sensitive material,such as titanium,on a substrate.The gun has a combustion chamber (CC) followed by a mixing chamber (MC),in which the combustion gas is mixed with the nitrogen gas at room temperature.The mixed gas is accelerated to supersonic speed through a converging-diverging (C-D) nozzle followed by a straight passage called the barrel.This paper proposes an experimental procedure to estimate the cooling rate of CC,MC and barrel separately.Then,the mathematical model is presented to predict the pressure and temperature in the MC for the specific mass flow rates of fuel,oxygen and nitrogen by assuming chemical equilibrium with water-cooling in the CC and MC,and frozen flow with constant specific heat from stagnant condition to the throat in the CC and MC.Finally,the present mathematical model was validated by comparing the calculated and measured stagnant pressures of the CC of the two-stage HVOF gun.
基金Supported by the Fundamental Research Funds for the Central UniversitiesNational Natural Science Foundation of China(No.50806071)and(No.51276177)
文摘The leaks of pressurized hydrogen can be ignited if an ignition source is within a certain distance from the source of the leaks, and jet ftres or explosions may take place. In this paper, a high speed camera was used to investigate the ignition kernel development, ignition probability and flame propagation along the axis of hydrogen jets, which leaked from a 3-ram-internal-diameter nozzle and were ignited by an electric spark. Experimental results indicate that for successful ignition events, the ignition delay time increases with an increase of the distance between the nozzle and the electrode. Ignitable zone of the hydrogen jets is underestimated if using the predicted hydrogen concentration along the jets centerline. The average rate of downstream flame decreases but that of the upstream flame increases with the electrode going far from the nozzle.
基金supported by National Natural Science Foundation of China(Grant No.51276177)
文摘The self-extinguishing behavior of kerosene spray fire was investigated in a completely enclosed compartment with the size of 3 m× 3 m × 3.4 m. The spray was generated by locating one BETE nozzle at the center of the bottom wall. A series of spray fire videos were obtained by changing BETE nozzle type and injecting pressure. The results show that spray ftre undergoes four stages： the growth stage, the quasi-steady stage, the stretch stage and the self-extinguishing stage. Consumption of large quantities of oxygen causes spray fire to first be stretched and then quench. In this process, fire base migrates away from spray region and leads to the emergence of ghost- hag fire. Ghosting fire promotes the instability of spray fire and large fluctuation of its height, which provides help to its self-extinguishing. With increasing the injecting pressure or the nozzle diameter, the self-extinguishing time decreases. It is found that the self-extinguishing time is approximately in inverse relation with injecting flow rate. Additionally, we also observed the occurrence of two-phase de flagration just after ignition, and it accelerates the spray fire growth and induces a larger fire height than the following quasi-steady spray fire. The deflagration turns stronger with increasing the injecting pressure.
基金Supported by K.C.Wong Magna Fund in Ningbo University,National Natural Science Foundation of China under Grant No.11205093National Natural Science Foundation of under Grant No.11347020
文摘We consider the backreaction of the fundamental flavor degrees of freedom on the A dSs-Schwarz background, and calculate their contributions to the shear viscosity and jet-quenching parameter of the thermal quark-gluon plasma.
